Abstract
The thermodynamic properties of liquid Ni-Ti alloys have been determined between 1475° and 1725°C by a Knudsen cell-mass spectrometric technique. The liquid Ni-Ti system exhibits strong negative deviations from ideality, indicating a preference for unlike atom bonding. Pronounced maxima in the excess stability function occur near the Ni3Ti and NiTi compositions at 1500° C.
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0. Kubaschewski:Trans. Faraday Soc, 1958, vol. 54, pp. 814–20.
P. A. Cherkasov, V. V. Averin, and A. M. Samarin:Russ. J. Phys. Chem., 1968, vol. 42, pp. 401–04.
M. Hansen and K. Anderko:Constitution of Binary Alloys, 2nd ed., p.1049, McGraw-Hill Book Co., New York, 1958.
R. P. Elliott:Constitution of Binary Alloys, First Suppl, p. 559, McGraw-Hill, Book Co., New York, 1965.
F. A. Shunk:Constitution of Binnary Alloys, Second Suppl, p. 676, McGraw-Hill Book Co., New York, 1969.
G. R. Belton and R. J. Fruehan:J. Phys. Chem., 1967, vol. 71, pp. 1403–09.
R. B. Reese, R. A. Rapp, and G. R. St. Pierre:Trans. TMS-AIME, 1968, vol. 242, pp. 1719–26.
S. W. Gilby and G. R. St. Pierre:Trans. TMS-AIME, 1969, vol. 245, pp. 1749–58.
R. Speiser and J. W. Spretnak:Vacuum Metallurgy, J. M. Blocher, ed., p. 155, The Electrochemical Soc, Boston, 1955.
L. S. Darken:Trans. TMS-AIME, 1967, vol. 239, pp. 80–89.
V. A. Geiderikh and Y. I. Gerasimov:Russ. J. Chem., 1963, vol. 37, pp. 1274–76.
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This paper is based upon a thesis by R. M. GERMAN is partial fulfillment of the requirements of the degree of Master of Science at The Ohio State University.
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German, R.M., Pierre, G.R.S. The high temperature thermodynamic properties of Ni-Ti alloys. Metall Trans 3, 2819–2823 (1972). https://doi.org/10.1007/BF02652848
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DOI: https://doi.org/10.1007/BF02652848