Summary
A numerical approach has been developed for the correlation of retention times (total retention time) with temperature in gas chromatography, which allows the calculation of retention parameters including retention index from data acquired under two or more different temperature program conditions. By using this procedure the optimization of temperature condition can be further achieved, especially when a temperature-programmed run is the most suitable mode in the preliminary development of an analytical method for the analysis of an unknown sample.
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Chen, J.P., Liang, X.M., Zhang, Q. et al. Prediction of GC retention values under various column temperature conditions from temperature programmed data. Chromatographia 53, 539–547 (2001). https://doi.org/10.1007/BF02491619
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DOI: https://doi.org/10.1007/BF02491619