Abstract
The synthesis of a series of soluble 5-alkoxy substituted isophthalamides is described. Condensation of 1,3-diaminobenzene or 2,6-diaminopyridine with alkoxy substituted isophthaloylchlorides yields the title polyaramides. The influence of the alkyl chain length on the supramolecular structure of the polymer is investigated by X-ray diffraction experiments. Initial results indicate a lamellar type solid lattice for the polymers studied here.
Similar content being viewed by others
References
P.W. Morgan, Macromolecules, 1977, 10, 138.
P.W Morgan, Chemtech, 1979, 316.
P.W. Morgan. J. Poly. Sci., Poly. Symp., 1985, 72, 27.
J. Preston, Kork-Othmer, Encyclopedia of Chemical Technology, 3rd Edn., Edr. M. Grayson and D. Eckroth, Wiley Intersciences, New York, 1978, 3, 213.
W. Bruce-Black and J. Preston, High Modulus Wholly Aromatic Fibers, Dekker, New York, 1973
W. Wang, M.C. Hund, G. Wegner and G. Lieser, Polymer, 1993, 34, 3247
H.R. Kricheldorf, B. Schmidt and R. Bürger, Macromolecules, 1992, 25, 5465.
D.H. Schönherr and J.H. Wendorff, Makromol. Chem., Rapid Commun., 1986, 7, 791.
T.I. Bair, P.W. Morgan and E.L. Killian, Macromolecules, 1977, 10, 1396.
H. Kakida, Y. Chatani and H. Tadokoro, J. Poly. Sci., Poly. Phys. Ed., 1976, 14, 427.
M.G. Northolt, Eur. Poly. J., 1974, 10, 799.
K. Tashiro, M. Kobayashi and H. Tadokoro, Macromolecules, 1977, 10, 413.
S. Valiyaveettil, V. Enkelmann and K. Müllen, J. Chem. Soc., Chem. Commun., 1994, in press.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Valiyaveettil, S., Gans, C., Klapper, M. et al. Synthesis and structural study of poly(isophthalamide)s. Polymer Bulletin 34, 13–19 (1995). https://doi.org/10.1007/BF00294881
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00294881