Summary
Dependences of rate constants on pressure (in aqueous solution up to 1.25 kbar) are reported for peroxodisulphate oxidation of hexacyanoferrate(II), tris(2,2′-bipyridyl)iron(II), tris(1,10-phenanthroline)iron(II), bis(1,4,7-triazacyclononane)nickel(II) and bis(1,2-ethanediamine)cysteinatocobalt(III) and its thioglycollato-analogue, and for periodate oxidation of the two last-named complexes. Derived activation volumes are reported and discussed in terms of intrinsic and solvational contributions. Rate laws and pressure effects on reactivity are reported for the reaction of peroxodisulphate with pentacyanoferrates(II) containing N-alkylpyrazinium ligands.
Similar content being viewed by others
References
J. Burgess, A. J. Duffield and R. Sherry, J. Chem. Soc., Chem. Commun., 350 (1980).
N. J. Blundell, J. Burgess and C. D. Hubbard, Inorg. Chim. Acta, 155, 165 (1989).
J. Burgess and C. D. Hubbard, Inorg. Chim. Acta, 64, L71 (1982).
D. H. Irvine, J. Chem. Soc., 2166 (1958), 2977 (1959); D. A. House, Chem. Rev., 62, 185 (1962); J. Burgess, J. Chem. Soc. (A), 2114 (1970).
R. I. Haines and A. McAuley, Coord. Chem. Rev., 39, 77 (1981).
O. Vollárová and J. Benko, J. Chem. Soc., Dalton Trans., 2359 (1983); J. Burgess, O. Vollárová and J. Benko, Transition Met. Chem., 12, 238 (1987); and references therein.
C. P. Sloan and J. H. Krueger, Inorg. Chem., 14, 1481 (1975).
D. L. Herting, C. P. Sloan, A. W. Cabral and J. H. Krueger, Inorg. Chem., 17, 1649 (1978).
O. Vollárová, J. Benko and I. Matejeková, Coll. Czech. Chem. Commun., 51, 1049 (1986).
N. Hallinan, P. McArdle, J. Burgess and P. Guardado, J. Organomet. Chem., 333, 77 (1987); S. Alshehri, J. Burgess and C. D. Hubbard, Transition Met. Chem., 18, 228 (1993).
A. Yeh and A. Haim, J. Am. Chem. Soc., 107, 369 (1985).
H. E. Toma and J. M. Malin, Inorg. Chem., 12, 1039 (1973).
S. Alshehri, Ph.D. Thesis, Leicester (1992).
J. Burgess and R. H. Prince, J. Chem. Soc. (A), 1772 (1966).
A. McAuley, P. R. Norman and O. Olubuyide, Inorg. Chem., 23, 1938 (1984).
T. Asano and W. J. Le Noble, Chem. Rev., 78, 407 (1978); J. Burgess and E. Pelizzetti, Progr. React. Kinet., 17, 1 (1992).
F. J. Millero, Chem. Rev., 71, 147 (1971).
J. Burgess, I. M. Horn and C. D. Hubbard, unpublished observations.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Benko, J., Vollárová, O., Alshehri, S. et al. Activation volumes for peroxodisulphate oxidation of cobalt(III), iron(II) and nickel(II) complexes. Transition Met Chem 18, 551–554 (1993). https://doi.org/10.1007/BF00191119
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00191119