Abstract
Gneisses in the Guri area of the Venezuelan Guayana Shield contain mineral assemblages with cordierite, garnet, sillimanite, hypersthene, biotite and Fe-Ti oxide intergrowths.
Analysis of mineral assemblages and compositional relationships in the light of experimental data indicate metamorphic conditions of 725–800° C, 5–6 kb P T , \(P_{{\text{H}}_{\text{2}} {\text{O}}}\) <P T for the highest grade rocks and 650–700° C, 5–7 kb P T , \(P_{{\text{H}}_{\text{2}} {\text{O}}}\) approximating P T for the lowest grade rocks. Oxygen fugacities in different lithologies ranged between those of the MH and QFM buffers.
The distribution coefficient K D (Mg-Fe) (gar-bio), decreases by 0.006 per atom percent increase in (Mn/Mn+Mg+Fe)gar, falls in the range of K D typical of the sillimanite-K feldspar zone and granulite facies, and is systematically lower in lower grade rocks-all in accord with observation in other localities. K D (Mg-Fe) (cord-bio) ranges from 3.0 in the highest grade rocks to 10.0 in the lowest grade rocks, appears independent of FeO/MgO of cordierite or biotite, and varies systematically with grade. In contrast with conclusions based on observation in other localities, data from the Guri area suggest -KD(cord-bio) may be a sensitive index of grade.
A number of mineralogic and geologic observations are difficultly reconciled with existing experimental data.
Similar content being viewed by others
References
Albee, A. L.: Distribution of Fe, Mg, and Mn between garnet and biotite in natural mineral assemblages. J. Geol. 73, 156–164 (1965)
Albee, A. L., Bingham, E., Chodos, A. A., Maynes, A. D.: Phase equilibria in three assemblages of kyanite-zone pelitic schists, Lincoln Mountain Quadrangle, central Vermont. J. Petrol. 6, 246–301 (1965)
Anderson, A. T.: The oxygen fugacity of alkaline basalts and related magmas, Tristan da Cunha. Am. J. Sci. 266, 704–727 (1968)
Buddington, A. F., Lindsley, D. H.: Iron-titanium oxide minerals and synthetic equivalents. J. Petrol. 5, 310–357 (1964)
Carmichael, C. M.: The magnetic properties of ilmenite-hematite crystals. Proc. Roy. Soc. (London) Ser. A 263, 508–530 (1961)
Chinner, G. A.: Garnet-cordierite paragenesis. Carnegie Inst. Wash. Yearbook 58, 112–114 (1959)
Currie, K. L.: The reaction 3 cordierite=2 garnet+4 sillimanite+5 quartz as a geological thermometer in the Opinicon Lake Region, Ontario. Contr. Mineral. and Petrol. 33, 215–226 (1971)
Dallmeyer, R. D.: Compositional controls on cordierite-bearing assemblages in high-grade regional metamorphism. 24th I.G.C., Section 2, p. 52–63 (1972)
Dallmeyer, R. D., Dodd, R. T.: Distribution and significance of cordierite in paragneisses of the Hudson Highlands, Southeastern New York. Contr. Mineral. and Petrol. 33, 289–308 (1971)
Fabbi, B. P.: A refined fusion x-ray fluorescence technique and determination of major and minor elements in silicate standards. Am. Mineralogist 57, 237–245 (1972)
French, B. M.: Progressive contact metamorphism of the Biwabik iron-formation, Mesabi Range, Minnesota. Minnesota Geol. Surv. Bull. 45, 103p (1968)
French, B. M., Eugster, H. P.: Experimental control of oxygen fugacities by graphite-gas equilibriums. J. Geophys. Res. 70, 1529–1539 (1965)
Gable, D. J., Sims, P. K.: Geology and regional metamorphism of some high-grade cordierite gneisses, Front Range, Colorado. Geol. Soc. Am. Spec. Papers 128, 87p (1969)
Gorbatschev, R.: Distribution of elements between cordierite, biotite, and garnet. Neues Jahrb. Mineral. Abhandl. 110, 57–80 (1968)
Hensen, B. J., Green, D. H.: Experimental study of the stability of cordierite and garnet in politic compositions with excess alumino-silicate. Contr. Mineral. and Petrol. 33, 309–330 (1971)
Hensen, B. J., Green, D. H.: Experimental study of the stability of cordierite and garnet in pelitic compositions at high pressures and temperatures. II. Compositions without excess alumino-silicate. Contr. Mineral. and Petrol. 35, 331–354 (1972)
Hensen, B. J., Green, D. H.: Experimental study of the stability of cordierite and garnet in politic compositions at high pressures and temperature. III. Synthesis of experimental data and geological applications. Contr. Mineral. and Petrol. 38, 151–166 (1973)
Hess, P. C.: Prograde and retrograde equilibria in garnet-cordierite gneisses in south-central Massachusetts. Contr. Mineral. and Petrol. 30, 177–195 (1971)
Hsu, L. C., Burnham, C. W.: Phase relationships in the system Fe3Al2Si3O12-Mg3Al2Si3O12at 2.0 kilobars. Geol. Soc. Am. Bull. 80, 2393–2408 (1969)
Kalliokoski, J.: Geology of the north-central Guayana Shield, Venezuela. Geol. Soc. Am. Bull. 76, 1027–1050 (1965)
Kerrick, D. M.: Experimental determination of muscovite+quartz stability with \(P_{{\text{H}}_{\text{2}} {\text{O}}} \overline <\)Ptotal. Am. J. Sci. 272, 946–958 (1972)
Kretz, R.: Some applications of thermodynamics to coexisting minerals of variable composition. Examples: orthopyroxene-clinopyroxene and orthopyroxene-garnet. J. Geol. 69, 361–387 (1961)
Kullerud, G., Yoder, H. S.: Pyrite stability relations in the Fe-S system. Econ. Geol. 54, 533–572 (1959)
Lal, R. K., Moorhouse, W. W.: Cordierite-gedrite rocks and associated gneisses of Fishtail Lake, Harcourt Township, Ontario. Can. J. Earth Sci. 6, 145–165 (1969)
Lindsley, D. H.: Equilibrium relations of coexisting pairs of Fe-Ti oxides. Carnegie Inst. Wash. Yearbook 62, 60–66 (1963)
Lindsley, D. H.: Delimination of the hematite-ilmenite miscibility gap. Geol. Soc. Am. Bull. 84, 657–662 (1973)
Lyons, J. B., Morse, S. A.: Mg/Fe partitioning in garnet and biotite from some granitic, politic and calcic rocks. Am. Mineralogist 55, 231–246 (1970)
Okrusch, M.: Garnet-cordierite-biotite equilibria in the Steinach Aureole, Bavaria. Contr. Mineral. and Petrol. 32, 1–23 (1971)
Peck, L. C.: Systematic analysis of silicates. U.S. Geol. Surv. Bull. 1170, 89p (1964)
Rose, H. J., Adler, I., Flanagan, F. J.: X-ray fluorescence analysis of the light elements in rocks and minerals. Appl. Spectr. 17, 81–85 (1963)
Rumble, D.: Thermodynamic analysis of phase equilibria in the system Fe2TiO4-Fe3O4-TiO2. Carnegie Inst. Wash. Yearbook 69, 198–207 (1970)
Rumble, D.: Fe-Ti oxide minerals and the behavior of oxygen during regional metamorphism. Carnegie Inst. Wash. Yearbook 70, 157–165 (1971)
Richardson, S. W.: Staurolite stability in a part of the system Fe-Al-Si-O-H. J. Petrol. 9, 467–488 (1968)
Saxena, S. K.: Distribution of elements among coexisting minerals and the nature of solid solution in garnet. Am. Mineralogist 53, 994–1014 (1968)
Saxena, S. K., Hollander, N. B.: Distribution of iron and magnesium in coexisting biotite, garnet, and cordierite. Am. J. Sci. 267, 210–216 (1969)
Schreyer, W., Seifert, F.: Compatibility relations of the aluminium silicates in the systems MgO-Al2O3-SiO2H2O and K2O-MgO-Al2O3-SiO2-H2O at high pressures. Am. J. Sci. 267, 371–388 (1969)
Thompson, J. B.: The graphical analysis of the mineral assemblages in pelitic schists. Am. Mineralogist 42, 842–858 (1957)
Vernon, R. H.: Reactions involving hydration of cordierite and hypersthene. Contr. Mineral. and Petrol. 35, 125–137 (1972)
Vincent, E. A., Wright, J. B., Chevallier, R., Mathieu, S.: Heating experiments on some natural titaniferous magnetites. Mineral. Mag. 31, 624–655 (1957)
Webster, A. H., Bright, N. F. H.: The system iron-titanium-oxygen at 1200° C and oxygen partial pressures between 1 atm and 2×10−14 atm. J. Am. Ceram. Soc. 44, 110–116 (1961)
Weisbrod, A.: Cordierite-garnet equilibrium in the system Fe-Mn-Al-Si-O-H. Carnegie Inst. Wash. Yearbook 72, 515–518 (1973)
Weisbrod, A.: Refinements of the equilibrium conditions of the reaction Fe Cordierite⇌Al-mandine+Quartz+Sillimanite (+H2O). Carnegie Inst. Wash. Yearbook 72, 518–521 (1973)
Winkler, H. G. F.: Petrogenesis of metamorphic rocks, 2nd edition, 237p. New York: Springer 1967
Wynne-Edwards, H. R., Hay, P. W.: Coexisting cordierite and garnet in regionally-metamorphosed rocks from the Westport area, Ontario. Can. Mineralogist 71, 453–478 (1963)
Wones, D. R., Eugster, H. P.: Stability of biotite: Experiment theory, application. Am. Mineralogist 50, 1228–1272 (1965)
Wood, B. J.: Fe2+-Mg2+ partitioning between coexisting cordierite and garnet. A discussion of the experimental data. Contr. Mineral. and Petrol. 40, 253–258 (1973)
Yund, R. A., Kullerud, G.: Thermal stability of assemblages in the Cu-Fe-S system. J. Petrol. 7, 454–488 (1966)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dougan, T.W. Cordierite gneisses and associated lithologies of the Guri area, Northwest Guayana Shield, Venezuela. Contr. Mineral. and Petrol. 46, 169–188 (1974). https://doi.org/10.1007/BF00487554
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00487554