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Aquadimethylsulfoxide complexes of rare earth elements Pr, Eu, and Tm with the [Mo3S7Br7]3− cluster anion

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Abstract

New complexes of rare earth elements [Ln(DMSO)m(H2O)n][Mo3S7Br7], Ln=Pr, Eu, Tm were synthesized and investigated by X-ray diffraction analysis. In [Pr(DMSO)6(H2O)2]3+ and [Eu(DMSO)7(H2O)]3+, the coordination polyhedra of Ln are distorted, square antiprisms (coordination number is 8); in [Tm(DMSO)6(H2O)]3+, the coordination polyhedron of Ln is a distorted pentagonal bipyramid (coordination number is 7). In all complexes, DMSO is coordinated via oxygen atoms.

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Authors
  1. V. E. Fedorov
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  2. O. A. Gerasko
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  3. Yu. V. Mironov
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  4. K. Hegetschweiler
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  5. R. Stoop
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  6. J. Gallus
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  7. F. Gramlich
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Additional information

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Swiss Technological Institute, Zurich, Switzerland. Translated fromZhurnal Strukturnoi Khimii, Vol. 36, No. 6, pp. 1046–1069, November–December, 1995.

Translated by L. Smolina

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Fedorov, V.E., Gerasko, O.A., Mironov, Y.V. et al. Aquadimethylsulfoxide complexes of rare earth elements Pr, Eu, and Tm with the [Mo3S7Br7]3− cluster anion. J Struct Chem 36, 956–978 (1995). https://doi.org/10.1007/BF02578554

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  • DOI: https://doi.org/10.1007/BF02578554

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