Abstract
Covington's nonstatistical distribution of solvate species theory of preferential solvation is used to analyze205Tl chemical shift data for 0.005M TlNO 3 in nine binary solvent systems. The theory quite adequately fits the experimental data, and equilibrium constants and free energies of preferential solvation are obtained. The effect of choosing different values for the solvation number is investigated and found to be slight except for systems involving DMSO,3 where decreasing the solvation number from 6 to 3 improves the fit to experimental data.
Similar content being viewed by others
References
R. W. Briggs and J. F. Hinton,J. Solution Chem. 6, 827 (1977).
R. W. Briggs and J. F. Hinton,J. Solution Chem. 7, 1 (1978).
J. F. Hinton and R. W. Briggs,J. Magn. Reson. 19, 393 (1975).
V. Gutmann,Coordination Chemistry in Nonaqueous Solutions (Springer-Verlag, Vienna, 1968).
V. Gutmann and R. Schmid,Coord. Chem. Rev. 12, 263 (1974).
L. S. Frankel, T. R. Stengle, and C. H. Langford,J. Chem. Soc. Chem. Commun., 393 (1965).
A. K. Covington, T. H. Lilley, K. E. Newman, and G. A. Porthouse,J. Chem. Soc. Faraday Trans. 1 69, 963 (1973).
A. K. Covington, K. E. Newman, and T. H. Lilley,J. Chem. Soc. Faraday Trans. 1 69, 973 (1973).
A. K. Covington, I. R. Lantzke, and J. M. Thain,J. Chem. Soc. Faraday Trans. 1 70, 1869 (1974).
A. K. Covington and J. M. Thain,J. Chem. Soc. Faraday Trans. 1 70, 1879 (1974).
A. K. Covington and K. E. Newman, Thermodynamics of Preferential Solvation of Electrolytes in Binary Solvent Mixtures inThermodynamic Behavior of Electrolytes in Mixed Solvents, W. F. Furter, ed.,Adv. Chem. Ser. 155 (American Chemical Society, Washington, D.C., 1976), pp. 153–196.
F. A. Cotton and R. Francis,J. Am. Chem. Soc. 82, 2986 (1960).
M. Salomon, inPhysical Chemistry of Organic Solvent Systems, A. K. Covington and T. Dickinson, eds., (Plenum Press, London, 1973), p. 175.
M. S. Greenberg and A. I. Popov,Spectrochim. Acta, Part A 31, 697 (1975).
J. J. Dechter and J. I. Zink,Inorg. Chem. 15, 1690 (1976).
T. R. Stengle, Y. C. E. Pan, and C. H. Langford,J. Am. Chem. Soc. 94, 9037 (1972).
R. W. Gurney,Ionic Processes in Solution (McGraw-Hill, New York, 1953).
J. L. Wuepper and A. I. Popov,J. Am. Chem. Soc. 92, 1493 (1970).
N. Ahmad and M. C. Day,I. Inorg. Nucl. Chem. 40, 1383 (1978).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Briggs, R.W., Hinton, J.F. Application of Covington's nonstatistical distribution of solvate species theory to the preferential solvation of Tl+ in various binary solvent systems. J Solution Chem 8, 519–527 (1979). https://doi.org/10.1007/BF00655208
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00655208