Skip to main content
Log in

Preparation and characterization of thin films of MgO, Al2O3 and MgAl2O4 by atomic layer deposition

  • Regular Issue Paper
  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

MgO, Al2O3 and MgAl2O4 thin films were deposited on silicon substrates at various temperatures by the atomic layer deposition (ALD) method using bis(cyclopentadienyl)magnesium, triethylaluminum, and H2O and were characterized systematically. High-quality polycrystalline MgO films were deposited for a substrate temperature above 500°C, and amorphous thin films were deposited around 400°C. The deposited Al2O3 and MgAl2O4 thin films were characterized as amorphous in structure. Applicability of ALD to complex oxides is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D.K. Fork, D.B. Fenner, G.A.N. Connell, Julia M. Phillips and T.H. Geballe,Appl. Phys. Lett. 57, 1137 (1990).

    Article  CAS  Google Scholar 

  2. M. Mikami, Y. Hokari, E. Egami, H. Tsuya and M. Kanamori,Ext. Abst. 15th Conf. on Solid State Devices and Mater., Tokyo, 31 (1983).

  3. H. Fukumoto, T. Imura and Y. Osaka,Appl. Phys. Lett. 55, 360 (1989).

    Article  CAS  Google Scholar 

  4. T. Inoue, Y. Yamamoto, S. Koyama, S. Suzuki and Y. Ueda,Appl. Phys. Lett. 56, 1332 (1990).

    Article  CAS  Google Scholar 

  5. D.K. Fork, D.B. Fenner and T.H. Geballe,J. Appl. Phys. 68, 4316 (1990).

    Article  CAS  Google Scholar 

  6. M. Ishida, K. Sawada, S. Yamagushi, T. Nakamura and T. Suzaki,Appl. Phys. Lett. 55, 556 (1989).

    Article  CAS  Google Scholar 

  7. W.J. DeSisto and R. L. Henry,J. Cryst. Growth 109, 314(1991).

    Article  CAS  Google Scholar 

  8. J.A. Aboaf,J. Electrochem. Soc. 114, 948 (1967).

    Article  CAS  Google Scholar 

  9. J. Saraie, J. Kwon and Y. Yodogawa,J. Electrochem. Soc. 132, 890 (1985).

    Article  CAS  Google Scholar 

  10. J. Saraie, K. Ono and S. Takeuchi,J. Electrochem. Soc. 136, 3139 (1989).

    Article  CAS  Google Scholar 

  11. T.H. Hua and M. Armgarth,J. Electron. Mater. 16, 27 (1987).

    CAS  Google Scholar 

  12. M.O. Aboelfotoh,J. Vac. Sci. Technol. 12, 67 (1975).

    Article  CAS  Google Scholar 

  13. H.Z. Durusoy,J. Mat. Sci. Lett. 10, 1023 (1991).

    Article  CAS  Google Scholar 

  14. B.S. Kwak, E.P. Boyd, K. Zhang, and A. Erbil,Appl. Phys. Lett. 54, 2542 (1989).

    Article  CAS  Google Scholar 

  15. T. Saburo, N. Hidenori and H. Kenjiro,Jpn. J. Appl. Phys. 29, 1059 (1990).

    Article  Google Scholar 

  16. M. Toshiro and S. Jun,Jpn. J. Appl. Phys. 29, L810 (1990).

    Article  Google Scholar 

  17. N. Dalacu, A.H. Kitai, B.W. Sanders and R. Huang,Thin Solid Films 209, 207 (1992).

    Article  CAS  Google Scholar 

  18. M. Ihara, Y. Arimoto, M. Jifuku, T. Kodama, H. Yamawak and T. Yamaoka,J. Electrochem. Soc. 129, 2569 (1982).

    Article  CAS  Google Scholar 

  19. T. Suntola and M. J. Antson, U.S. Patent No. 4,058,430 (1977).

  20. R. Clausen, K. Petermann,IEEE J. Quantum Electron 24, 1114(1988).

    Article  CAS  Google Scholar 

  21. D.K. Fork, F.A. Ponce, J.C. Tramontana and T.H. Geballe,Appl. Phys. Lett. 58, 2295 (1991).

    Google Scholar 

  22. W. Hsu and R. Raj,Appl. Phys. Lett. 60, 3105 (1992).

    Article  CAS  Google Scholar 

  23. T. Suntola,Mat. Sci. Report 4, 261 (1989).

    Article  CAS  Google Scholar 

  24. M. Ozeki,Mat. Sci. Report 8, 97 (1992).

    Article  CAS  Google Scholar 

  25. G. Oya, M. Yoshida and Y. Sawada,Appl. Phys. Lett. 51, 1143 (1987).

    Article  CAS  Google Scholar 

  26. G. Oya and Y. Sawada,J. Cryst. Growth 99, 572 (1990).

    Article  CAS  Google Scholar 

  27. R. Huang and A Kitai,Appl. Phys. Lett. 61, 1450 (1992).

    Article  CAS  Google Scholar 

  28. R. Huang and A. Kitai, to be published.

  29. R. Kelly,Surf. Sci. 100, 85 (1980).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Huang, R., Kitai, A.H. Preparation and characterization of thin films of MgO, Al2O3 and MgAl2O4 by atomic layer deposition. J. Electron. Mater. 22, 215–220 (1993). https://doi.org/10.1007/BF02665029

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02665029

Key words

Navigation