Skip to main content
Log in

Rheological properties of SEBS, EVA and EBA polymer modified bitumens

  • Scientific Reports
  • Published:
Materials and Structures Aims and scope Submit manuscript

Abstract

The rheological properties of various polymer modified bitumens were studied. Three bitumens from two different sources were mixed with styrene-ethylenbutylene-styrene (SEBS), ethylene vinyl acetate (EVA) and ethylene butyl acrylate (EBA) copolymers at different polymer contents. The rheological properties of the modified binders were investigated by means of dynamic mechanical analysis and creep test (bending beam rheometer). The results indicated that polymer modification increased binder elastic responses and dynamic moduli at intermediate and high temperatures, and reduced binder complex and stiffness moduli at low temperatures. Polymer modification also reduced temperature susceptibility, glass transition temperature as well as limiting stiffness temperature. The degree of the improvement generally increased with polymer content, but varied with bitumen source/grade and polymer type.

Résumé

Les propriété rhéologiques de divers bitumes modifiés ont été étudiées. Trois bitumes de deux origines différentes ont été mélangés avec les copolymères styrène-éthylènebutylène-styrène (SEBS), éthylène-vinyl-acétate (EVA) et éthylène-butyl-acrylate (EBA), en utilisant différents pourcentages de polymère. Les propriétés rhéologiques des différents liants modifiés ont été examinées au moyen d’essais dynamiques et d’essais de fluage (bending beam rheometer). Les résultats montrent que l’ajout de polymère augmente la réponse élastique du liant et le module dynamique aux températures moyennes et hautes, et diminue le module complexe et le module de rigidité à basse température. L’ajout de polymère diminue la susceptibilité thermique, la température de transition vitreuse et la température de «rigidité limite». Le degré d’amélioration augmente généralement avec le pourcentage de polymère, mais il varie avec l’origine et la nature du bitume, et le type de polymère.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Barnes, H. A., Hutton, J. F. and Walters, K., ‘An Introduction to Rheology’ (Elsevier Science Publishers B. V., 1989).

  2. Dukatz, Jr., E. L., Anderson, D. A. and Rosenberger, J. L., ‘Relationship between asphalt flow properties and asphalt composition’,Proceedings of the Association of Asphalt Paving Technologists,53 (1984) 160–185.

    Google Scholar 

  3. Petersen, J. C., Robertson, R. E., Branthaver, J. F., Harnsberger, P. W., Duvall, J. J., Kim, S. S., Anderson, D. A., Christiansen, D. W. and Bahia, H. U., ‘Binder Characterization and Evaluation’, Vol. 1, SHRP-A-367, National Research Council, Washington, D. C., 1994.

    Google Scholar 

  4. Corbett, L. W., ‘Relationship between composition and physical properties of asphalt’,Proceedings of the Association of Asphalt Paving Technologists,39 (1970) 481.

    Google Scholar 

  5. Thenoux, G., Bell, C. A. and Wilson, J. E., ‘Evaluation of physical and fractional properties of asphalt and their interrelationship’, TRR 1171, TRB, National Research Council, Washington, D. C., 1988, 82–97.

    Google Scholar 

  6. Halstead, W. J., ‘Relation of asphalt chemistry to physical properties and specifications’,Proceedings of the Association of Asphalt Paving Technologists,54 (1985) 91–117.

    Google Scholar 

  7. Isacsson, U. and Lu, X., ‘Testing and appraisal of polymer modified road bitumens—State-of-the-art’,Mater. Struct. 28 (1995) 139–159.

    Article  Google Scholar 

  8. Brûlé, B., Ramond, G. and Such, C., ‘Relationships between composition, structure, and properties of road asphalts: State of research at the French Public Works Central Laboratory’, TRR 1096, TRB, National Research Council, Washington, D. C. (1986) 22–34.

    Google Scholar 

  9. Collins, J. H., Bouldin, M. G., Gelles, R. and Berker, A., ‘Improved performance of paving asphalts by polymer modification’,Proceedings of the Association of Asphalt Paving Technologists 60 (1991) 43–79.

    Google Scholar 

  10. King, G. N., King, H. W., Harders, O., Arnad, W. and Planche, P.-P., ‘Influence of asphalt grade and polymer concentration on the low temperature performance of polymer modified asphalt’,Ibid 62 (1993) 1–22.

    Google Scholar 

  11. Valkering, C. P., Vonk, W. C. and Whiteoak, C. D., ‘Improved asphalt properties using SBS modified modified bitumens’,Shell Bitumen Review 66 (May 1992) 9–11.

    Google Scholar 

  12. Lu, X. and Isacsson, U., ‘Compatibility and storage stability of styrene-butadiene-styrene copolymer modified bitumens’,Mater. Struct. 30 (1997) 618–626.

    Google Scholar 

  13. Lu, X. and Isacsson, U., ‘Rheological characterization of styrene-butadiene-styrene copolymer modified bitumens’,Construction and Building Materials 11 (1997) 23–32.

    Article  Google Scholar 

  14. Bahia, H. U., Anderson, D. A. and Christensen, D. W., ‘The bending beam rheometer: A simple device for measuring lowtemperature rheology of asphalt binders’,Proceedings of the Association of Asphalt Paving Technologists 61 (1992) 117–153.

    Google Scholar 

  15. Isacsson, U., Lu, X. and Ekblad, J., ‘Characterization of Polymer Modified Bitumens Containing SEBS, EVA and EBA’,Journal of Materials Science, in press.

  16. Petersen, J. C., Robertson, R. E., Branthaver, J. F., Harnsberger, P. M., Duvall, J. J., Kim, S. S., Anderson, D. A., Christiansen, D. W., Bahia, H. U., Dongre, R., Antle, C. E., Sharma, M. G., Button, J. W. and Glover, C. J., ‘Binder Characterization and Evaluation, Vol. 4: Test Methods’, SHRP-A-370, National Research Council Washington, D. C., 1994.

    Google Scholar 

  17. Bahia, H. U. and Anderson, D. A., ‘The new proposed rheological properties of asphalt binders: why are they required and how do they compare to conventional properties’, in ‘Physical Properties of Asphalt Cement Binders’, ASTM STP 1241, John C. Hardin, Ed., (American Society for Testing and materials, Philadelphia, 1995) 1–27.

    Google Scholar 

  18. Anderson, D. A. and Kennedy, T. W., ‘Development of SHRP binder specification’,Proceedings of the Association of Asphalt Paving Technologists 62 (1993) 481–507.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Editorial Note Prof. Ulf Isacsson is a RILEM Senior Member, he works at the Royal Institute of Technology, a RILEM Titular Member.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lu, X., Isacsson, U. & Ekblad, J. Rheological properties of SEBS, EVA and EBA polymer modified bitumens. Mat. Struct. 32, 131–139 (1999). https://doi.org/10.1007/BF02479440

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02479440

Keywords

Navigation