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Preparation and gas chromatographic characterisation of 3-bromo-4-(4-methylbenzyloxy)azobenzene stationary phase

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Summary

The synthesis of 3-bromo-4-(4-methylbenzyloxy)azobenzene (BMBOA) and its use as a stationary phase in packed columns are described. Chromatographic characteristics such as column efficiency, polarity (McReynolds constants) and operating temperature range were studied. Retention factors, specific retention volumes and activity coefficients for alcohols, esters, ketones, aromatic hydrocarbons andn-alkanes were determined. Phenols and 2,3, and 4-chlorobenzyl chlorides were separated on the new phase. Based on experimental data some assumptions were made on the possible types of intermolecular forces between solute and solvent.

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References

  1. L. S. Ettre, Chromatographia7, 623 (1974).

    Google Scholar 

  2. A. Hartkopf, J. Chromatogr. Sci.12, 113 (1974).

    Google Scholar 

  3. S. R. Lowry, S. Tsuge, J. J. Leary, T. L. Isenhour, J. Chromatogr. Sci.12, 125 (1974).

    Google Scholar 

  4. S. K. Poole, C. Poole, J. Chromatogr.500, 329 (1990).

    Google Scholar 

  5. M. Iovu, S. Radu, Rev. Roum. Chim.18, 473 (1973).

    Google Scholar 

  6. M. Iovu, S. Radu, Rev. Chim. (Bucharest)27, 653 (1976).

    Google Scholar 

  7. M. Iovu, S. Radu, Rev. Roum. Chim.32, 509 (1987).

    Google Scholar 

  8. W. O. McReynolds, J. Chromatogr. Sci.8, 685 (1970).

    Google Scholar 

  9. P. Fleming, Analyst117, 1553 (1992).

    Google Scholar 

  10. P. J. M. van Tulder, J. P. Franke, R. A. de Zeeuw, HRC&CC10, 191 (1987).

    Google Scholar 

  11. A. B. Littlewood, C. S. G. Phillips, D. T. Prince, J. Chem. Soc. 1480 (1955).

  12. J. H. Purnell, “Gas Chromatography” J. Wiley, New York, 1962, p. 208.

    Google Scholar 

  13. R. C. Reid, J. M. Prausnitz, T. K. Sherwood, “The Properties of Gases and Liquids”, 3rd. Ed., McGraw-Hill, New York, 1977.

    Google Scholar 

  14. J. H. Purnell, “Gas Chromatography”, J. Wiley, New York, 1962, p. 419.

    Google Scholar 

  15. A. J. Ashworth, D. H. Everett, Trans. Faraday Soc.56, 1609 (1960).

    Google Scholar 

  16. S. H. Langer, J. H. Purnell, J. Phys. Chem.67, 263 (1963).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry. Faculty of Sciences, University of Craiova, 1100, Craiova, Romania

    M. Baniceru & S. Radu

  2. Department of Analytical Chemistry, Faculty of Chemistry, University of Bucharest, Romania

    C. Patroescu

Authors
  1. M. Baniceru
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  2. S. Radu
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  3. C. Patroescu
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Baniceru, M., Radu, S. & Patroescu, C. Preparation and gas chromatographic characterisation of 3-bromo-4-(4-methylbenzyloxy)azobenzene stationary phase. Chromatographia 41, 697–701 (1995). https://doi.org/10.1007/BF02267807

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  • DOI: https://doi.org/10.1007/BF02267807

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