Skip to main content
SpringerLink
Log in

Kinetic and analytical study on precipitation reactions with110AgNO3 of some di (β-chloroethyl) amine derivates and hydrochlorides with esters of N-(p-aminobenzoyl)-L-aspartic acid as carriers from dimethylformamide-water solution

  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

The kinetics of precipitation reactions with110AgNO3 of some di (β-chlorethyl) amine derivates and hydrochlorides with esters of N-(p-aminobenzoyl)-L-aspartic acid as carriers in dimethylformamide-water mixture, were studied. The rate constants of these reactions were of the order of 10−4 1 · mol−1 · min−1. The concentrations of the corresponding hydrochloride solutions were measured by radiometric titration with110AgNO3 solution of given concentration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. HAISSINSKY, La chime nucléaire et ses applications, Masson et Cie editeurs, Paris, 1957.

    Google Scholar 

  2. S. ARONOFF, Techniques of Radiobiochemistry, The Iowa State College Press, Iowa, 1958.

    Google Scholar 

  3. M. B. NEIMAN, D. GÁL, The Kinetick Isotope Method and its Application, Akadémiai Kiadó, Budapest, 1971.

    Google Scholar 

  4. F. DUTKA, D. GÁL, Intern. J. Appl. Radiation Isotopes, 13 (1962) 27.

    Article  Google Scholar 

  5. F. DUTKA, D. GÁL, Intern. J. Appl. Radiation Isotopes, 13 (1962) 35.

    Article  Google Scholar 

  6. D. GÁL, L. GUCZI, in Radioisotopes in the Physical Science and Industry, IAEA, Vienna, 1962.

    Google Scholar 

  7. I. P. SKIBIDA, Z. K. MAIZUS, N. M. EMANUEL, Dokl. Akad. Nauk SSSR, 146 (1962) 170.

    Google Scholar 

  8. I. P. SKIBIDA, Z. I. KULITSKI, Z. K. MAIZUS, Dokl. Akad. Nauk SSSR, 148 (1963) 1358.

    CAS  Google Scholar 

  9. I. P. SKIBIDA, E. M. GONIKBERG, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk. (1964) 286.

  10. A. LANGER, J. Phys. Chem., 45 (1941) 639.

    Article  CAS  Google Scholar 

  11. L. HERFORTH, H. KOCH, Radiophysikalisches und radiochemisches Grundprakticum, VEB Deutscher Verlag der Wissenschaften, Berlin, 1962.

    Google Scholar 

  12. J. TÖLGYESSY, V. JESENAK, T. BRAUN, Radiochemical Methods of Analysis, IAEA, Vienna, 1965.

    Google Scholar 

  13. T. BRAUN, J. TÖLGYESSY, Radiometric Titrations, Pergamon Press, Oxford, 1967.

    Google Scholar 

  14. T. NĂŞCUŢIU, Metode radiochimice de analiza, Editura Academiei RSR, Bucareşti, 1973.

    Google Scholar 

  15. K. KIMURA, F. KAMETANI, Japan Analyst, 10 (1961) 1293.

    CAS  Google Scholar 

  16. J. TÖLGYESSY, S. VARGA, Chem. Zvesti, 17 (1963) 779.

    Google Scholar 

  17. T. BRAUN, Chim. Anal., 46 (1964) 61.

    CAS  Google Scholar 

  18. T. BRAUN, I. MAXIM, I. GĂLĂŢÊANU, Zhur. Anal. Khim. 14 (1959) 542.

    CAS  Google Scholar 

  19. I. GĂLĂŢÊANU, Radiochimie aplicată, Editura Academiei RSR, Bucuresti, 1976.

    Google Scholar 

  20. I. M. KORENMAN, F. R. SEYANOVA, H. M. MEZINA, M. I.OSTASEVA, Zhur. Anal. Khim., 12 (1957) 48.

    CAS  Google Scholar 

  21. V. SUNEL, C. H. BUDEANU, I. MAZILU, M. AOSTOLESCU, Bul. Inst. Politehnic Iasi, 25 (1979) 85.

    CAS  Google Scholar 

  22. V. SUNEL, Al. CECAL, Rev. Chim., in print.

  23. V. SUNEL, M. APOSTOLESCU, C. H. BUDEANU, D. DĂNET, Rev. Chim., in print.

  24. I. G. MURGULESCU, E. SEGAL, T. OONCESCU, Introducere în Chimia Fizică, Vol. II, 2, Editura Academiei RSR, Bucuresti, 1981.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemical Technology, Polytechnic Institute of Iasi, Splai Bahlui-71, 6600, Iasi, (Romania)

    AL. Cecal, V. Sunel & L. Ghimiciu

Authors
  1. AL. Cecal
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Sunel
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. Ghimiciu
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cecal, A., Sunel, V. & Ghimiciu, L. Kinetic and analytical study on precipitation reactions with110AgNO3 of some di (β-chloroethyl) amine derivates and hydrochlorides with esters of N-(p-aminobenzoyl)-L-aspartic acid as carriers from dimethylformamide-water solution. J. Radioanal. Chem. 78, 247–253 (1983). https://doi.org/10.1007/BF02530435

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02530435

Keywords

Search

Navigation