Abstract
Organoammonium-montmorillonite intercalation compounds were prepared by solid-state ion exchange reactions which we have developed recently in order to understand the nature of the solid-state intercalation reactions. The reactions were carried out by grinding the mixtures of homoionic-montmorillonites and organoammonium (dodecyltrimethylammonium, tetramethylammonium, and tetrabutylammonium) halides (chloride, bromide, and iodide) at room temperature. Both of the counter anions of the organoammonium salts and the interlayer exchangeable cations of montmorillonite are concerned with the solid-state ion exchange reactions, indicating that the solid-solid reactions are thermodynamically governed. The solid-state ion exchange reactions lead to novel and different reactivities and intercalation compounds from those of conventional solution methods.
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References
G.A. Ozin, Adv. Mater. 4, 612 (1992).
B.M. Barrer, Zeolites and Clay Minerals as Sorbents and Molecular Sieves (Academic Press: London, 1978).
B.K.G. Theng, The Chemistry of Clay-Organic Reactions (Adam Hilger: London, 1974).
G. Lagaly, Clay Miner. 16, 1 (1981), G. Lagaly, Solid State Ionics 22, 43 (1986).
J.W. Jordan, J. Phys. Colloid Chem. 54, 294 (1950).
S.V. Bondarenko, A.I. Zhukova, and YuI. Tarasevich, J. Chromatogr. 241, 281 (1982).
J.F. Lee, M.M. Mortland, S.A. Boyd, and C.T. Chiou, J. Chem. Soc., Faraday Trans. 1 85, 2953 (1989).
S.A. Boyd, J.F. Lee, and M. Mortland, Nature 333, 345 (1988).
A. Cornelis and P. Laszlo, Synthesis, 162 (1982).
T.R. Jones, Clay Miner. 18, 399 (1983).
M. Ogawa, T. Handa, K. Kuroda, C. Kato, and T. Tani, J. Phys. Chem. 96, 8116 (1992), M. Ogawa, M. Takahashi, C. Kato, and K. Kuroda, J. Mater. Chem. 4, 519 (1994), M. Ogawa, M. Takahashi, and K. Kuroda, Chem. Mater. 6, 715 (1994), T. Seki, and K. Ichimura, Macromolecules 23, 31 (1990).
O. Patil, D.Y. Curtin, and I.C. Paul, J. Am. Chem. Soc. 106, 348 (1984), W.E. Brown, D. Dollimore, and A.K. Galwey, in Comprehensive Chemical Kinetics Vol. 22, C.H. Bamford and C.F.H. Tipper, eds. (Elsevier: Amsterdam, 1980).
F. Toda, K. Tanaka, and A. Sekikawa, J. Chem. Soc., Chem. Commun. 1987, 279.
M. Ogawa, K. Kuroda, and C. Kato, Chem. Lett. 1659 (1989).
M. Ogawa, K. Kato, K. Kuroda, and C. Kato, Clay Sci. 8, 31 (1990).
M. Ogawa, T. Handa, K. Kuroda, and C. Kato, Chem. Lett. 71 (1990).
M. Ogawa, T. Hashizume, K. Kuroda, and C. Kato, Inorg. Chem. 30, 584 (1991).
M. Ogawa, K. Fujii, K. Kuroda, and C. Kato, Mater. Res. Soc. Symp. Proc. 233, 89 (1991).
M. Ogawa, M. Hirata, K. Kuroda, and C. Kato, Chem. Lett. 365 (1992).
M. Ogawa, Y. Nagafusa, K. Kuroda, and C. Kato, Appl.Clay Sci. 7, 291 (1992).
M. Ogawa, H. Shirai, K. Kuroda, and C. Kato, Clays Clay Miner 40, 485 (1992).
M. Ogawa, T. Aono, K. Kuroda, and C. Kato, Langmuir 9, 1529 (1993).
M.A. Vicente, M. Sánchez-Camazano, M.J. Sánchez-Martín, M. Del Arco, C. Martín, V. Rives, and J. Vicente-Hernández, Clays Clay Miner. 37, 157 (1989).
M. Crocker, R.H.M. Herold, C.A. Emeis, and M. Krijger, Ctal. Lett. 15, 339 (1992).
J. Bujdák and H. Slosiariková, Appl. Clay Sci. 7, 263 (1992).
A.V. Kucherov and A.A. Slinkin, Zeolites 6, 175 (1986).
A.V. Kucherov and A.A. Slinkin, Zeolites 7, 38 (1987).
A.V. Kucherov and A.A. Slinkin, Zeolites 7, 43 (1987).
H.K. Beyer, H.G. Karge, and G. Borbery, Zeolites 8, 79 (1988).
H.G. Karge, H.K. Beyer, and G. Borbery, Catalysis Today 3, 41 (1988).
S. Beran, B. Wichterlova, and H.G. Karge, J. Chem. Soc. Faraday Trans. 86, 3033 (1990).
H. Eseman and H. Förster, J. Chem. Soc. Chem. Commun. 1319 (1994).
Y. Sugahara, K. Kuroda, and C. Kato, J. Am. Ceram. Soc. 67, C-247 (1987).
T.C. Waddington, Advances in Inorganic Chemistry and Radiochemistry, H.J. Emeleus and A.G. Sharpe, eds. (Academic Press, New York, 1959) p. 190.
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Ogawa, M., Hagiwara, A., Handa, T. et al. Solid-state ion exchange reactions between homoionic-montmorillonites and organoammonium salts. J Porous Mater 1, 85–89 (1995). https://doi.org/10.1007/BF00486527
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DOI: https://doi.org/10.1007/BF00486527