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Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon

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Abstract

Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb2+ > Cu2+ > Ni2+. Langmuir model had higher R2 values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.

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References

  • Abdel Ghani, N.; Elchaghaby, G. A., (2007). Influence of operating conditions on the removal of Cu, Zn, Cd and Pb ions from wastewater by adsorption., Int. J. Environ. Sci. Tech., 4(4), 451–456 (6 pages).

    Article  Google Scholar 

  • Abdel-Ghani, N. T.; Hegazy, A. K.; El-Chaghaby, G. A., (2009). Typha domingensis leaf powder for decontamination of aluminium, iron, zinc and lead: Biosorption kinetics and equilibrium modeling. Int. J. Environ. Sci. Tech., 6(2), 243–248 (6 pages).

    CAS  Google Scholar 

  • Acharya, J.; Sahu, J. N.; Mohanty, C. R.; Meikap, B. C., (2009). Removal of lead (II) from wastewater by activated carbon developed from Tamarind wood by zinc chloride activation. Chem. Eng. J., 149(1–3), 249–262 (14 pages).

    Article  CAS  Google Scholar 

  • Allen, S.J.; Whitten, L. J.; Murray, M. and Duggan, O., (1997). The adsorption of pollutants by mpeat, lignite and activated chars. J. Chem. Tech. Biotech., 68(4), 442–452 (11 pages).

    Article  CAS  Google Scholar 

  • Aziz, H. A.; Yusoff, M. S.; Adlan, M. N.; Adnan, N. H.; Alias, S., (2004). Physico-chemical removal of iron from semi-aerobic landfill leachate by limestone filter. Waste Manag., 24(4), 353–358 (6 pages).

    Article  CAS  Google Scholar 

  • Babel, S.; Kurniawan, T. A., (2004). Cr (VI) removal from synthetic wastewater using coconut shell charcoal and commercial activated carbon modified with oxidizing agents and/or chitosan. Chemosphere, 54(7), 951–967 (17 pages).

    Article  CAS  Google Scholar 

  • Bansal, R. C.; Goyal, M., (2005). Activated carbon adsorption. London, Taylor and Francis Group, 351–353.

    Book  Google Scholar 

  • Bishop, P.L. (2004). Pollution prevention: Fundamentals and practice, Waveland Press Inc.

  • Bong, K. P.; Seung, H. S.; Young, J. Y., (2004). Selective biosorption of mixed heavy metal ions using polysaccharides. Korean J. Chem. Eng., 21(6), 1168–1172 (5 pages).

    Article  Google Scholar 

  • Chantawong,V.; Harvey, N. W.; Bashkin, V. N., (2003). Comparison of heavy metals adsorption by Thai Kaolin and Ballclay. Water, Air, Soil Pollut., 148 (1–4), 111–125 (15 pages).

  • Corapcioglu, M. O.; Huang, C. P., (1987). The adsorption of heavy metals onto hydrous activated carbon. Water Res., 21(9), 1031–1044 (14 pages).

    Article  CAS  Google Scholar 

  • Dakiky, M.; Khamis, M.; Manassra, A.; Mer’eb, M., (2002). Selective adsorption of chromium (VI) in industrial wastewater using low-cost abundantly available adsorbents. Adv. Environ. Res., 6(4), 533–540 (8 pages).

    Article  CAS  Google Scholar 

  • Department of Environment-DOE (1979)., Environmental Quality (Sewage and industrial effluents) Regulations 1978, In: Environmental Quality Act 1974. E-publishing Lawnet, Malaysia.

  • Edwin, V. A., (2008). Surface Modification of Activated Carbon for enhancement of Nickel (II) adsorption. E-J. Chem., 5(4), 814–819 (6 pages).

    Google Scholar 

  • Freundlich, H.; Hatfield, H., (1926). Colloid and Capillary Chemistry. Methuen and Co. Ltd., London.

    Google Scholar 

  • Garg, V.K.; Gupta, R.; Yadav, A. B.; Kumar, R. D., (2003). Dye removal from aqueous solution by adsorption on treated sawdust. Bioresour. Tech., 89(2), 121–124 (4 pages).

    Article  CAS  Google Scholar 

  • Georg Steinhauser, M. B., (2008). Adsorption of ions onto high silica volcanic glass. Appl. Rad. Iso., 66(1), 1–8 (8 pages).

    Article  Google Scholar 

  • Goel, J.; Krishna, K.; Chira, R.; Vinod, K., (2005). Removal of lead (II) by adsorption using treated granular activated carbon and column studies. J. Hazard. Mater., B125, 211–220 (10 pages).

    Article  Google Scholar 

  • Gueu, S.; Yao, B.; Adouby, K.; Ado, G., (2007). Kinetics and thermodynamics study of lead adsorption on to activated carbons from coconut and seed hull of the palm tree. Int. J. Environ. Sci. Tech., 4(1), 11–17 (7 pages).

    Article  CAS  Google Scholar 

  • Horsfall, M.; Abia, A., (2003). Sorption of C(II) and Zn(II) ions from aqueous solutions by cassava waste biomass. Water Res., 37(20), 4913–4923 (11 pages).

    Article  CAS  Google Scholar 

  • Huang, C. P.; Morehart, A. L., (1991). Proton competition in Cu(II) adsorption in fungal Mycellia. Water Res., 25(11), 1365–1375 (11 pages).

    Article  CAS  Google Scholar 

  • Igbinosa, E. O.; Okoh, A. I., (2009). Impact of discharge wastewater effluents on the physico-chemical qualities of a receiving watershed in a typical rural community. Int. J. Environ. Sci. Tech., 6(2), 175–182 (8 pages).

    CAS  Google Scholar 

  • Igwe, J. C.; Abia, A. A.; Ibeh, C. A., (2007). Adsorption kinetic and intraparticulate diffusivities of Hg, As and Pb ions on unmodified and thiolated coconut fiber. Int. J. Environ. Sci. Tech., 5(1), 83–92 (10 pages).

    Article  Google Scholar 

  • Issabayeva, G.; Aroua, M. K.; Sulaiman, N. M., (2007). Continuous adsorption of lead ions in a column packed with palm shell activated carbon. J. Hazard. Mater., 155(1–2), 109–113 (5 pages).

    Google Scholar 

  • Karbassi, A. R.; Nouri, J.; Ayaz, G. O., (2007). Flocculation of trace metals during mixing of Talar river water with Caspian Seawater. Int. J. Environ. Res., 1(1), 66–73 (8 pages).

    CAS  Google Scholar 

  • Langmuir, I., (1918). The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc., 40(8), 1361–1403 (43 pages).

    Article  CAS  Google Scholar 

  • Mahvi, A.H., (2008). Application of agricutural fibers in pollution removal from aqueous solution. Int. J. Environ. Sci. Tech., 5(2), 275–285 (11 pages).

    Article  CAS  Google Scholar 

  • Malakootian, M.; Almasi, A.; Hossaini, H., (2009). Pb and Co removal from paint industries effluent using wood ash. Int. J. Environ. Sci. Tech., 5(2), 217–222 (6 pages).

    Article  Google Scholar 

  • Metcalf and Eddy (2003). Wastewater Engineering: Treatment and Reuse. In: McGraw Hill series in civil and environmental engineering, 4th. Ed. (pp. 1149 and 1819)., McGraw-Hill, New York.

    Google Scholar 

  • Mondal, P.; Majumder C. B.; Mohanty, B. ( 2008). Effects of adsorbent dose, its particle size and initial arsenic concentration on the removal of arsenic, iron and manganese from simulated ground water by Fe3+ impregnated activated carbon. J. Hazard. Mater., 150(3), 695–702 (8 pages).

    Article  CAS  Google Scholar 

  • Najua, D. T.; Luqman, C. A.; Zawani, Z.; Suraya, A. R. (2008). Adsorption of copper from aqueous solution by Elais Guineensis kernel activated carbon., J. Eng. Sci. Tech., 3(2), 180–189 (10 pages).

    Google Scholar 

  • Pons, M. P.; Fuste, C. M., (1993). Uranium uptake by immobilized cells of Pseudomonas strain EPS 5028. Appl. Microbio. Biotech., 39(4–5), 661–665 (5 pages).

    Article  CAS  Google Scholar 

  • Resmi, G.; Thampi, S. G.; Chandrakaran, S., (2010). Brevundimonas vesicularis check for this species in other resources: A novel bio-sorbent for removal of lead from wastewater. Int. J. Environ. Res., 4(2), 281–288 (7 pages).

    CAS  Google Scholar 

  • Shetty, R.; Rajkumar, Sh., (2009). Biosorption of Cu (II) by metal resistant Pseudomonas check for this species in other resources sp. Int. J. Environ. Res., 3(1), 121–128 (8 pages).

    CAS  Google Scholar 

  • Skinner, J. H.; Bassin, N. J. (1 988). The environmental protection agency’s hazardouswaste research and development program., J. APCA.

  • Standard Methods (2000). Standard Methods for the Examination of Water and Wastewater, In: Metals, 3500.

  • Ulmanu, M.; Maranon, E.; Fernandez, Y.; Castrillon, L.; Anger, L.; Dumitriu, D., (2003). Removal of copper and cadmium ions from diluted aqueous solutions by low cost and waste material adsorbents. Water, Air, Soil Pollut., 142(1–4), 357–373 (17 pages).

    Article  CAS  Google Scholar 

  • Uzun, I.; Guzel, F. (2000). Adsorption of some heavy metal ions from aqueous solution by activated carbon and comparison of percentage adsorption results of activated carbon with those of some other adsorbents. Turk. J. Chem. 24, 291–297 (7 pages).

    CAS  Google Scholar 

  • Zhang, J.; Huang, Z.; Ruitao, L.; Yang, Q. and Kang, F., (2009). Effect of growing CNTs onto Bamboo charcoals on adsorption of copper ions in aqueous solution. Langmuir, 25(1), 269–274 (6 pages).

    Article  Google Scholar 

  • Zvinowanda, C. M.; Okonkwo, J. O.; Shabalala, P. N.; Agyei, N. M., (2009). A novel adsorbent for heavy metal remediation in aqueous environments. Int. J. Environ. Sci. Tech., 6(3), 425–434 (10 pages).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Bioenvironmental Engineering Research Unit (BERU), Department of Biotechnology Engineering, Faculty of Engineering, International Islamic University Malaysia, Gombak, 50728, Kuala Lumpur, Malaysia

    Y. B. Onundi M.Sc., A. A. Mamun Ph.D., M. F. Al Khatib Ph.D. & Y. M. Ahmed M.Sc.

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  1. Y. B. Onundi M.Sc.
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  2. A. A. Mamun Ph.D.
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  3. M. F. Al Khatib Ph.D.
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  4. Y. M. Ahmed M.Sc.
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Correspondence to A. A. Mamun Ph.D..

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Onundi, Y.B., Mamun, A.A., Khatib, M.F.A. et al. Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon. Int. J. Environ. Sci. Technol. 7, 751–758 (2010). https://doi.org/10.1007/BF03326184

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