Skip to main content
SpringerLink
Log in

Solvent extraction studies on cadmium

I. Extraction and separation of microamounts of cadmium halides in absence and presence of sulphuric acid

  • Published:
Journal of Radioanalytical Chemistry Aims and scope Submit manuscript

Abstract

An extraction study was performed on tracer concentrations of cadmium halides in absence and presence of sulphuric acid. Inert solvents, nitrobenzene, a long chain amine (Amberlite LA-2) and organophosphorus solvents (TBP and HDEHP) have been investigated. The comparative stability of cadmium chloride and bromide TBP solvates were determined. The presence of sulphuric acid was found to enhance considerably the extraction of cadmium halides by nitrobenzene, Amberlite LA-2 and TBP. The mechanism of extraction has been discussed in light of the obtained results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. ALIAN, W. SANAD, Radiochim. Acta, 17 (1972) 158.

    CAS  Google Scholar 

  2. A. ALIAN, A. HAGGAG, M. S. EL-BASSIOUNY, J. Inorg. Nucl. Chem., 36 (1974) 1629.

    Article  CAS  Google Scholar 

  3. A. ALIAN, W. SANAD, M. NOFAL, H. KHALIFA, J. Inorg. Nucl. Chem., 37 (1975) 297.

    Article  CAS  Google Scholar 

  4. A. ALIAN, A. HAGGAG, W. SANAD, J. Radioanal. Chem., 20 (1974) 559.

    Article  CAS  Google Scholar 

  5. P. MARKEL, I. MARKEL, F. HECHT, Mikrochim. Acta, 1 (1968) 1.

    Article  Google Scholar 

  6. J. R. KNAPP, R. E. VAN AMAN, J. H. KANZELMEYER, Anal. Chem., 34 (1962) 1374.

    Article  CAS  Google Scholar 

  7. H. A. C. MACKAY, Proc. 1st Conf. Peaceful Uses of Atomic Energy, Geneva, 1955, p. 441.

  8. J. M. SCHMITT, C. A. BLAKE Jr., USAEC Report ORNL 3548, Feb. 1964.

  9. L. J. BEUFAIT, Jr., H. R. LUKERS, Jr., U. S. Atomic Energy Commission, Report N. P. 5056, May 1953.

  10. G. GUNZLER, D. MAHL, J. Prakt. Chem., 23 (1964) 71.

    Article  Google Scholar 

  11. E. L. SHORT, D. N. WETERS, D. F. C. MORRIS, J. Inorg. Nucl. Chem., 26 (1964) 902.

    Article  CAS  Google Scholar 

  12. H. SPECKER, Z. Anal. Chem., 197 (1963) 109.

    Article  CAS  Google Scholar 

  13. D. F. C. MORRIS, E. L. SHORT, J. Chem. Soc., 2662 (1962).

  14. D. F. C. MORRIS, D. N. SLATER, J. Inorg. Nucl. Chem., 27 (1965) 250.

    Article  CAS  Google Scholar 

  15. D. F. C. MORRIS, E. L. SHORT, D. N. ELATER, Electrochem. Acta, 8 (1963) 289.

    Article  CAS  Google Scholar 

  16. L. MATUTANO, Report CEA-R 2760, Centre D'Etudes Nucléaires de Saclay, 1965.

  17. V. M. VDOVENKO, T. V. KOVALEVA, M. PYAZANOV, Radiokhimiya, 7 (1965) 133.

    CAS  Google Scholar 

  18. E. W. NADIG, M. SMUTZ, USAEC Report, IS-595, 1963.

  19. M. HALPERN, T. KIM, N. C. LI, J. Inorg. Nucl. Chem., 24 (1962) 1251.

    Article  CAS  Google Scholar 

  20. N. SAITO, A. YAMASAKI, Bull. Chem. Soc. Japan, 36 (1963) 1055.

    Article  Google Scholar 

  21. M. I. TOCHER, D. C. WHITNEY, R. M. DIAMOND, J. Phys. Chem., 68 (1964) 368.

    CAS  Google Scholar 

  22. R. ROBINSON, R. STOCKS, Electrolyte Solutions, London, 1959.

  23. R. DEVOE JAMES, USAEC Report, NAS-NS 3001, January 1960.

Download references

Author information

Authors and Affiliations

  1. Nuclear Chemistry Department, Atomic Energy Establishment, Cairo, Egypt

    A. Alian

  2. El-Nasr Company for Television, Cairo, Egypt

    A. El-Kot

  3. Chemistry Department, Faculty of Science, Cairo University, Cairo, Egypt

    A. Badran & M. S. El-Bassiouny

Authors
  1. A. Alian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. El-Kot
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Badran
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. S. El-Bassiouny
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

At present Humboldt-Fellow, Gesellschaft für Strahlen- und Umweltforschung mbH München, Institut für Strahlenschutz, D-8042 Neuherberg bei München, FRG.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Alian, A., El-Kot, A., Badran, A. et al. Solvent extraction studies on cadmium. J. Radioanal. Chem. 27, 383–399 (1975). https://doi.org/10.1007/BF02520577

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02520577

Keywords

Search

Navigation