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The regularities of the gas-chromatographic behavior of methyl-substitutedN-alkylpiperidines

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Abstract

The gas-chromatographic behavior of 2-, 3-, 4-methyl- and 2,6-dimethylpiperidine bases on glass capillary columns with OV-101/KF and PEG-40M/KF at 110 °C has been studied. The contribution of a methyl group to the total molar free energy of Sorption of nonalkylated piperidine bases depends on its position in the piperidine cycle and is the least for positions 2 and 6. The variation in the retention indices of homologousN-alkylpiperidines (C1-C7) is given by a universal type of equation.

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Authors and Affiliations

  1. Institute of Food Substances, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    I. L. Zhuravleva, R. V. Golovnya & T. E. Kuzmenko

Authors
  1. I. L. Zhuravleva
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  2. R. V. Golovnya
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  3. T. E. Kuzmenko
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1754–1757, October, 1993.

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Zhuravleva, I.L., Golovnya, R.V. & Kuzmenko, T.E. The regularities of the gas-chromatographic behavior of methyl-substitutedN-alkylpiperidines. Russ Chem Bull 42, 1677–1679 (1993). https://doi.org/10.1007/BF00697038

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  • DOI: https://doi.org/10.1007/BF00697038

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