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Voltammetric behaviour of rhenium(I) complexes with phosphine and carbon monoxide ligands in acetonitrile solvent

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Summary

The anodic and cathodic behaviour of the complexesmer-[ReCl(CO)3(PMe2Ph)2],fac[ReCl(CO)3(PMe2Ph)2],mer-[ReCl(CO)3(PPh3)2], and [ReCl(CO)2(PMe2Ph)3] in acetonitrile solvent were studied using platinum and mercury electrodes. Cyclic voltammetry and controlled potential coulometry were the main electroanalytical techniques employed. The nature of the electrolysis products and of the electrode oxidation and reduction processes were investigated. In particular, [ReCl(CO)(MeCN)2(PMe2Ph)3][ClO4]2, [ReCl3(CO)2(PMe2Ph)2], and a not completely defined rhenium(-I) complex were electrochemically synthesized and characterized by means of i.r. and1H n.m.r. spectroscopy, and by elemental analysis.

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Authors and Affiliations

  1. Dipartimento di Chimica, Universitá di Siena, Pian dei Mantellini 44, 53100, Siena, Italy

    Renato Seeber

  2. Dipartimento di Spettroscopia ed Elettrochimica, Universitá di Venezia, Dorsoduro 2137, 30123, Venezia, Italy

    Gian Antonio Mazzocchin

  3. Istituto di Chimica e Tecnologia dei Radioelementi del C.N.R., Area della Ricerca, Corso Stati Uniti 5, 35100, Padova, Italy

    Ulderico Mazzi, Edoardo Roncari & Fiorenzo Refosco

Authors
  1. Renato Seeber
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  2. Gian Antonio Mazzocchin
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  3. Ulderico Mazzi
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  4. Edoardo Roncari
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  5. Fiorenzo Refosco
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Seeber, R., Mazzocchin, G.A., Mazzi, U. et al. Voltammetric behaviour of rhenium(I) complexes with phosphine and carbon monoxide ligands in acetonitrile solvent. Transition Met Chem 9, 315–318 (1984). https://doi.org/10.1007/BF00618173

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  • DOI: https://doi.org/10.1007/BF00618173

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