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The discovery and acceptance of the Kirkendall Effect: The result of a short research career

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Abstract

In the 1940s, it was a common belief that atomic diffusion took place via a direct exchange or ring mechanism that indicated the equality of diffusion of binary elements in metals and alloys. However, Ernest Kirkendall first observed inequality in the diffusion of copper and zinc in interdiffusion between brass and copper. This article reports how Kirkendall discovered the effect, now known as the Kirkendall Effect, in his short research career.

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Editor's Note: A hypertext-enhanced version of this article can be found at http://www.tms.org/pubs/journals/JOM/9706/Nakajima-9706.html. Also some of the artwork employed here was photographically reproduced from existing publications. As a result, the quality of the images is sometimes less than ideal.

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Nakajima, H. The discovery and acceptance of the Kirkendall Effect: The result of a short research career. JOM 49, 15–19 (1997). https://doi.org/10.1007/BF02914706

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