Skip to main content
SpringerLink
Log in

Metal exchanged layered zirconium hydrogen phosphate as base catalyst of the Michael reaction

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Layered zirconium hydrogen phosphate, exfoliated by intercalation of propylamine and then exchanged with alkali metal ions has proved to be an excellent catalyst for Michael addition of β-dicarbonyl compounds. The reactions occur with high yield, in mild conditions and with ease of work up. The catalyst, recovered from the reaction vessel, may be reused several times.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Clearfield, ed.,Inorganic Ion Exchange Materials (CRC Press, Boca Raton, 1982); G. Alberti, Accounts Chem. Res. 11 (1978) 163; A. Clearfield, Comments Inorg. Chem. 10 (1990) 89; G. Alberti and U. Costantino, in:Inclusion Compounds, Vol. 5, eds. J.L. Atwood, J.E.D. Davies and D.D. MacNicol (Oxford Univ. Press, Oxford, 1991) p. 136.

    Google Scholar 

  2. A. Clearfield and G.D. Smith, J. Inorg. Chem. 8 (1969) 431.

    Google Scholar 

  3. U. Costantino and A. La Ginestra, Thermochim. Acta 58 (1982) 179.

    Google Scholar 

  4. A. Clearfield and D.S. Thakur, Appl. Catal. 26 (1986) 1, and references therein.

    Google Scholar 

  5. K. Segawa, S. Nakata and S. Asaoka, Mater.Chem.Phys. 17 (1987) 181.

    Google Scholar 

  6. A. La Ginestra, P. Patrono, M.L. Berardelli, P. Galli, C. Ferragina and M.A. Massucci, J. Catal. 103 (1987) 346.

    Google Scholar 

  7. G. Alberti and E. Torracca, J. Inorg. Nucl. Chem. 30 (1968) 317.

    Google Scholar 

  8. F. Marmottini, in:Multifunctional Mesoporous Solids, eds. C.A.C. Sequeira and M.J. Hudson (Kluwer, Amsterdam, 1993) p. 37.

    Google Scholar 

  9. G. Alberti, M. Casciola and U. Costantino, J. Colloid Interf. Sci. 107 (1985) 256.

    Google Scholar 

  10. A. Clearfield and S.P. Pack, J. Inorg. Nucl. Chem. 37 (1975) 1283.

    Google Scholar 

  11. J. Yamawaki, T. Kawate, T. Ando and T. Hanafusa, Bull. Chem. Soc. Japan 56 (1983) 1885.

    Google Scholar 

  12. P. Laszlo, M.T. Montaufier and S.L. Randriamahefa, Tetrahedron Lett. 34 (1990) 4867.

    Google Scholar 

  13. B.C. Ranu, S. Bhar and D.C. Sarkar, Tetrahedron Lett. 24 (1991) 2811.

    Google Scholar 

  14. B.C. Ranu and S. Bhar, Tetrahedron 48 (1992) 1327.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dipartimento di Chimica, Universitàdi Perugia, Via Elce di Sotto, 06123, Perugia, Italy

    U. Costantino & F. Marmottini

  2. Istituto di Chimica Organica, Facoltà di Fannacia, Universitàdi Perugia, Via del Liceo, 06123, Perugia, Italy

    M. Curini & O. Rosati

Authors
  1. U. Costantino
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. Marmottini
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Curini
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. Rosati
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Costantino, U., Marmottini, F., Curini, M. et al. Metal exchanged layered zirconium hydrogen phosphate as base catalyst of the Michael reaction. Catal Lett 22, 333–336 (1993). https://doi.org/10.1007/BF00807241

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00807241

Keywords

Search

Navigation