Skip to main content
Log in

Conclusions

It has been shown that the region of diamond thermodynamic stability depends on the dimensions of the carbon particles in small-particle systems. At the high supersaturation realized in vacuum condensation and chemical decomposition, there is an increase in the ratio of the probabilities for diamond and graphite nucleation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. O. I. Leipunskii, Usp. Khim.,8, 1519 (1939).

    Google Scholar 

  2. R. Berman and F. Simon, Z. Electrochem.,59, 333 (1955).

    Google Scholar 

  3. R. A. Munson, Carbon,5, 471 (1967).

    Google Scholar 

  4. R. G. Arkhipov, T. D. Varfolomeeva, and S. V. Popova, Dokl. Akad. Nauk SSSR,199, 55 (1971).

    Google Scholar 

  5. D. V. Fedoseev and B. V. Deryagin, Dokl. Akad. Nauk SSSR,238, 91 (1977).

    Google Scholar 

  6. W. D. Harkins, J. Chem. Phys.,10, 268 (1942).

    Google Scholar 

  7. B. V. Belokurov, Zh. Fiz. Khim.,34, 440 (1960).

    Google Scholar 

  8. Yu. V. Naidich and G. A. Kolesnichenko, The Interaction of Metallic Melts with Diamond and Graphite Surfaces [in Russian], Naukova Dumka, Kiev (1967).

    Google Scholar 

  9. L. F. Vereshchagin, E. N. Yakovlev, L. M. Buchnev, and B. K. Dymov, Teplofiz. Vys. Temp,15, 316 (1977).

    Google Scholar 

  10. A. A. Zhukov, Zh. Fiz. Khim.,41, 185 (1967).

    Google Scholar 

  11. V. I. Farafontov and Ya. A. Kalashnikov, Zh. Fiz. Khim.,50, 830 (1976).

    Google Scholar 

  12. L. F. Vereshyagin, Ya. A. Kalashnikov, and M. D. Shalimov, High Temp. High Pressure,7, 41 (1975).

    Google Scholar 

  13. D. V. Fedoseev, N. F. Kirova, and B. V. Deryagin, Dokl. Akad. Nauk SSSR,230, 1155 (1976).

    Google Scholar 

  14. B. V. Deryagin and D. V. Fedoseev, Usp. Khim.,39, 1661 (1970).

    Google Scholar 

  15. D. V. Fedoseev, I. G. Varshavskaya, A. V. Lavrent'ev, and B. V. Deryagin, Izv. Akad. Nauk SSSR, Ser. Khim., 928 (1977).

  16. V. M. Gol'yanov and A. P. Demidov, French Patent 2157957 (1973).

  17. V. E. Strel'nitskii, S. I. Vakula, N. N. Matyushenko, B. L. Tomak, A. M. Pshisukha, and É. P. Nikolova, in: Synthetic Diamonds [in Russian], Naukova Dumka, Kiev (1977), No. 4 (52), p. 14.

    Google Scholar 

  18. B. V. Deryagin, Teor. Eksp. Khim.,9, 471 (1973).

    Google Scholar 

  19. B. V. Deryagin, D. V. Fedoseev, V. P. Varnin, A. E. Gorodetskii, A. P. Zakharov, and I. G. Teremetskaya, Zh. Eksp. Teor. Fiz.,69, 1250 (1975).

    Google Scholar 

  20. V. P. Varnin, B. V. Deryagin, D. V. Fedoseev, I. G. Teremetskaya, and A. N. Khodan, Kristallografiya,22, 893 (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1184–1188, June, 1979.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Deryagin, B.V., Fedoseev, D.V. Phase transitions and nucleation in diamond and graphite. Russ Chem Bull 28, 1106–1109 (1979). https://doi.org/10.1007/BF00947364

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00947364

Keywords

Navigation