Abstract
Solid state photolysis of alkali tris(malonato)ferrates(III), i.e., M3[Fe(CH2C2O4)3]xH2O (M=Li, Na, K, NH4) has been studied employing Mössbauer, infrared and reflectance spectroscopic techniques. The complexes were irradiated for 300 hours using a medium pressure mercury vapour lamp of 250 W, Photodecomposition led to the formation of an iron(II) intermediate, M2[FeII(CH2C2O4)2(H2O)2] (M=Li, Na, K) which on prolonged standing in air oxidized to M[FeIII(CH2C2O4)2(H2O)2]. However, in case of ammonium complex, FeIICH2C2O4·2H2O once formed remained stable. The extent of photoreduction showed the sequence: NH4, K>Li>Na. The results have been compared with those of alkali tris (oxalato) ferrates(III).
References
A. S. Brar, B. S. Randhawa, Bull Chem. Soc. Japan, 54 (1981) 3166.
A. S. Brar, S. Brar, S. S. Sandhu, Polyhedron, 2 (1983) 421.
B. S. Randhawa, A. S. Brar, T. K. Bansal, Radiochem. Radioanal. Letts, 53 (1982) 359.
W. W. Wendlandt, E. L. Simmons, J. Inorg. Nucl. Chem., 28 (1966) 2420.
H. Sato, T. Tominaga, Bull Chem. Soc. Japan, 52 (1979) 1402.
P. S. Bassi, B. S. Randhawa, Sandeep Kaur, Hyperfine Interactions, 28 (1986) 745.
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, 2nd, ed. J. Wiley and Sons, New York, 1970.
M. Blume, Phys. Rev. Lett., 14 (1965) 96.
A. Vertes, L. Korecz, K. Burger, Mössbauer Spectroscopy, Elsevier Sci, Publ. Co., New York, 1979. p. 47.
K. Kuraishi, T. Takano, K. Nagase, N. Tanaka, J. Inorg. Nucl. Chem., 43 (1981) 2293.
R. B. Lanjewar, A. M. Waditwar, A. N. Garg, J. Radioanal. Nucl. Chem., 125 (1988) 75.
A. K. Galway, M. A. Mohammed, J. Chem. Soc, Faraday Trans. I, 81 (1985) 2503.
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Randhawa, B.S. Mössbauer study on solid state photolysis of alkali tris(malonato)ferrates(III). J Radioanal Nucl Chem 230, 295–298 (1998). https://doi.org/10.1007/BF02387484
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DOI: https://doi.org/10.1007/BF02387484