Abstract
The alkaloid composition of the epigeal part of Arundo donax has been studied, and from an ether extract have been isolated the alkaloids donaxine, arundine, deoxyvasicinone, N-phenyl-β-naphthylamine, donaxarine, and donaxaridine. On the basis of an x-ray structural analysis, new structures have been established for donaxarine and donaxaridine:spiro[(N-methylpyrrolidin-2-one)-3,4′-(2′-methyl-3′,1′-benzoxazine)] and 3-hydroxy-3-(2′-aminophenyl)-N-methyl-2 pyrrolidone, respectively. Spectral characteristics of the derivatives obtained are given and their chemical interconversions are described.
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References
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Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (3712) 89 14 75. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 720–727, September–October, 1995. Original article submitted March 22, 1995.
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Rhuzhaev, V.U., Tashkhodzhaev, B. & Aripova, S.F. Alkaloids ofArundo donax. III. Reconsideration of the structures of donaxarine and donaxaridine. Chem Nat Compd 31, 604–609 (1995). https://doi.org/10.1007/BF01164889
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DOI: https://doi.org/10.1007/BF01164889