Summary
Polytetrahydrofuran macroinimers were synthesized by means of cationic polymerization of tetrahydrofuran, initiated by azo-oxocarbenium salt, followed by termination with methacrylate anion. The macroinimers were characterized by 1H-NMR analysis and GPC measurements. Self polymerization of macroinimers and copolymerization with methyl methacrylate (MMA) yielded crosslinked and soluble branched block copolymers depending on the MMA concentration.
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Baskan, A., Denizligil, S. & Yagci, Y. Polytetrahydrofuran macroinimer. Polymer Bulletin 36, 27–34 (1996). https://doi.org/10.1007/BF00296004
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DOI: https://doi.org/10.1007/BF00296004