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Interaction of titanium and iron halides with lithium aluminum hydride in diethyl ether

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the interaction of titanium and iron halides with LiAlH4 at−110°C, the hydroaluminates Ti(AlH4)4 and Fe(AlH4)2 are formed.

  2. 2.

    The thermal decomposition of titanium and iron hydroaluminates was studied, and possible schemes of their decomposition were proposed.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    M. E. Kost & A. L. Golovanova

Authors
  1. M. E. Kost
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  2. A. L. Golovanova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 991–994, May, 1975.

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Kost, M.E., Golovanova, A.L. Interaction of titanium and iron halides with lithium aluminum hydride in diethyl ether. Russ Chem Bull 24, 905–907 (1975). https://doi.org/10.1007/BF00922929

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  • DOI: https://doi.org/10.1007/BF00922929

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