Abstract
The coupling between the electronic angular momentum and the rotating atom-atom axis in the initial or the final phase of an atom-atom collision is discussed, making use of the concepts of radial and rotational (Coriolis) coupling between different molecular states. The description is based on a limited number of well-understood approximations, and it allows an illustrative geometric representation of the transition from the body fixed to the space fixed motion of the electrons.
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Blum, K., Kleinpoppen, H.: Phys. Rep.96, 251 (1983)
Andersen, N.: Phys. Scr. T6, 130 (1983)
Hertel, I.V., Schmidt, H., Bähring, A., Meyer, E.: Rep. Prog. Phys.48, 375 (1985)
Nikitin, E.E.: In: Atomic physics. Putlitz, G. zu, Weber, E.W., Winnacker, A. (eds.), Vol. 4, p. 529. New York, London: Plenum 1975
Lewis, E.L.: Phys. Rep.58, 1 (1980)
Baylis, W.E.: In: Progress in atomic spectroscopy B. Hanle, W., Kleinpoppen, H. (eds.), p. 1227. New York, London: Plenum 1979
Delos, J.B., Thorson, W.R.: J. Chem. Phys.70, 1774 (1979)
Child, M.S.: Molecular collision theory. London, New York: Academic Press 1974
Kronig, R. de L.: Band spectra and molecular structure. Cambridge: University Press 1930
Brink, D.M., Satchler, G.R.: Angular momentum. Oxford: Clarendon Press 1962
Brown, J.M., Hougen, J.T., Huber, K.-P., Johns, J.W.C., Kopp, I., Lefebvre-Brion, H., Merer, A.J., Ramsay, D.A., Kostas, J., Zare, R.N.: J. Mol. Spectrosc.55, 500 (1975)
Grosser, J., Vries, A.E. de: Chem. Phys.3, 180 (1974); Chem. Phys.10, 229 (1975)
Grosser, J.: Chem. Phys.30, 187 (1978)
Grosser, J.: J. Phys. B14, 1449 (1981)
Bähring, A., Hertel, I.V., Meyer, E., Schmidt, H.: Z. Phys. A — Atoms and Nuclei312, 293 (1983)
Abramowitz, M., Stegun, I.A.: Handbook of mathematical functions. New York: Dover Publications 1970
Szegö, G.: Orthogonal polynominals. American Mathematical Society Colloquium Publications 23, rev. Edn. New York: Providence 1975
Gel'fand, I.M., Minlos, R.A., Shapiro, Z.Ya.: Representations of the rotation and Lorentz groups and their applications. Oxford, New York, Paris: Pergamon Press 1963
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Grosser, J. Angular momentum coupling in atom-atom collisions. Z Phys D - Atoms, Molecules and Clusters 3, 39–58 (1986). https://doi.org/10.1007/BF01442346
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DOI: https://doi.org/10.1007/BF01442346