Abstract
Recent advances address the development of anti-mildew and UV-resistance microcapsules for wood. IPBC (3-iodo-2-propynylbutylcarbamate) is enclosed in the drug-loaded carriers through slow release, resulting in the anti-mildew process. Anti-mildew experiments showed that the control effectiveness of 1.25wt% nano SiO2-IPBC microcapsules was 78.125% against Botryodiplodia theobromae. In addition, a novel angle of view is discussed, which is the UV-resistance, including different mass fractions of nano SiO2-IPBC microcapsules, IPBC and the control group. Different FTIR characterizations and surface colors related to impregnated wood samples are discussed. Nano SiO2-IPBC microcapsules had better bonding performance and UV-resistance than IPBC due to the synergistic effect of nano SiO2 and IPBC in the microcapsules. Color measurements showed that the UV-resistance of microcapsules was better than 1.25wt% IPBC-impregnated wood samples. It helps us open new horizons to anti-mould agent, which offers multi-function of great anti-mildew effect and excellent UV-resistance. The simple and green method for the preparation of microcapsules could have tremendous potential for the extensive development of wood protection.
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References
Bai Y, Li Z, Cheng B, Zhang M, Su K (2017) Higher UV-shielding ability and lower photocatalytic activity of TiO 2@ SiO 2/APTES and its excellent performance in enhancing the photostability of poly (p-phenylene sulfide). RSC Adv 7(35):21758–21767. https://doi.org/10.1039/C6RA28098F
Bak M (2018) Possibilities of using nanotechnology in Wood Colour Protection. Obuda Univ e-Bulletin 8(2):29–33
Bisht P, Pandey KK, Barshilia HC (2021) Photostable transparent wood composite functionalized with an UV-absorber. Polym Degrad Stab 189:109600. https://doi.org/10.1016/j.polymdegradstab.2021.109600
Cai L, Jeremic D, Lim H et al (2019) β-Cyclodextrins as sustained-release carriers for natural wood preservatives. Ind Crops Prod 130:42–48. https://doi.org/10.1016/j.indcrop.2018.12.061
Cai L, Lim H, Kim Y et al (2020) β-Cyclodextrin-allyl isothiocyanate complex as a natural preservative for strand-based wood composites. Compos Part B: Eng 193:108037. https://doi.org/10.1016/j.compositesb.2020.108037
Can A, Erkan G, Duran H et al (2021) Microencapsulated di-ammonium hydrogen phosphate (DAHP) with a polyurethane shell: characterization and its properties in wood. Eur J Wood Prod 79(6):1405–1417. https://doi.org/10.1007/s00107-021-01717-y
Cao L, Liu Y, Xu C et al (2019) Biodegradable poly (3-hydroxybutyrate-co-4-hydroxybutyrate) microcapsules for controlled release of trifluralin with improved photostability and herbicidal activity. Mater Sci Engineering: C 102:134–141. https://doi.org/10.1016/j.msec.2019.04.050
Currie RB, Kanji B, Bruce A et al (2021) Use of LA-ICP-MS for determination of elemental concentrations of boron in preservative treated solid wood and engineered wood panels. Holzforschung 75(2):195–198. https://doi.org/10.1515/hf-2020-0008
Dai X, Qi Y, Luo H et al (2022) Leachability and Anti-mold Efficiency of Nanosilver on Poplar Wood Surface. Polymers 14(5):884. https://doi.org/10.3390/polym14050884
Evans PD, Haase JG, Seman A S B, M et al (2015) The search for durable exterior clear coatings for wood. Coatings 5(4):830–864. https://doi.org/10.3390/coatings5040830
Forsskåhl I, Janson J (1992) Sequential treatment of mechanical and chemimechanical pulps with light and heat. Nord Pulp Pap Res J 7(2):48–54. https://doi.org/10.3183/npprj-1992-07-02-p048-054
Gao Y, Xiao Y, Mao K et al (2020) Thermoresponsive polymer-encapsulated hollow mesoporous silica nanoparticles and their application in insecticide delivery. Chem Eng J 383:123169. https://doi.org/10.1016/j.cej.2019.123169
General Administration of Quality Supervision (2013) Inspection and Quarantin of the people’s Republic of China, Standardization Administration of the People’s Republic of China. Test method for anti-mildew agents in controlling wood mould and stain fungi: GB/T 18261–2013 [S]. Standards Press of China, Beijing
Guo H, Fuchs P, Cabane E et al (2016) UV-protection of wood surfaces by controlled morphology fine-tuning of ZnO nanostructures. Holzforschung 70(8):699–708. https://doi.org/10.1515/hf-2015-0185
Hashim A, Hamad Z (2020) Lower cost and higher UV-absorption of polyvinyl alcohol/silica nanocomposites for potential applications. Egypt J Chem 63(2):461–470. https://doi.org/10.21608/EJCHEM.2019.7264.1593
Hernandez VA, Evans PD (2015) Melanization of the wood-staining fungus aureobasidium pullulans in response to UV radiation. Wood Fiber Sci 47(1):120–124
Hodgson JL, Coote ML (2010) Clarifying the mechanism of the Denisov cycle: how do hindered amine light stabilizers protect polymer coatings from photo-oxidative degradation? Macromolecules 43(10):4573–4583. https://doi.org/10.1021/ma100453d
Hon DNS, Chang ST (1984) Surface degradation of wood by ultraviolet light[J]. J Polym Science: Polym Chem Ed 22(9):2227–2241
Hon DNS, Shiraishi N (2000) Wood and cellulosic chemistry, revised, and expanded. CRC press, Boca Raton
Huang X, Kocaefe D, Kocaefe Y et al (2013) Structural analysis of heat-treated birch (Betule papyrifera) surface during artificial weathering. Appl Surf Sci 264:117–127. https://doi.org/10.1016/j.apsusc.2012.09.137
Kanbayashi T, Kataoka Y, Ishikawa A, Matsunaga M, Kobayashi M, Kiguchi M (2018) Confocal raman microscopy reveals changes in chemical composition of wood surfaces exposed to artificial weathering. J Photochem Photobiol B Biol 187:136–140. https://doi.org/10.1016/j.jphotobiol.2018.08.016
Kataoka Y, Kiguchi M, Williams RS et al (2007) Violet light causes photodegradation of wood beyond the zone affected by ultraviolet radiation. Holzforschung 61(1):23–27. https://doi.org/10.1515/HF.2007.005
Kr´anitz K, Sonderegger W, Bues CT, Niemz P (2016) Effects of aging on wood: a literature review. Wood Sci Technol 50(1):7–22. https://doi.org/10.1007/s00226-015-0766-0
Lebow S, Lebow P, Halverson S (2010) Penetration of boron from topically applied borate solutions. For Prod J 60(1):13–22. https://doi.org/10.13073/0015-7473-60.1.13
Li J (2003) Wood Spectroscopy. Science Press, Beijing
Li XW, Li JN, L M et al (2015) Effects of iodopropargyl carbamate (IPBC) on blue stain and mould in rubber wood. China Wood Industry 29(02):42–45. https://doi.org/10.19455/j.mcgy.2015.02.010
Li Jiaqi X, Guoqi Q, Shaoshan (2022) Preparation of nano-SiO2-IPBC microcapsule and its application in mildew resistance of Hevea brasiliensis. Jourmal of Beijing Forestry University 44(11):122–131. https://doi.org/10.12171/j.1000-1522.20220229
Liu L, Xu G (2019) Preparation and stability of microcapsule wood preservative from neem extract. BioResources 14(2):3352–3363. https://doi.org/10.15376/biores.14.2.3352-33663
Liu Y, Yan L, Heiden P et al (2001) Use of nanoparticles for controlled release of biocides in solid wood. J Appl Polym Sci 79(3):458–465. https://doi.org/10.1002/1097-4628(20010118)79:3%458::AID-APP80%3.0.CO;2-H
Liu M, Zhong H, Ma E et al (2018) Resistance to fungal decay of paraffin wax emulsion/copper azole compound system treated wood. Int Biodeterior Biodegrad 129:61–66. https://doi.org/10.1016/j.ibiod.2018.01.005
Liu MG, Liu Y, Zhao R (2021) Preparation, characterization and release behavior of isothiazolinone microcapsules. Polym Mater Sci Eng 37(02):49–53
MacLeod IT, Scully AD, Ghiggino KP et al (1995) Photodegradation at the wood-clearcoat interface. Wood Sci Technol 29(3):183–189. https://doi.org/10.1007/BF00204584
Manzano M, Vallet-Regí M (2020) Mesoporous silica nanoparticles for drug delivery. Adv Funct Mater 30(2):1902634. https://doi.org/10.1002/adfm.201902634
Müller U, Rätzsch M, Schwanninger M et al (2003) Yellowing and IR-changes of spruce wood as result of UV-irradiation. J Photochem Photobiol B 69(2):97–105. https://doi.org/10.1016/S1011-1344(02)00412-8
Nazir MT, Phung BT (2018) Accelerated ultraviolet weathering investigation on micro-/nano‐SiO2 filled silicone rubber composites. High Voltage 3(4):295–302. https://doi.org/10.1049/hve.2018.5004
Németh K, Faix O (1994) Beobachtung der Photodegradation des Holzes durch quantitative DRIFT-Spektroskopie. (Monitoring of the photodegradation of wood by quantitative DRIFT spectroscopy). Holz Roh- Werkstf 52(4):261–266. https://doi.org/10.1007/BF02619106
Pánek M, Reinprecht L (2014) Colour stability and surface defects of naturally aged wood treated with transparent paints for exterior constructions. Wood Res 59(3):421–430
Peng Y, Wang Y, Zhang R et al (2021) Improvement of wood against UV weathering and decay by using plant origin substances: tannin acid and Tung oil. Ind Crops Prod 168:113606. https://doi.org/10.1016/j.indcrop.2021.113606
Rosu D, Teaca CA, Bodirlau R et al (2010) FTIR and color change of the modified wood as a result of artificial light irradiation. J Photochem Photobiol B 99(3):144–149. https://doi.org/10.1016/j.jphotobiol.2010.03.010
Sanchez CL, Souders IICL, Pena-Delgado CJ et al (2020) Neurotoxicity assessment of triazole fungicides on mitochondrial oxidative respiration and lipids in differentiated human SH-SY5Y neuroblastoma cells. Neurotoxicology 80:76–86. https://doi.org/10.1016/j.neuro.2020.06.009
Shao P, Xuan S, Wu W, Qu L (2019) Encapsulation efficiency and controlled release of Ganoderma Lucidum polysaccharide microcapsules by spray drying using different combinations of wall materials. Int J Biol Macromol 125:962–969. https://doi.org/10.1016/j.ijbiomac.2018.12.153
Sun JH, Shan Z, Maschmeyer T et al (2003) Synthesis of bimodal nanostructured silicas with independently controlled small and large mesopore sizes. Langmuir 19(20):8395–8402. https://doi.org/10.1021/la0351156
Temiz A, Terziev N, Eikenes M et al (2007) Effect of accelerated weathering on surface chemistry of modified wood. Appl Surf Sci 253(12):5355–5362. https://doi.org/10.1016/j.apsusc.2006.12.005
Tolvaj L, Faix O (1995) Artificial Ageing of Wood monitored by DRIFT spectroscopy and CIE L*a*b* color measurements. 1. Effect of UV Light 49(5):397–404. https://doi.org/10.1515/hfsg.1995.49.5.397
Tolvaj L, Mitsui K (2005) Light source dependence of the photodegradation of wood. J wood Sci 51:468–473. https://doi.org/10.1007/s10086-004-0693-4
Wang Y, Wu X, Wang Y et al (2021) Hydrophobic and UV-resistant properties of environmentally friendly nano-ZnO-coated wood. Holzforschung 75(2):138–147. https://doi.org/10.1515/hf-2019-0312
Wu Z, Deng X, Luo Z et al (2021) Improvements in Fire resistance, decay resistance, anti-mold property and bonding performance in plywood treated with manganese chloride, phosphoric acid, boric acid and ammonium chloride. Coatings 11(4):399. https://doi.org/10.3390/coatings11040399
Xie Y, Krause A, Mai C et al (2005) Weathering of wood modified with the N-methylol compound 1, 3-dimethylol-4, 5-dihydroxyethyleneurea. Polym Degrad Stab 89(2):189–199. https://doi.org/10.1016/j.polymdegradstab.2004.08.017
Yalcin M, Pelit H, Akcay C, Cakicier N (2017) Surface properties of tannin-impregnated and varnished beech wood after exposure to accelerated weathering. Color Technol 133(4):334–340. https://doi.org/10.1111/cote.12287
Yu L, Cao J, Gao W et al (2011) Evaluation of ACQ-D treated Chinese fir and Mongolian scots pine with different post-treatments after 20 months of exposure. Int Biodeterior Biodegrad 65(4):585–590. https://doi.org/10.1016/j.ibiod.2011.03.001
Zayat M, Garcia-Parejo P, Levy D (2007) Preventing UV-light damage of light sensitive materials using a highly protective UV-absorbing coating. Chem Soc Rev 36(8):1270–1281. https://doi.org/10.1039/B608888K
Zhang J, Kamdem DP, Temiz A (2009) Weathering of copper–amine treated wood. Appl Surf Sci 256(3):842–846. https://doi.org/10.1016/j.apsusc.2009.08.071
Zhang R, Li Y, He Y et al (2020) Preparation of iodopropynyl butycarbamate loaded halloysite and its anti-mildew activity. J Mater Res Technol 9(5):10148–10156. https://doi.org/10.1016/j.jmrt.2020.07.019
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The authors would like to acknowledge funding from the National Natural Science Foundation of China (grant No.31500470) and Natural Science Foundation of Heilongjiang Province, China (grant No.C2016014).
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Jiaqi Li was responsible for data curation and writing original draft, Shaoshan Qin was responsible for supervision and editing, Guoqi Xu was responsible for conceptualization, funding acquisition, resources, supervision, and review & editing. All authors reviewed the manuscript.
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Li, J., Xu, G. & Qin, S. Application of nano SiO2-IPBC microcapsules in the anti-mildew and UV-resistance of rubberwood. Eur. J. Wood Prod. 82, 515–528 (2024). https://doi.org/10.1007/s00107-023-02008-4
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DOI: https://doi.org/10.1007/s00107-023-02008-4