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Laser-induced fluorescence study on the interaction of Eu(III) with polycarboxylates

  • Materials Science: Positron Annihilation/Isotopes
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Abstract

Laser-induced fluorescence spectroscopy was applied to obtaining hydration structure of Eu(III) complexes with synthetic polycarboxylates of poly(acrylic acid), poly(maleic acid), poly(methacrylic acid), and poly(a-hydroxyacrylic acid). Dependence of\(N_{H_2 O} \) (the number of water molecules in the first coordination sphere of Eu(III) ion) on pH and supporting electrolyte concentration was obtained for these complexes. The spectroscopic results show that Eu(III) is surrounded by the “cage” of polycarboxylate ligands. The pH-induced transition in conformation of poly(methacrylic acid) ligand was clearly observed in the\(N_{H_2 O} \) plot vs. pH.

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Author notes

  1. T. Tominaga (Professor Emeritus)

    Present address: University of Tokyo, Hongo, Bunkyo-ku, 113, Tokyo, Japan

Authors and Affiliations

  1. Radioisotope Center, The University of Tokyo, Yayoi, Bunkyo-ku, 113, Tokyo, Japan

    Y. Takahashi (Research Fellow of the Japan Society for the Promotion of Science) & Y. Makide

  2. Japan Atomic Energy Research Institute, Tokai-mura, 319-11, Ibaraki, Japan

    T. Kimura & Y. Kato

  3. Center for Arts and Sciences, Musashi University, Toyotama-kami, Nerima-ku, 176, Tokyo, Japan

    Y. Minai

Authors
  1. Y. Takahashi
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  2. T. Kimura
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  3. Y. Kato
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  4. Y. Minai
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  5. Y. Makide
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  6. T. Tominaga
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Takahashi, Y., Kimura, T., Kato, Y. et al. Laser-induced fluorescence study on the interaction of Eu(III) with polycarboxylates. J Radioanal Nucl Chem 239, 335–340 (1999). https://doi.org/10.1007/BF02349507

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  • DOI: https://doi.org/10.1007/BF02349507

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