Skip to main content
Log in

Synthesis of ZnO nanowires on Si substrate by thermal evaporation method without catalyst: Structural and optical properties

  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Synthesis of ZnO nanowires was achieved on Si(100) substrate by the thermal evaporation of high purity metallic zinc powder without the use of any metal catalyst or additives. The diameter and length of the as-grown nanowires were in the range of 20–35 nm and few micrometers, respectively. The shapes and sizes of ZnO nanowires were dependent on the growth time. The high resolution transmission electron microscopy and selected area electron diffraction patterns indicated that the as-grown products are single crystalline with wurtzite hexagonal phase. Room temperature photoluminescence studies exhibited a strong UV emission and a suppressed green emission, confirming the good optical properties for the deposited nanowires.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Arnold, M. S., Avouris, P., Pan, W. Z. and Wang, Z. L., “Field-effect transistors based on single semiconducting oxide nanobelts,”J. Phys. Chem. B.,107, 659 (2003).

    Article  CAS  Google Scholar 

  • Duan, X. F. and Lieber, C. M., “Laser-assisted catalytic growth of single crystal GaN nanowires,”J. Am. Chem. Soc.,122, 188 (2000).

    Article  CAS  Google Scholar 

  • Golra, C. R., Emanetoglu, N. W., Liang, S., Mayo, W. E., Lu, Y., Wraback, M. and Shen, H., “Structural, optical, and surface acoustic wave properties of epitaxial ZnO films grown on (0112) sapphire by metalorganic chemical vapor deposition,”J. Appl. Phys.,85, 2595 (1999).

    Article  Google Scholar 

  • Gordillo, G., “New materials used as optical window in thin film solar cells,”Surf. Rev. Lett.,9, 1675 (2002).

    Article  CAS  Google Scholar 

  • Jeong, J. S., Lee, J. Y., Cho, J. H., Suh, H. J. and Lee, C. J., “Single-crystalline ZnO microtubes formed by coalescence of ZnO nanowires using a simple metal-vapor deposition method,”Chem. Mater.,17, 2752 (2005).

    Article  CAS  Google Scholar 

  • Keis, K., Vayssieres, L., Lindquist, S. and Hagfeldt, A., “Nanostructured ZnO electrodes for photovoltaic applications,”Nanostuct. Mater.,12, 487 (1999).

    Article  Google Scholar 

  • Kim, S. H., Umar, A. and Hahn, Y. B., “Growth and formation mechanism of sea-urchin like ZnO nanostructures on Si,”Korean J. Chem. Eng.,22, 489 (2005).

    CAS  Google Scholar 

  • Kim, T. Y., Lee, S. H., Mo, Y. H., Nahm, K. S., Kim, J. Y., Suh, E.-K., Kim, M., “Growth mechanism of needle-shaped ZnO nanostructures over NiO-coated Si substrates,”Korean J. Chem. Eng.,21, 733 (2004).

    Article  CAS  Google Scholar 

  • Kind, H., Yan, H., Law, M., Messer, B. and Yang, P., “Nanowire ultraviolet photodetectors and optical switches,”Adv. Mater.,14, 158 (2002).

    Article  CAS  Google Scholar 

  • Kong, X. Y. and Wang, Z. L., “Spontaneous polarization-induced nanohelixes, nanosprings, and nanorings of piezoelectric nanobelts,”Nano Lett.,3, 1625 (2003).

    Article  CAS  Google Scholar 

  • Lee, S., Im, Y. H. and Hahn, Y. B., “Two-step growth of ZnO films on silicon by atomic layer deposition,”Korean J. Chem. Eng.,22, 334 (2005).

    Article  CAS  Google Scholar 

  • Ma, D. D. D., Lee, C. S., Au, F. C. K., Tong, S. Y. and Lee, S. T., “Smalldiameter silicon nanowire surfaces,”Science,299, 1874 (2003).

    Article  CAS  Google Scholar 

  • Minne, S. C., Manalis, S. R. and Quate, C. F., “Parallel atomic force microscopy using cantilevers with integrated piezoresistive sensors and integrated piezoelectric actuators,”Appl. Phys. Lett.,67, 3918 (1995).

    Article  CAS  Google Scholar 

  • Pal, B. and Sharon, M., “Enhanced photocatalytic activity of highly porous ZnO thin films prepared by sol-gel process,”Mater. Chem. Phys.,76, 82 (2002).

    Article  CAS  Google Scholar 

  • Pan, Z. W., Dai, Z. R. and Wang, Z. L., “Nanobelts of semiconducting oxides,”Science,291, 1947 (2001).

    Article  CAS  Google Scholar 

  • Peng, L.-H., Zhang, Y.-C. and Lin, Y.-C., “Zinc oxide doping effects in polarization switching of lithium niobate,”Appl. Phys. Lett.,78, 4 (2001).

    Article  CAS  Google Scholar 

  • Sekar, A., Kim, S. H., Umar, A. and Hahn, Y. B., “Catalyst-free synthesis of ZnO nanowires on Si by oxidation of Zn powders,”J. Crystal Growth,277, 471 (2005).

    Article  CAS  Google Scholar 

  • Umar, A., Kim, S. H., Lee, Y. S., Nahm, K. S. and Hahn, Y. B., “Catalyst free large-scale synthesis of ZnO nanorods by a vapor-solid growth mechanism: Structural and optical properties,”J. Crystal Growth,282, 131 (2005).

    Article  CAS  Google Scholar 

  • Umar, A., Lee, S., Lee, Y. S., Nahm, K. S. and Hahn, Y. B., “Star-shaped ZnO nanostructures on silicon by cyclic feeding chemical vapor deposition,”J. Crystal Growth,277, 479 (2005).

    Article  CAS  Google Scholar 

  • Umar, A., Lee, S., Im, Y. H. and Hahn, Y. B., “Flower-shaped ZnO nanostructures obtained by cyclic feeding chemical vapor deposition: Structural and optical properties,”Nanotechnology,16, 2462 (2005).

    Article  CAS  Google Scholar 

  • Vanheusdan, K., Warren, W. L., Seager, C. H., Tallent, D. R., Voigt, J. A. and Gnade, B. E., “Mechanism behind green photoluminescence in ZnO phosphor powders,”J. Appl. Phys.,79, 7983 (1996).

    Article  Google Scholar 

  • Wagner, R. S. and Ellis, W. C., “Vapor-liquid-solid mechanism of single crystal growth,”Appl. Phys. Lett.,4, 89 (1964).

    Article  CAS  Google Scholar 

  • Wang, X., Li, Q., Liu, Z., Zhang, J., Liu, Z. and Wang, R., “Low-temperature growth and properties of ZnO nanowires,”Appl. Phys. Lett.,84, 4941 (2004).

    Article  CAS  Google Scholar 

  • Wu, Z. H., Mei, X., Kim, D., Blumin, M., Ruda, H. E., Liu, J. Q. and Kavanagh, K. L., “Growth, branching, and kinking of molecularbeam epitaxial <110> GaAs nanowires,”Appl. Phys. Lett.,83, 3368 (2003).

    Article  CAS  Google Scholar 

  • Xiangfeng, C., Dongli, J., Djurisic, A. B. and Leung, Y. H., “Gas-sensing properties of thick film based on ZnO nano-tetrapods,”Chem. Phys. Lett.,401, 426 (2005).

    Article  Google Scholar 

  • Xing, Y. J., Xi, Z. H., Xue, Z. Q., Zhang, X. D., Song, J. H., Wang, R. M., Xu, J., Song, Y., Zhang, S. L. and Yu, D. P., “Optical properties of the ZnO nanotubes synthesized via vapor phase growth,”Appl. Phys. Lett.,83, 1689 (2003).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yoon-Bong Hahn.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Umar, A., Ra, HW., Jeong, JP. et al. Synthesis of ZnO nanowires on Si substrate by thermal evaporation method without catalyst: Structural and optical properties. Korean J. Chem. Eng. 23, 499–504 (2006). https://doi.org/10.1007/BF02706756

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02706756

Key words

Navigation