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Einkristallstrukturanalyse vonBis(trimethylsilyl)peroxid

Crystal structure ofbis(trimethylsilyl)peroxide

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Zusammenfassung

Bis(trimethylsilyl)peroxid wurde aus Trimethylchlorsilan, Wasserstoffperoxid und 1,4-Diazobicyclo[2.2.2]octan dargestellt. Ein Einkristall wurdein situ auf einem Vierkreisdiffraktometer gezüchtet und mittels Einkristallstrukturanalyse charakterisiert (T=193(2) K, 2522 Reflexe, P21/c;a=606.7(1) pm,b=1098.5(1) pm,c=858.2(1) pm, β=101.88(2)°,Z=2,R=0.045). Die Konformation des Moleküls im Kristall ist durch C-H...O-Brücken bestimmt.

Summary

Bis(trimethylsilyl)peroxide has been prepared from trimethylchlorsilane, hydrogen peroxide, and 1,4-diazobicyclo[2.2.2]octane. Crystal growth was achievedin situ on a diffractometer and characterized by crystal structure analysis (T=193(2) K, 2522 reflections, P21/c;a=606.7(1) pm,b=1098.5(1) pm,c=858.2(1) pm, β=101.88(2)°,Z=2,R=0.045). The molecule's conformation in the crystalline solid is determined by C-H...O-bridges.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Universität Bonn, D-53121, Bonn, Germany

    D. Königstein & M. Jansen

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  1. D. Königstein
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  2. M. Jansen
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Königstein, D., Jansen, M. Einkristallstrukturanalyse vonBis(trimethylsilyl)peroxid. Monatsh Chem 127, 1221–1227 (1996). https://doi.org/10.1007/BF00807788

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  • DOI: https://doi.org/10.1007/BF00807788

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