Abstract
Catalysis by transition metal compounds in solution or supported on solids is an active field of research of considerable interest. It is worthwile to recall that transition metal ions were found active and selective for a great number of reactions among them, oxidation of ethylene to acetaldehyde, hydroformylation of olefins to aldehydes, carbonylation and homologation of alcohols, hydrogenation and isomerisation of olefins, oligomerisation and cyclodimerisation of olefins, water gas shift reaction ... etc. In recent years a new area of research developed which consisted to anchor or immobilize to a solid support a soluble transition metal complex to produce a potential active and selective new type of heterogeneous catalyst. In addition it is thought that relationship between homogeneous and heterogeneous catalysis may be found through the studies of such heterogeneized catalysts. Several distinct ways for “heterogeneizing homogeneous catalysts” have been proposed. One approach was to anchor the soluble metal complex to an oxide surface either through surface oxygen bond resulting from the reaction of the metal ligands with hydroxyl groups, or by ligand exchange with functionalized oxide surface. An alternative means for converting homogeneous metal complexes into heterogeneous catalysts is to introduce the active complex into the intercrystal space of a layer lattice silicate by exchanging the Na+ cations of the layer silicate by cationic transition metal ions.
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References
J. A. Rabo ed. Zeolite Chemistry and Catalysis, ACS monograph, 171 (1976).
J. H. Lunsford, Catalysis Review, 12, 137 (1975).
C. Naccache and Y. Ben Taarit, Acta Physica et Chemica, Hungaria 24, 23 (1978).
J. H. Lunsford, “Molecular Sieves II” (J. R. Katzer ed.) 40, 39 (1977).
G. K. Boreskov and Kh. M. Minachev “Application of zeolites in Catalysis”, Akademiai Kiado, Budapest (1979).
C. Naccache and Y. Ben Taarit, Pure and Appl. Chem., 52, 2175, (1980).
Y. Ben Taarit and M. Che, in “Catalysis by zeolites” (B. Imelik et al. eds), Elsevier Co, Amsterdam (1980), p. 167.
P. Gelin, F. Lefebvre, B. Elleuch, C. Naccache and Y. Ben Taarit, Intra zeolitic symposium. Meeting of the American Chemical Soc., Kansas City Missouri, A.C.S. Symposium Series, 218 (1983), p. 455.
A. Cremers, Molecular Sieves II (J.R. Katzer ed.), A.C.S. Symposium Series, 40, 179 (1977).
Hsu Rhu Reng and Yu Guo Chen, Proc. Fifth Int. Conference on Zeolites (ed. L.V. Rees) Heyden London (1980), p. 231.
K.G. Ione, P. N. Kuznetsov, V. N. Romannikov, Application of zeolites to catalysis (eds G. K. Boreskov, Kh. M. Minachev) Akad. Kiodo, Budapest (1979), p. 87.
V. F. Anufrienko et al., Application of zeolites to catalysis (eds G.K. Boreskov, Kh. M. Minachev) Akad. Kiodo, Budapest, (1979), p. 109.
A. M. Rubinstein, A. A. Slinkin, M. I. Loktev, E. A. Fedorovskaya, H. Bremer, F. Vogt, Z. Anorg. Alg. Chem. 423, 164 (1976).
A. H. Badran, J. Dwyer, N. P. Evmerides and J. A. Manford, Inorg. Chim. Acta, 21, 61, (1977).
J. R. Pearce, D. E. Sherwood, M. B. Hall and J. H. Lunsford, J. Phys. Chem., 84, 3215 (1980).
J. R. Pearce, W. J. Mortier and J. B. Uytterhoeven, J. Chem. Soc. Faraday Trans I, 77, 937 (1981).
J. A. Rabo, V. Schomaker and P. E. Pickert, Proceedings 3rd Int. Congr. Catal., North Holland, Amsterdam, p. 1264 (1965).
P. Gallezot, Catal. Rev. Sc. Eng., 20, 121 (1979).
C. Naccache, J. F. Dutel and M. Che, J. Catal. 29, 179 (1973).
P. Gallezot and G. Bergeret, Metal microstructures in zeolites (eds P. A. Jacobs, N. I. Jaeger, P. Jiru, G. Schylz-Ekloff), Studies in Surface Sciences and Catalysis, Elsevier Amsterdam, 12, p. 167 (19
B. Christensen and M. Scurrel, J.C.S. Faraday I, 73, 2036, (1977).
Y. Okamoto, N. Ishida, T. Imanaka, S. Teranishi, J. Catal., 58, 82, (1979).
R. Shannon et al., to be published.
C. Naccache, Y. Ben Taarit, M. Boudart, A.C.S. Symp. Ser., 40, 156 (1972).
P. Gelin, M. Dufaux, C. Naccache, “Catalysis by zeolites (B. Imelik et al. eds) Elsevier Amsterdam, p. 261 (1980).
J. H. Lunsford “Metal microstructures in zeolites” (P. A. Jacobs et al. eds) Elsevier Amsterdam, p. 1 (1982).
R. M. Barrer, Nature, 164, 112 (1949).
T. M. Troup, A. Clearfield, J. Phys. Chem. 74, 2578, (1970).
P. S. E. Dai, J. Lunsford, J. Catal., 64, 173, (1980).
J. Scherrer, D. Fort, J. Catal., 71, 111 (1981).
P. Gallezot, G. Coudurier, M. Primet, B. Imelik, Molecular Sieves (J. Katzer ed.), A.C.S. Symposium Series 40, p. 144 (1977).
D. Ballivet-Tkatchenko, G. Coudurier, Nguyen Due Chau, Metal microstructures in zeolites (P. A. Jacobs et al. eds) Elsevier Amsterdam, p. 123 (1982).
Th. Bein, P. A. Jacobs, F. Schmidt, Metal Microstructures in zeolites (P. A. Jacobs et al. eds) Elsevier Amsterdam p. 111 (1982).
K. M. Minachev, G. V. Antoshin, E. S. Shpiro, T. A. Navruzov, Isv. Akad. Nauk. SSR, Ser. Khim 2131 (1973).
K. H. Minachev, G. V. Antoshin, E. S. Shpiro, Y. A. Yusifov, Proc. 6th Inter. Congress. Catal., London 1976 (G.C. Bond, F.C. Thompkins eds), vol. 2, p. 621, Chemical Soc. (1977).
M. Primet, J. C. Vedrine, C. Naccache, J. Mol. Catal., 4, 411, (1978).
S. Lars, T. Anderson, M. S. Scurrell, J. Catal., 71, 233 (1981).
M. Niwa, J. H. Lunsford, J. Catal., 75, 302 (1982).
J. W. Ward in Zeolite Chemistry and Catalysis (J.A. Rabo ed.) A.C.S. Monograph 171, p. 118 (1976).
J. Morice, L. V. C. Rees, Trans. Farad. Soc. 64, 1388 (1977).
R. L. Garten, W. N. Delgass, M. Boudart, J. Catal. 18, 90 (1970).
P. H. Kasai, R. J. Bishop, J. Phys. Chem., 81, 1527 (1977).
C. Naccache, Y. Ben Taarit, Acta Physica et Chemica Hungaria 24, 23 (1978).
J. J. Verdonck, R. A. Schoonheydt, P. Jacobs, J. Phys. Chem. 85, 2393, 1981.
C. P. Madhusudhan, M. D. Patil, M. L. Good Inorg. Chem. 18, 2383 (1979).
M. Goldwasser, A. Abou Kais, J. F. Dutel, C. Naccache, to be published.
R. F. Howe, J. H. Lunsford, J. Phys. Chem., 79, 1836, (1975).
Y. Ben Taarit, J. C. Vedrine, J. F. Dutel, C. Naccache. J. Magn. Resonance
P. H. Kasai and R. J. Bishop, Jr., J. Phys. Chem., 77, 2308, (1973).
C. Naccache and Y. Ben Taarit, J. Chem. Soc. Farad. Trans. I 69, 1475 (1973).
J. W. Jermyn, T. J. Johnson, E. F. Vansant and J. H. Lunsford, J. Phys. Chem., 77, 2964 (1977).
J. W. Ward, in “Zeolite Chemistry and Catalysis” (J. A. Rabo ed.) A.C.S. Monograph 171, p. 118 (1976).
P. Gelin, G. Coudurier, Y. Ben Taarit, C. Naccache, J. Catal., 70, 32, (1981).
E. Montovani, N. Palladino and A. Zanobi, J. Mol. Catal. 3, 285, (1977).
P. Gelin, Y. Ben Taarit, C. Naccache, J. Catal. 59, 357, (1979).
J. R. Anderson, Structure of Metallic catalysts, Academic Press London (1978).
T. A. Dorling, B. W. J. Lynch and R. L. Moss, J. Catal. 20, 190 (1971).
J. A. Rabo, V. Schomaker and P. E. Pickert, Proc. Int. Congress Catal. 3rd, 2, 1264 (1964).
R. A. Dalla Betta and M. Boudart, Proc. Int. Congress Catal., 5th North Holland Pub. 2, 1329 (1973).
P. Gallezot, J. Datka, J. Massardier, M. Primet and B. Imelik, Proc. Intern. Cong. Catal. 6th, 696 (1976).
C. Naccache, N. Kaufherr, M. Dufaux, J. Bandiera and B. Imelik, A.C.S. Symposium Series 40, Molecular Sieves-II (ed. Katzer, J.R.) 538 (1977).
P. Gallezot, Catal. Rev. Sci. Eng., 20, 121 (1979).
C. W. Kruse and R. F. Kleinschmidt, J. Am. Chem. Soc., 83, 213 (1961).
R. S. Neale, L. Elek and R. E. Malz Jr., J. Catal., 27, 432 (1972).
P. Pichat, J. C. Vedrine, P. Gallezot and B. Imelik, J. Catal., 32, 790 (1974).
Y. Okamoto, N. Ishida, T. Imanaka and S. Teranishi, J. Catal., 58, 82 (1979).
R. Cramer, J. Am. Chem. Soc. 87, 4717 (1965).
U.S. Patent 3, 444, 253 (1969) and 3, 497, 462 (1970) to Union Carbide Corp. ii)_H. Reimlinger, U. Krüerke and E. Ruiter, Chem. Ber. 103, 2317 (1970).
P. Heimbach, P. W. Jolly and G. Wilke, advan. Organometal. Chem., 8, 29 (1970).
I.E. Maxwell, R. S. Downing and S. A. J. Van Laugen, J. Catal. 61, 485 (1980).
C. Naccache and Y. Ben Taarit, J. Catal. 41, 412 (1976).
H. Arai, T. Yamashiro, T. Kubo and H. Tominaga, Bull. Japan Petroleum Institute 18, 39 (1976).
S. Tsuruya, Y. Okamoto and T. Kuwada, J. Catal., 50, 52 (1979).
S. Tsuruya, H. Miyamoto, T. Sakae and M. Masai, J. Catal. 64, 260 (1980).
J. F. Roth, J. H. Craddock, A. Hershman, P. E. Paulik, Chem. Tech., 600 (1971).
B. K. Nefedov, N. S. Seergerva and L. L. Krasnova, Izv Akad. Nauk., SSSR, Khim, 614 (1977).
B. Christensen and M. S. Scurrell, J. Chem. Soc. Farad. Trans., 74, 2313 (1978).
N. Takakashi, Y. Orikasa and T. Yashima, J. Catal. 59, 61 (1979).
P. Gelin, Y. Ben Taarit and C. Naccache, VII International Congress on Catalysis, Tokyo (1980).
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Naccache, C., Taarit, Y.B. (1984). Transition Metal Exchanged Zeolites : Physical and Catalytic Properties. In: Ribeiro, F.R., Rodrigues, A.E., Rollmann, L.D., Naccache, C. (eds) Zeolites: Science and Technology. NATO ASI Series, vol 80. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6128-9_14
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DOI: https://doi.org/10.1007/978-94-009-6128-9_14
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