Summary
Thep-tert-butylcalix[n]arenes (n=4,6,7,8) andp-tert-butyldihomooxacalix[4]arene have been separated by reverse phase liquid chromatography. Optimum conditions have been obtained on a Spherisorb ODS1, 5 μm C18 column by isocratic ambient elution with acetonitrile-methyltert-butyl ether. Calibration plots have been obtained from purified calixarenes and the reliability of the method is confirmed from test mixtures of calixarenes of known composition.
Similar content being viewed by others
References
C. D. Gutsche, “Calixarenes”, Monographs in Supramoleucular Chemistry, Series Ed. J. F. Stoddart, Royal Society of Chemistry, Cambridge, 1989.
S. Shinkai, “Calixarenes — The Third Generation of Supramolecules”, Tetrahedron Report Number 340, Tetrahedron49, 8933 (1993).
C. D. Gutsche, M. Iqbal, Org. Syn.68, 234 (1989).
C. D. Gutsche, B. Dhawan, M. Leonis, D. Stewart, Org Syn.68, 238 (1989).
J. H. Munch, C. D. Gutsche, Org. Syn.68, 243 (1989).
D. R. Stewart, C. D. Gutsche, Oppi Briefs25, 137 (1993).
F. Ludwig, A. Bailie, Anal. Chem.58, 2069 (1986).
Y. Nakamoto, S. I. Ishida, Makromol. Chem. Rapid Commun.3, 705 (1982).
F. Vocanson, “Thesis”, University of Lyon I, 1994.
R. Rosset, M. Caude, A. Jardy, “Manuel Pratique de chromatographie en phase liquide”, Masson, Paris, 1990.
R. W. Yost, L. S. Ettre, R. D. Conlon, “Pratique de la chromatographie liquide”, Tech et Doc., Paris, 1981.
F. Vocanson, R. Lamartine, R. Perrin, Supramol. Chem.4, 153 (1994).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vocanson, F., Lamartine, R., Duchamp, C. et al. Reverse-phase liquid chromatography ofp-tert-butylcalixarenes. Chromatographia 41, 204–206 (1995). https://doi.org/10.1007/BF02267956
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02267956