Abstract
A functionalized cyclotriphosphazene with four pyrazolyl substituents, N3P3(MeNC2H4O)(dmp)4 where dmp = 3,5-dimethylpyrazole, has been synthesized and characterized. The reaction of this potentially multi-site coordinating cyclotriphosphazene with diorganotin(IV) dichlorides, SnR2Cl2 (R = Ph, Me), leads to dinuclear [(SnPh2Cl2)2{N3P3(MeNC2H4O)(dmp)4}] (1) and mononuclear [(SnMe2Cl2){N3P3(MeNC2H4O)(dmp)4}] (2) complexes. These new compounds were characterized by elemental analysis and IR, 1H, 31P and 119Sn NMR spectroscopy. On the basis of these data, in the complex 1 pyrazolylcyclotriphosphazene acts as a bis-bidentate ligand and coordinates to two SnPh2Cl2 molecules via two geminal pyrazolyl nitrogen atoms. As for complex 2, coordination to one SnMe2Cl2 molecule occurs through two nongeminally substituted pyrazolyl nitrogens. The 119Sn NMR data are consistent with the increasing of coordination number of tin(IV) in solution.
Similar content being viewed by others
References
M. Gleria, R.D. Jaeger, Applicative Aspects of Cyclophosphazenes, Nova Science Publishers Inc., New York, 2004.
V. Chandrasekhar, Inorganic and Organometallic Polymers, Springer-Verlag, Heidelberg, Germany, 2005.
J.E. Mark, H.R. Allcock, R. West, Inorganic Polymers, 2nd ed., Oxford University Press, New York, 2005.
V. Chandrasekhar, S. Nagendran, Chem. Soc. Rev. 30 (2001) 193.
V. Chandrasekhar, P. Thilagar, B.M. Pandian, Coord. Chem. Rev. 251 (2007) 1045.
J.Y. Yu, Y.J. Jun, S.H.J. Lee, Y.S. Sohn, J. Inorg. Biochem. 101 (2007) 1931.
M. Harmjanz, I.M. Piglosiewicz, B.L. Scott, C.J. Burns, Inorg. Chem. 43 (2004) 642.
E.W. Ainscough, A.M. Brodie, C.V. Depree, C.A. Otter, Polyhedron 25 (2006) 2341.
M. Gall, M. Breza, Polyhedron 28 (2009) 521.
Gleria, R.D. Jaeger, Phosphazenes: A Worldwide Insight, Nova Science Publishers Inc., New York, 2004.
P.I. Richards, A. Steiner, Inorg. Chem. 43 (2004) 2810.
Y. Cho, H. Baek, Y.S, Sohn, Macromolecules 32 (1999) 2167.
E.W. Ainscough, A.M. Brodie, J. Davidson, C.A. Otter, Inorg. Chem. Commun. 11 (2008) 171.
R. Frech, S. York, H. Allcock, C. Kellam, Macromolecules 37 (2004) 8699.
S.C. Song, S.B. Lee, B.H. Lee, H.W. Ha, K.T. Lee, Y.S. Sohn, J. Controlled Release 90 (2003) 303.
M.S. Papkov, K. Agashi, A. Olaye, K. Shakesheff, A.J. Domb, Adv. Drug Delivery Rev. 59 (2007) 187.
T. Sedaghat, A. Tarassoli, A. Mojaddami, J. Coord. Chem. 62 (2009) 840.
S. Shahzadi, S. Ali, J. Iran. Chem. Soc. 5 (2008) 16.
A. Tarassoli, T. Sedaghat, in: R.P. Irwin (Ed.), Organometallic Chemistry Research Perspectives, Nova Science Publishers Inc., New York, Chap. 7, 2007.
S. Tabassum, C. Pettinari, J. Organomet. Chem. 691 (2006) 1761.
Y. Arakawa, in: P.J. Smith (Ed.), Chemistry of Tin, 2nd ed., Blackie, London, Chap. 10, 1998.
S.K. Hadjikakou, N. Hadjiliadis, Coord. Chem. Rev. 253 (2009) 235.
V. Chandrasekhar, S.S. Krishnamurthy, H. Manohar, A.R. Vasudeva Murthy, R.A. Shaw, M. Woods, J. Chem. Soc., Dalton Trans. (1984) 621.
K.D. Gallicano, N.L. Paddock, Can. J. Chem. 60 (1982) 521.
K.R.J. Thomas, V. Chandrasekhar, P. Pal, S.R. Scott, R. Hallford, A.W. Cordes, Inorg. Chem. 32 (1993) 606.
A.G. Davies, Organotin Chemistry, 2nd ed., WILEYVCH: Weinheim, 2004.
T.P. Lockhart, W.F. Manders, Inorg. Chem. 25 (1986) 892.
V. Chandrasekhar, B.M. Pandian, R. Azhakar, Inorg. Chem. 45 (2006) 3510.
M. Harmjanz, I.M. Piglosiewicz, B.L. Scott, C.J. Burns, Inorg. Chem. 43 (2004) 642.
A. Chandrasekharan, S.S. Krishnamurthy, M. Nethaji, Inorg. Chem. 32 (1993) 6102.
J. Otera, J. Organomet. Chem. 221 (1981) 57.
J. Otera, A. Kusaba, T. Hinoishi, Y. Kawasaki, J. Organomet. Chem. 228 (1982) 223.
C. Pettinarri, A. Lorenzotti, G. Sclavi, A. Cingolani, E. Rivarola, M. Colapietro, A. Cassetta, J. Organomet. Chem. 496 (1995) 69.
J.S. Casas, E.E. Castellano, F.J.G. Barros, A. Sanchez, A.S. Gonzalez, J. Sordo, J.Z. Schpector, J. Organomet. Chem. 519 (1996) 209.
G.G. Lobbia, G. Valle, S. Calogero, P. Cecchi, C. Santini, F. Marchetti, J. Chem. Soc., Dalton Trans. (1996) 2475.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sedaghat, T., Tarassoli, A. & Mojaddami, A. New organotin(IV) complexes with a potentially multi-site ligand based on the cyclotriphosphazene platform: Synthesis and spectral studies. JICS 7, 371–375 (2010). https://doi.org/10.1007/BF03246022
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF03246022