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FTIR spectroscopy of polymer films under uniaxial stretching

2. Amorphous and semicrystalline poly(ethyleneterephthalate)

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Summary

The FTIR changes in films of amorphous and semicrystalline poly(ethylene-terephthalate), PET, were registrated during uniaxial stretching at small deformations (1%–25%). The accompaning frequency shifts of vibrational bands of benzene ring and glycol residue are analysed. It was shown that the deformation behaviour of the band shifts strongly depends on phase and morphology of polymer sample. High pressure and temperature effects on IR spectra of PET are also discussed.

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Author notes

  1. S. N. Magonov

    Present address: Freiburger Metallforschungszentrum der Universität, Stefan-Meier-Strasse 31, W-7800, Freiburg, Germany

Authors and Affiliations

  1. Institute of Chemical Physics of the USSR Academy of Sciences, Kosygina Str. 4, SU-117977, Moscow, USSR

    S. S. Sheiko, I. S. Vainilovitch & S. N. Magonov

Authors
  1. S. S. Sheiko
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  2. I. S. Vainilovitch
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  3. S. N. Magonov
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Sheiko, S.S., Vainilovitch, I.S. & Magonov, S.N. FTIR spectroscopy of polymer films under uniaxial stretching. Polymer Bulletin 25, 499–506 (1991). https://doi.org/10.1007/BF00310242

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  • DOI: https://doi.org/10.1007/BF00310242

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