Abstract
Several alkyl-, aralkyl-, and aryl-substituted diammoniumμ-oxobis[trichloroferrate(III)] salts, of potential interest as model compounds for the study of certain electrophysical and biological processes, are synthesized via the corresponding tetrachloroferrate(III) salts and are characterized by IR and Raman spectroscopy. A structure analysis is performed on the representative bis(benzyldimethylphenylammonium)μ-oxobis(trichloroferrate). The (tetracoordinate) iron atoms in the oxo-bridged dinuclear anion of the salt each possess an ever so slightly distorted tetrahedral ligand environment; the bridge geometry [Fe-O distances 1.757(5) and 1.775(5) Å, Fe-O-Fe angle 147.7(3)°] compares well with that of other salts containing the [Cl3Fe-O-FeCl3]2- anion. Crystallographic Data:a=26.392(5) Å,b=14.015(3) Å,c=9.638(2) Å,β=92.65(2)°, andZ=4; space groupP21/n.R(F)=0.070,R W (F)=0.078 for 4447 observed reflections.
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Armstrong, W. H., and Lippard, S. J. (1983)J. Am. Chem. Soc. 105, 4837.
Cowell, G. W., Ledwith, A., White, A. C., and Woods, H. J. (1970)J. Chem. Soc. B, 227.
Cromer, D. T., and Mann, J. B. (1968)Acta Crystallogr. A 24, 321.
Cromer, D. T., and Liberman, D. (1970)J. Chem. Phys. 53, 1891.
Dehnicke, K., Prinz, H., Massa, W., Pebler, J., and Schmidt, R. (1983)Z. Anorg. Allg. Chem. 499, 20.
Drew, M. G. B., McKee, V., and Nelson, S. M. (1978)J. Chem. Soc. Dalton Trans., 80.
Ginsberg, A. P., and Robin, M. B. (1963)Inorg. Chem. 2, 817.
Hewkin, D. T., and Griffith, W. P. (1966)J. Chem. Soc. A, 474.
Meek, D. W., and Drago, R. S. (1961)J. Am. Chem. Soc. 83, 4322.
Murray, K. S. (1974)Coord. Chem. Revs. 12, 1.
Neuse, E. W., and Meirim, M. G. (1984)Transition Met. Chem. 9, 205.
O'Keeffe, D. H., Barlow, C. H., Smythe, G. A., Fuchsman, W. H., Moss, Th. H., Lilienthal, H. R., and Caughey, W. S. (1975)Bioinorg. Chem. 5, 125.
Reiff, W. M., Witten, E. H., Mottle, K., Brennan, T. F., and Garafalo, A. R. (1983)Inorg. Chim. Acta 77, L83.
Schmidbaur, H., Zybill, C. E., and Neugebauer, D. (1983)Angew. Chem. 95, 161;Angew. Chem. Suppl., 169.
Solbrig, R. M., Duff, L. L., Shriver, D. F., and Klotz, I. M. (1982)J. Inorg. Biochem. 17, 69.
Walker, N., and Stuart, D. (1983)Acta Crystallogr. A,39, 158.
Weinland, R. F., and Kissling, A. (1922)Z. Anorg. Allg. Chem. 120, 209.
Weiss, H., and Strähle, J. (1984)Z. Naturforsch. Teil B 39, 1453.
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Neuse, E.W., Khan, F.B.D., Berhalter, K. et al. Diammonium μ-oxobis[trichloroferrate(III)] salts. Crystal and molecular structure of bis(benzyldimethylphenylammonium) μ-oxobis(trichloroferrate). Journal of Crystallographic and Spectroscopic Research 16, 483–493 (1986). https://doi.org/10.1007/BF01161037
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DOI: https://doi.org/10.1007/BF01161037