Conclusions
It has been shown that the region of diamond thermodynamic stability depends on the dimensions of the carbon particles in small-particle systems. At the high supersaturation realized in vacuum condensation and chemical decomposition, there is an increase in the ratio of the probabilities for diamond and graphite nucleation.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1184–1188, June, 1979.
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Deryagin, B.V., Fedoseev, D.V. Phase transitions and nucleation in diamond and graphite. Russ Chem Bull 28, 1106–1109 (1979). https://doi.org/10.1007/BF00947364
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DOI: https://doi.org/10.1007/BF00947364