Growth, structure and upconversion mechanisms of Ba₂ErCl₇ crystal

Abstract

The methods to grow a novel upconversion crystal Ba₂ErCl₇ are reported in this note. Ba₂ErCl₇ material was synthesized with Er₂O₃, BaCl₂·2H₂O and NH₄Cl by using a so-called “direct synthesis method”. High quality Ba₂ErCl₇ single crystals with size up to 4 mm×8 mm×15 mm were grown by using the Czochralski and the Bridgman methods. Intense yellow-green luminescence was detected when the crystal was pumped by an 803 laser diode (LD). Transmittance spectrum was measured by using HITACH U-3500 spectrophotometer at room temperature for the first time, in which one can see that the transmittance is high in the range from 350 to 1 600 nm and the cut-off wavelength of the crystal was 230 nm. The upconversion mechanisms were discussed.