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Comparative study of breakthrough volumes BTV on various sorbents

Vergleichende Untersuchung des Durchbruchsvolumens an verschiedenen Sorbentien

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Zusammenfassung

An 10 verschiedenen Sorbentien (Chromosorb 102, 104, 105, 106; Porapak R und S; XAD-2; XAD-7; Tenax GC; Carbosphere) wurden für 15 flüchtige organische Verbindungen (halogenierte Kohlenwasserstoffe, Alkohole u. a.) die Durchbruchsvolumina bestimmt. Es wurde dafür ein indirektes Verfahren mit typischen chromatographischen Parametern (Retentionsvolumen, Peakbreite) benutzt. Die Methode erscheint nützlich für die vorläufige Abschätzung der Adsorptionskapazität von Sorbentien, eignet sich jedoch nicht für die Untersuchung des Einflusses verschiedener Parameter auf das Durchbruchsvolumen.

Summary

Breakthrough volumes on ten sorbents (Chromosorb 102, 104, 105 and 106, Porapak R and S, XAD-2, XAD-7, Tenax GC and Carbosphere) have been determined for vapours of 15 volatile organic compounds (halogenated hydrocarbons, alcohols, etc.). The volumes were determined by an indirect method employing typical chromatographic parameters such as retention volume and peak width.

The method seems to be useful for preliminary estimation of adsorption capacity of various sorbents. It is not suitable, however, for the investigation of the effect of various parameters on the breakthrough volume.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry and Technology, Technical University, PL-80-952, Gdańsk, Poland

    Jacek Namieśnik & Edmund Kozłowski

Authors
  1. Jacek Namieśnik
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  2. Edmund Kozłowski
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Part of this research was supported by Institute of Oceanology, Polish Academy of Sciences, Gdańsk, grant MR. I-15.

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Namieśnik, J., Kozłowski, E. Comparative study of breakthrough volumes BTV on various sorbents. Z. Anal. Chem. 311, 581–584 (1982). https://doi.org/10.1007/BF00635534

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  • DOI: https://doi.org/10.1007/BF00635534

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