Abstract
Allyl-propenyl rearrangement (prototropic isomerization) occurs in the synthesis of allyl organyl chalcogenides in a hydrazine hydrate-KOH system with a 6–10-fold molar excess of KOH. Specificities of the rearrangement that depend on the nature of the chalcogen were studied.
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References
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 231–233, January, 1996.
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Deryagina, E.N., Korchevin, N.A. Isomerization processes in the synthesis of asymmetric allyl chalcogenides. Russ Chem Bull 45, 223–225 (1996). https://doi.org/10.1007/BF01433766
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DOI: https://doi.org/10.1007/BF01433766