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Acid/Base Functionalized Hybrid Porous Materials: Potential Catalysts for Industrially Important Chemical Transformation

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Advances in Spectroscopy: Molecules to Materials

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 236))

Abstract

Mesoporous, ordered MCM-48, MCM-41 and SBA-15, types of siliceous materials are demanding for their applications in various fields, particularly in the catalysis area. Functionalization of these materials with different substitutes increases their acceptability in the chemical industry. A series of acid/base functionalized porous materials were synthesized and thoroughly characterized to confirm their functionalization. Catalytic behaviour was studied in transesterification of triacetin using methanol. Acidity and basicity were estimated using TG-DTA and correlated their catalytic activities. Accessibility of active sites was also estimated by calculating turn over frequency. Comparison between acid and base functionalized materials was performed.

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Authors and Affiliations

  1. Institute of Infrastructure, Technology, Research and Management, IITRAM, Maninagar, Ahmedabad, Gujarat, India

    Mahuya Bandyopadhyay & Divya Jadav

Authors
  1. Mahuya Bandyopadhyay
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  2. Divya Jadav
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Correspondence to Mahuya Bandyopadhyay .

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Editors and Affiliations

  1. Department of Physics, Institute of Infrastructure Technology Research And Management, Ahmedabad, Gujarat, India

    Dheeraj Kumar Singh

  2. Department of Chemistry, Institute of Infrastructure Technology Research And Management, Ahmedabad, Gujarat, India

    Sourav Das

  3. Department of Physics and Earth Science, Jacobs University Bremen gGmbH, Bremen, Germany

    Arnulf Materny

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Bandyopadhyay, M., Jadav, D. (2019). Acid/Base Functionalized Hybrid Porous Materials: Potential Catalysts for Industrially Important Chemical Transformation. In: Singh, D., Das, S., Materny, A. (eds) Advances in Spectroscopy: Molecules to Materials. Springer Proceedings in Physics, vol 236. Springer, Singapore. https://doi.org/10.1007/978-981-15-0202-6_14

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  • DOI: https://doi.org/10.1007/978-981-15-0202-6_14

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  • Print ISBN: 978-981-15-0201-9

  • Online ISBN: 978-981-15-0202-6

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