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Vinyl polymerization initiated by peroxydiphosphate

IX. Polymerization of acrylamide and methacrylamide by potassium peroxydiphosphate

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Abstract

The kinetics of aqueous polymerization of acrylamide and methacrylamide initiated by potassium peroxydiphosphate has been investigated. The kinetic orders with respect to peroxydiphosphate and monomer were close to 0.5 and 1 respectively. Overall activation energies were computed and a suitable kinetic scheme suggested. Comparison with kinetic studies of the analogous acrylamide polymerization by peroxydisulphate shed doubt on the cage effect interpretation of the complex order with respect to monomer.

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Author notes

  1. S. Lenka

    Present address: Laboratory of Polymers and Fibers, Department of Chemistry, Ravenshaw College, Cuttack, Orissa, India

Authors and Affiliations

  1. Laboratory of Polymers and Fibers, Department of Chemistry, Ravenshaw College, Cuttack, Orissa, India

    P. L. Nayak, S. B. Dash & S. Ray

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  1. S. Lenka
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  3. S. B. Dash
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  4. S. Ray
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Lenka, S., Nayak, P.L., Dash, S.B. et al. Vinyl polymerization initiated by peroxydiphosphate. Colloid & Polymer Sci 261, 40–44 (1983). https://doi.org/10.1007/BF01411515

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