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Ombrotrophic peat as a medium for historical monitoring of heavy metal pollution

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Abstract

Knowledge of historical trends in heavy metal deposition can aid the study and impact prediction of contemporary pollution. For this purpose, analysis of ombrotrophic peat cores has proved a valuable complement to other sedimentary analyses. However, doubts still remain concerning the mobility of heavy metals in peat. The debate cannot be resolved until the behaviour of these elements in peat is better understood.

Peat cores were collected from hollows and hummocks on Ringinglow Bog in the southern Pennines. The cores were sliced into contiguous 1-cm slices. Samples were analysed for total concentrations of major elements (Al, Ca, K, Mg, Na) and trace metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb, Zn) using atomic absorption spectrophotometry. Multivariate statistical analysis was conducted on the data.

Preliminary results indicate relatively high concentrations of Cd, Cu, Fe, Pb and Zn reflecting the influence of industrial activities in Sheffield and Manchester. As aluminium, cadmium, copper, lead and zinc exhibit similar profiles they may be suitable surrogates for monitoring historical pollution. However, other elements (e.g. Fe, K, Mn, Na) are clearly influenced by bog hydrology or plant translocation and would be inappropriate monitors.

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References

  • Beavington, F. 1977. Trace elements (Cu, Zn, Pb, Cd, Fe and Mn) in rainwater and dry deposition around a smelting complex.Environ. Pollut.,13, 127–131.

    Article  CAS  Google Scholar 

  • Bohlin, E., Hamalainen, M. and Sunden, T. 1989. Botanical and chemical characterisation of peat using multivariate methods.Soil Sci., 147, 252–263.

    Article  Google Scholar 

  • Clymo, R.S. 1988. A high-resolution sampler of surface peat.Func. Ecol.,2, 425–431.

    Article  Google Scholar 

  • Cole, K., Engstrom, D.R., Futyama, R.P. and Stottlemyer, R. 1990. Past atmospheric deposition of metals in Northern Indian measured in a peat core from Cowles Bog.Environ. Sci. Technol.,24, 543–549.

    Article  CAS  Google Scholar 

  • Coleman, D.O. 1985. Peat. In: MARC (ed.),Historical Monitoring. Technical Report No. 31, pp. 155–173. MARC, Chelsea College, London.

    Google Scholar 

  • Conway, V.M. 1947. Ringinglow Bog, near Sheffield. I. Historical.J. Ecol.,34, 149–181.

    Article  Google Scholar 

  • Davison, R.L., Natusch, D.F.S., Wallace, J.R. and Evans, C.A. 1974. Trace elements in fly ash: dependence of concentration on particle size.Environ. Sci. Technol., 8, 1107–1113.

    Article  CAS  Google Scholar 

  • Ferguson, P., Lee, J.A. and Bell, J.N.B. 1978. Effects of sulphur pollutants on the growth of Sphagnum species.Environ. Pollut., Ser.A.,21, 59–71.

    Google Scholar 

  • Hamalainen, M. and Albano, C. 1992. Principal variations in the chemical composition of peat: predictive peat scales based on multivariate strategies.J. Chemometrics,6, 41–56.

    Article  CAS  Google Scholar 

  • Jones, J.M. 1985. Heavy metals and magnetic minerals in ombrotrophic peat. PhD thesis, University of Liverpool.

  • Jones, J.M. 1987. Chemical fractionation of copper, lead and zinc in ombrotrophic peat.Environ. Pollut.,48, 131–144.

    Article  CAS  Google Scholar 

  • Joreskog, K.G., Klovan, J.E. and Reyment, R.A. 1976.Geological Factor Analysis. Elsevier Scientific Publishing Company.

  • Lee, J.A. and Tallis, J.H. 1973. Regional and historical aspects of lead pollution in Britain.Nature,245, 216–218.

    Article  CAS  Google Scholar 

  • Livett, E.A. 1988. Geochemical monitoring of atmospheric heavy metal pollution: theory and applications.Adv. Ecol. Res.,18, 65–173.

    Article  Google Scholar 

  • Livett, E.A., Lee, J.A. and Tallis, J.H. 1979. Lead, zinc and copper analyses of British blanket peats.J. Ecol.,67, 865–891.

    Article  CAS  Google Scholar 

  • Norton, S. 1990.Geochemistry of Selected Maine Peat Deposits. Bulletin 34. Maine Geological Survey.

  • Norton, S. and Kahl, J.S. 1987. A comparison of lake sediments and ombrotrophic peat deposits as long-term monitors of atmospheric pollution. In: Boyle, T.P. (ed.),New Approaches to Monitoring Aquatic Ecosystems, pp. 40–57. ASTM, Philadelphia.

    Google Scholar 

  • Schell, W.R., Tobin, M.J. and Massey, C.D. 1989. Evaluation of trace metal deposition history and potential element mobility in selected cores from peat and wetland ecosystems.Sci. Total Environ.,87/88, 19–42.

    Article  Google Scholar 

  • Shotyk, W., Nesbitt, H.W. and Fyfe, W.S. 1990. The behaviour of major and trace elements in complete vertical peat profiles from three Sphagnum bogs. Int. J. Coal Geol., 15, 163–190.

    Article  CAS  Google Scholar 

  • Shotyk, W., Nesbitt, H.W. and Fyfe, W.S. 1992. Natural and anthropogenic enrichments of trace metals in peat profiles.Int. J. Coal Geol.,20, 49–84.

    Article  CAS  Google Scholar 

  • Urban, N.R., Eisenreich, S.J., Grigal, D.F. and Schurr, K.T. 1990. Mobility and diagenesis of Pb and210Pb in peat.Geochim. Cosmochim. Acta,54, 3329–3346.

    Article  CAS  Google Scholar 

  • Van Craen, M.J., Denoyer, E.A., Natusch, D.F.S. and Adams, F. 1983. Surface enrichment of trace elements in electric steel furnace dust.Environ. Sci. Technol.,17, 435–43

    Article  Google Scholar 

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Jones, J.M., Hao, J. Ombrotrophic peat as a medium for historical monitoring of heavy metal pollution. Environ Geochem Health 15, 67–74 (1993). https://doi.org/10.1007/BF02627824

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