Skip to main content
SpringerLink
Log in

Decomposition of carbon dioxide to carbon by hydrogen-reduced Ni(II)-bearing ferrite

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Hydrogen-activated Ni(II)-bearing ferrite, Ni 2+0.37 Fe 2+0.49 Fe 3+2.09 O4.00, showed a high rate of decomposition of carbon dioxide to carbon at 300°C. This is based on the redox process of the Ni(II)-bearing ferrite with the spinel type of crystal structure. The rates of both activation by hydrogen gas and oxidation in carbon dioxide gas were much improved in the Ni (II)-bearing ferrite. The rate of decomposition was 0.178 mol h−1 for the activated Ni(II)-bearing ferrite and 0.005 92 mol h−1 for the activated magnetite in the batch mode, being 30 times larger. The rate of carbon dioxide decomposition was 16 times higher in the flow system in comparison with that of the activated magnetite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. SACCO, Jr and R. C. REID, Carbon 17 (1979) 459.

    Article  CAS  Google Scholar 

  2. R. C. WAGNER, R. CARRASQUILLO, J. EDWARDS and R. HOLMES, in “Proceedings of 18th Intersociety Conference on Environmental Systems”, SAE Technical Paper Series 880995, Society of Automotive Engineers, Warrendale PA (1988).

    Google Scholar 

  3. M. LEE, J. LEE and C. CHANAG, J. Chem. Eng. Jpn 23 (1990) 130.

    Article  CAS  Google Scholar 

  4. Y. TAMAURA and M. TABATA, Nature 346 (1990 225.

    Article  Google Scholar 

  5. K. NISHIZAWA, T. KODAMA, M. TABATA, T. YOSHIDA, M. TSUJI and Y. TAMAURA, J. Chem. Soc. Farad. Trans. 88 (1992) 2771.

    Article  CAS  Google Scholar 

  6. M. TABATA, Y. NISHIDA, T. KODAMA, K. MIMORI, T. YOSHIDA and Y. TAMAURA, J. Mater. Sci. 28 (1993) 971.

    Article  CAS  Google Scholar 

  7. M. TABATA, K. AKANUMA, K. NISHIZAWA, T. YOSHIDA, M. TSUJI and Y. TAMAURA, ibid. 28 (1993) 6753.

    Article  CAS  Google Scholar 

  8. T. KODAMA, K. TOMINAGA, M. TABATA, T. YOSHIDA and Y. TAMAURA, J. Amer. Ceram. Soc. 75 (1992) 1287.

    Article  CAS  Google Scholar 

  9. K. AKANUMA, M. TABATA, T. YOSHIDA, M. TSUJI and Y. TAMAURA, J. Mater. Chem., 3 (1993) 943.

    Article  CAS  Google Scholar 

  10. Y. TAMAURA, S. MECHAIMONCHIT and T. KATSURA, J. Inorg. Nucl. Chem. 43 (1980) 671.

    Article  Google Scholar 

  11. T. KATSURA, Y. TAMAURA and G. S. CHYO, Bull. Chem. Soc. Jpn 52 (1979) 96.

    Article  CAS  Google Scholar 

  12. Y. TAMAURA, P. V. BUDUAN and T. KATSURA, J. Chem. Soc. Dalton Trans. (1981) 1807.

  13. M. KIYAMA, Bull. Chem. Soc. Jpn 47 (1974) 1646.

    Article  CAS  Google Scholar 

  14. K. A. KRAUS and G. E. MOORE, J. Am. Chem. Soc. 75 (1953) 1460.

    Article  CAS  Google Scholar 

  15. T. KODAMA, J. Mater. Chem. 2 (1992) 525.

    Article  CAS  Google Scholar 

  16. R. D. WALDRON, Phys. Rev. 99 (1955) 1972.

    Article  Google Scholar 

  17. T. MISAWA, K. HASHIMOTO and S. SHIMODAIRA, Boshoku Gijutsu (Corros. Eng.) 23 (1974) 17.

    CAS  Google Scholar 

  18. H. FRANKE and M. ROSENBERG, J. Magn. Mag. Mater. 9 (1979) 74.

    Article  Google Scholar 

  19. K. VOLENÍK, M. SEBERÍNI and J. NEID, Czech. J. Phys. B25 (1975) 1063.

    Article  Google Scholar 

  20. M. ROBBINS, G. K. WERTHEIM, R. C. SHERWOOD and D. N. E. BUCHANAN, J. Phys. Chem. Solids 32 (1971) 717.

    Article  CAS  Google Scholar 

  21. K. AKANUMA, K. NISHIZAWA, T. KODAMA, M. TABATA, K. MIMORI, T. YOSHIDA, M. TSUJI and Y. TAMAURA, J. Mater. Sci. 28 (1993) 860.

    Article  CAS  Google Scholar 

  22. J. G. McCARTY and H. WISE, J. Catal. 57 (1979) 406.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Research Center for Carbon Recycling and Utilization, Tokyo Institute of Technology, 2-12-1, Ookayama, Meguro-ku, 152, Tokyo, Japan

    H. Kato, T. Kodama, M. Tsuji & Y. Tamaura

  2. Lawrence Berkeley Laboratory, University of California, 1 Cyclotron Road, 94720, Berkeley, CA, USA

    S. G. Chang

Authors
  1. H. Kato
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Kodama
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Tsuji
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Y. Tamaura
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. G. Chang
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kato, H., Kodama, T., Tsuji, M. et al. Decomposition of carbon dioxide to carbon by hydrogen-reduced Ni(II)-bearing ferrite. JOURNAL OF MATERIALS SCIENCE 29, 5689–5692 (1994). https://doi.org/10.1007/BF00349965

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00349965

Keywords

Search

Navigation