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EPR of iron centres in silicon dioxide

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Abstract

A review is presented of the present status of EPR-based understanding of Fe in SiO2. As a primary goal, a guide to the literature is given. Quantitative evaluation of all relevant spin-Hamiltonian parameters is discussed, as is computer-based spectral simulation, for single crystals (alpha-quartz), powders and glasses (vitreous quartz). Identification of the numerous centres now known (e.g., for Fe3+:[FeO4/M]0 with M=H, Li, Na, …, as well as [FeO4]−) is featured, discussing atomic positions, surroundings and dynamic effects. Some general chemical considerations, including comparison between Fe in SiO2 crystals and glasses, are covered, as are future needs.

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  1. Department of Chemistry University of Saskatchewan, S7N 0W0, Saskatoon, SK, Canada

    J. A. Weil

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Dedication Dedicated to the memory of the late Gerhard Lehmann, who contributed much to our knowledge of magnetic defects in minerals.

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Weil, J.A. EPR of iron centres in silicon dioxide. Appl. Magn. Reson. 6, 1–16 (1994). https://doi.org/10.1007/BF03162478

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