Summary
2-Alkyl-2-(cyclohexen-1-yl)-phenylacetonitriles and 2-alkyl-2-cyclohexyl-phenylacetonitriles were prepared from cyclohexylidene-phenylacetonitriles and 2-cyclohexyl-phenylacetonitrile, respectively, by alkylation with alkyl halogenides using sodium amide in liquid ammonia. The products were separated by gas chromatography using five stationary phases of different polarities, such as Apiezon L, SE-30, OV-17, Carbowax 20M and FFAP. The conditions for separation and determination of these high boiling nitriles were studied.
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References
J. E. Campbell, J. W. Rhoades andA. L. Gross, Nature199, 991 (1963).
I. Lysyj, Anal. Chem.32, 771 (1960).
C. H. F. Allen andG. P. Happ, Can. J. Chem.42, 641 (1964).
J. N. Butler andR. D. McAlpine, Can. J. Chem.41, 2487 (1963).
D. F. Nelson andP. L. Kirk, Anal. Chem.36, 875 (1964).
A. I. Parimskii andI. K. Shelomov, Maslob. Hir. Prom.6, 28 (1964).
M. Taramasso andA. Guerra, J. Chromatogr.3, 138 (1965).
J. Dandoy, J. Chromatogr.39, 185 (1968).
T. B. Thomson, J. Chromatogr.39, 500 (1969).
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Bosnjak-Kovačić, N., Mutak, S. & Polak, L. Separation of some 2,2-disubstituted phenylacetonitriles by gas chromatography. Chromatographia 9, 403–404 (1976). https://doi.org/10.1007/BF02330390
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DOI: https://doi.org/10.1007/BF02330390