Abstract
Fructose oleates synthesis was performed in a batch reactor by trans- or direct esterification. An immobilized lipase from Candida antartica was used. When a solvent was used, 65% and 46% of conversion of fructose were obtained by transesterification and direct esterification, respectively. These two reactions were also compared in a solvent-free melt. Both in molten media and with cosolvent, two isomeric forms of fructose oleates were produced.
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Adelhorst, K., Björkling, F. and Godtfredsen, O.K., (1990), Synthesis, 112–115.
Akoh, C.C. and Swanson, B.G., (1989), J. Am. Oil Chem. Soc., 66, 1295–1301.
Björkling, F., Godtfredsen, S.E. and Kirk, O., (1989), J. Chem. Soc. Chem. Commun., 14, 934–935.
Fregapane, G., Sarney, D.B., Greenberg, S.G., Knight, D.J. and Vulfson, E.N., (1994), J. Am. Oil Chem. Soc., 71,87–91.
Haferburg, D., Hommel, R., Claus, R. and Kleber, H.-P., (1986), Adv. Biochem. Eng.Biotechnol., 33, 53.
Ikeda, I. and Klibanov, A.M., (1993), Biotechnol. Bioeng., 42, 788–791
Janssen, A.E.M., Klabbers, C., Franssen, M.C.R. and van't Riet, K., (1991), Enzyme Microb. Technol., 13, 565–572.
Khaled, N., Montet, D., Farines, M., Pina, M. and Graille, J., (1992),Oléagineux, 47, 181–190.
Khaled, N., Montet, D., Pina, M. and Graille, J., (1991), Biotechnol. Lett., 13, 167–172.
Klibanov, A.M., (1990), Acc. Chem. Res., 23, 114–121.
Mukesh, D., Jadhav, S., Sheth, D., Banerjii, A.A., Newadkar, R. and Bevinkatti, H.S., (1993), Biotechnol. Technics, 7, 569–572.
Oguntimein, O.B., Erdmann, H. and Schmid, R.D., (1993), Biotechnol. Lett., 15, 175–180.
Schlotterbeck, A., Lang, S., Wray, V. and Wagner, F., (1993), Biotech. Lett., 15, 61–64.
Therisod, M. and Klibanov, A.M., (1986), J. Am. Chem. Soc., 108, 5638–5640.
Yamamoto, T., Morishita, S., Kinami, K., Nakamura, S. and Hotta, H., (1982), UK Patent Application GB, n∘2.O81.266A.
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Coulon, D., Girardin, M., Rovel, B. et al. Comparison of direct esterification and transesterification of fructose by Candida antartica lipase. Biotechnol Lett 17, 183–186 (1995). https://doi.org/10.1007/BF00127985
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DOI: https://doi.org/10.1007/BF00127985