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A mass- spectrometric investigation of the high temperature thermodynamic stabilities of Pd- Ti alloys

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An Erratum to this article was published on 01 December 1977

Abstract

From the Kundsen cell mass-spectrometric investigation of Pd-rich liquid alloys of Ti, the Gibbs energies of formation of TiPd and TiPd3 at 1873 K have been derived as -67 ± 8 and -56 ± 8 kj/g atom, respectively. The corresponding enthalpies of formation at 298 K are estimated to be -80 ± 10 and -70 ± kjJg atom. The stabilities of some Ti-X systems, with X = Fe, Ni, Pd and Pt, are compared and correlated with the extent of electron transfer which is consistent with the Engel-Brewer concepts of alloying behavior in transition metals.

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Authors and Affiliations

  1. University of Wisconsin, 53201, Milwaukee, WI

    U. V. Choudary

  2. Texas A & M University, 77843, College Station, TX

    K. A. Gingerich (Professor) & L. R. Cornwell (Associate Professor)

Authors
  1. U. V. Choudary
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  2. K. A. Gingerich
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  3. L. R. Cornwell
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Additional information

Formerly with Texas A & M University.

An erratum to this article is available at http://dx.doi.org/10.1007/BF02646586.

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Choudary, U.V., Gingerich, K.A. & Cornwell, L.R. A mass- spectrometric investigation of the high temperature thermodynamic stabilities of Pd- Ti alloys. Metall Trans A 8, 1487–1491 (1977). https://doi.org/10.1007/BF02642863

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  • DOI: https://doi.org/10.1007/BF02642863

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