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Structure of {Pb[S2CN(C2H5)2]2(1,10-phenanthroline)}2

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Abstract

Lead (II) nitrate reacts with 1,10-phenanthroline and sodium diethyldithiocarbamate in water to produce yellow bisdiethyldithiocarbamata 1,10-phenanthroline lead(II). Crystals from water are triclinic, space group\(P\bar 1\)(#2),a=10.53(2) Å,b=11.050(12)Å,c=24.74 (3) Å, α=94.71 (9)0, β=98.15(11)o, γ=114.11(9)o,V=2569(6) Å3,Z=2. Each lead atom has approximate pentagonal pyramid coordination geometry through the nitrogens of a phenathroline and sulfurs of two dithiocarbamates. Additionally, complexes form loose dimers in which lead atoms are weakly coordinated to a sulfur in an adjacent complex. IR and proton nmr spectrum of the complex are consistent with the solid state structure.

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Authors and Affiliations

  1. Department of Chemistry, Jackson State University, 39217, Jackson, Mississippi

    Jeffrey D. Zubkowski & Tesia Hall

  2. Department of Chemistry, Mississippi College, 39058, Clinton, Mississippi

    Edward J. Valente

  3. Lawrence Berkeley National Laboratory, University of California, 94720, Berkeley, California

    Dale L. Perry

  4. Department of Science and Technology, Universidad Metropolitana, 00928, Rio Pedras, Puerto Rico

    Luis A. Feliu & James Garmon

Authors
  1. Jeffrey D. Zubkowski
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  2. Tesia Hall
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  3. Edward J. Valente
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  4. Dale L. Perry
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  5. Luis A. Feliu
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  6. James Garmon
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Zubkowski, J.D., Hall, T., Valente, E.J. et al. Structure of {Pb[S2CN(C2H5)2]2(1,10-phenanthroline)}2 . J Chem Crystallogr 27, 251–255 (1997). https://doi.org/10.1007/BF02575964

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  • DOI: https://doi.org/10.1007/BF02575964

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