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Biomass Fractionation by Hot Compressed Liquid Water

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Advances in Thermochemical Biomass Conversion

Abstract

Samples of six woody and four herbaceous biomass species were washed with compressed, liquid water for 0 to 15 minutes at 200°–230°C. Between 40 and 60% of the sample mass was solubilized. In all cases, 100% of the hemicellulose was solubilized, of which 90% (on average) was recoverable as monomeric sugar. Concurrently, between 4–22% of the cellulose and 35–60% of the lignin were also solubilized. The solvolysis process is so facile that the results are practically independent of temperature and time within the range studied. The observed variations occurred primarily as a function of species. High lignin solubilization apparently reduced the ability to recover hemicellulose sugar.

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References

  1. Bobleter, O., Niesner, R. and Rohr, M., The hydrothermal degradation of cellulosic matter to sugars and their fermentative conversion to protein. J ADO. Polym. Sci., 1976, 20, 2083–2093.

    CAS  Google Scholar 

  2. Pou-Ilinas, J., Driguez, H., Excoffier, G., Vignon, M. and Canellas, J., Steam pretreatment of almond shells for xylose production. Carbohydrate Research 1990, 207, 126–130.

    Article  CAS  Google Scholar 

  3. Abatzoglou, N., Koeberle, P.G., Chornet, E., Overend, R.P. and Koukios, E.G., Dilute acid hydrolysis of lignocellulosics: An application to medium consistency suspensions of hardwoods using a plug flow reactor. Can. Chem. Eng. 1990, 68 627–638.

    Google Scholar 

  4. Heitz, M., Capek-Menard, E., Koeberle, P.G., Gange, J., Chornet, E. Overend, R.P., Taylor, J.D. and Yu, E., Fractionation of populus tremuloides at the pilot plant scale: Optimization of steam pretreatment conditions using the STAKE II technology. Bioresource Technology 1991, in press.

    Google Scholar 

  5. Mok, W. and Antal, M.J., Uncatalyzed solvolysis of whole biomass hemicellulose by hot compressed liquid water. had, Eng. Chem. Res., 1992, 31, 1157–1161.

    Google Scholar 

  6. Freund, J.E., Mathematical Statistics. 2nd Edition, Prentice-Hall International, Inc., 1972, p. 382.

    Google Scholar 

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© 1993 Springer Science+Business Media Dordrecht

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Mok, W.SL., Antal, M.J. (1993). Biomass Fractionation by Hot Compressed Liquid Water. In: Bridgwater, A.V. (eds) Advances in Thermochemical Biomass Conversion. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1336-6_128

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  • DOI: https://doi.org/10.1007/978-94-011-1336-6_128

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4582-7

  • Online ISBN: 978-94-011-1336-6

  • eBook Packages: Springer Book Archive

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