Abstract
Coffee is undoubtedly one of the most complex of the more commonly encountered food commodities from the point of view of its chemistry. Not so much because the green coffee bean contains a wide range of different chemical compounds, but rather that these compounds react and interact at all stages of coffee processing to produce a final product (a cup of coffee) with an even greater diversity and complexity of structures. Our understanding of this complex mixture has been exacerbated by two major analytical problems, namely the extremely low levels at which some compounds are present, and yet will have sensory significance, and secondly that many of the interactions lead to the formation of high molecular weight polymeric material which is often very difficult to characterise structurally. Nonetheless, polymeric material may well contribute up to 50 % of a coffee brew and is important for aroma retention as well as physical properties. These analytical problems become readily apparent in a consideration of the nitrogenous components. Thus, for example, volatile nitrogen heterocyclic compounds may be present at the sub-ppb level, and the brown pigments or coloured matter present in coffee brew are mainly high molecular weight products of the browning reaction (melanoidins).
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Bothe, H. and Cammenga, N. K., Proc. 9th Coll. ASIC, 1980, 135–44.
Seidell, A. and Linke, W. F., Solubility of Organic Compounds, Vol. 2, Supplement, 3rd edn, Van Nostrand, New York, 1951, 610–13.
Stephen, H. and Stephen, T., Solubilities ofInorganic and Organic Compounds, Part 1, Pergamon, Oxford, 1963, Table 6227.
Sivetz, M. and Desrosier, N. W., Coffee Technology, AVI Publishing Co., Westport, Conn., 1979, 620.
Maier, H. G., Kaffee, Paul Parey, Berlin, 1981, 35–6.
Clifford, M. N., Proc. Biochem.,1975 (May), 13–16.
Clifford, M. N., Proc. Biochem.,1975 (May), 19.
Kroplien, U., Green and Roasted Coffee Tests, Gordian, Hamburg, 1961.
Streuli, H., Proc. 6th Coll. ASIC, 1973, 61–72.
Roffi, J., Proc. 5th Coll. ASIC, 1971, 179–200.
Chassevent, F., Gerwig, S. and Bouharmont, M., Proc. 6th Coll. ASIC, 1973, 57–60.
Charrier, A. and Berthaud, J., Café Cacao Thé, 1975, 19, 251–64.
Charrier, A., Proc. 7th Coll. ASIC, 1975, 295–302.
Wurziger, J., Kaffee and Tee Markt, 1977, 27, 3–8.
Kum-Tatt, L., Analyst, 1961, 86, 825–8.
Kogan, L., DiCarlo, F. J. and Maynard, W. E., Anal. Chem., 1953, 25, 1118–20.
D’Ornano, M., Chassevent, F. and Pougneaud, S., Café Cacao Thé, 1967, 11, 14–30.
Sloman, K. G., Proc. 9th Coll. ASIC, 1980, 159–68.
Trugo, L. C., Macrae, R. and Dick, J., J. Sci. Fd Agric., 1983, 34, 300–6.
Angelucci, E., Proc. 6th Coll. ASIC, 1973, 178–83.
Clarke, R. J. and Walker, L. J., J. Sci. Fd Agric., 1974, 25, 1389–1404.
Vitzthum, O. G., in Kaffe und Coffin, Ed. O. Eichler, Springer-Verlag, Berlin, 1976, 3–64.
Zosel, K., Angew. Chem., 1978, 90, 748–55.
Clarke, R. J., Proc. 9th Coll. ASIC, 1980, 467–72.
Marks, V. and Kelly, J. F., Lancet, 1973, 14, 827.
Voilley, A., Sauvageot, F. and Durand, D., Proc. 8th Coll. ASIC, 1977, 251–9.
Graham, D. M., Nutr. Rev., 1978, 36, 97–102.
Kallman, W. M. and Isaac, W., Psych opharmacologie, 1975, 40, 313–18.
Dews, P. B., Ann. Rev. Nutr., 1982, 2, 323–41.
Stalder, R., Luginbuhl, H., Bexter, A. and Wurzner, H. P., Proc. 10th Coll. ASIC, 1982, 339–46.
Palm, P. E., Arnold, E. P., Rachwall, P. C., Leyczeik, J. C., Teague, K. W. and Kensler, C. J., Toxicol. appl. Pharmacol., 1978, 44, 1–16.
Association of Official Analytical Chemists, Official Methods of ’Analysis, 8th edn, Washington, DC, 1955, 238.
Borker, E., J. Assoc. offic. anal. Chem., 1959, 42, 299–301.
Borker, E., J. Assoc. offic. anal. Chem., 1960, 43, 620–2.
Association of Official Analytical Chemists, Official Methods of ’Analysis, 9th edn, Washington, DC, 1970, 237.
Levine, J., J. Assoc. of fic. anal. Chem., 1962, 46, 254–5.
Yeransian, J. A., Kadin, H. and Borker, E., J. Assoc. offic. anal. Chem., 1963, 46, 315–19.
Borker, E., J. Assoc. offic. anal. Chem., 1963, 46, 319–20.
Borker, E. and Sloman, K. G., J. Assoc. offic. anal. Chem., 1965, 48, 705–9.
Newton, J. M., J. Assoc. offic. anal. Chem., 1979, 62, 705–8.
International Standard, Modified Levine Method for Determination of Caffeine Content, IS 4052, 1983.
British Standard, Method of Test for Coffee and its Products, BS 5752, Part 3, 1984.
Baltes, W., Z. Lebensm. Unters. Forsch., 1971, 145, 34–8.
Strahl, N. R., Lewis, H. and Fargen, R., J. agric. Fd Chum., 1977, 25, 233–6.
Carisano, A., Riva, M. and Daghetta, A., Boll. Lab. Chim. Pror., 1972, 23, 557–60.
Vitzthum, O. G., Barthels, M. and Kwasny, K., Z. Lebensm. Unters. Forsch., 1974, 154, 135–40.
Jurgens, U. and Riessner, R., Dtsch. Lebensm. Rundschau, 1980, 76, 39–42
Wildanger, W., J. Chromatogr., 1975, 114, 480–2.
Madison, B. L., Kozarek, W. J. and Damo, C. P., J. Assoc. offic. anal. Chum., 1976, 59, 1258–61.
Duijn, J. van and Stegen, G. H. D. van der, J. Chromatogr., 1979, 179, 199–204.
Pokorny, S., Coupek, J., Tai, P. T. and Pokorny, J., Z. Lebensm. Unters. Forsch., 1975, 159, 43–6.
Ischler, N. H., Finucane, T. P. and Borker, E., Anal. Chem., 1948, 20, 1162–6.
Streuli, H., Handbuch der Lebensmittelchemie, Ed. J. Schormüller, Springer-Verlag, Berlin, 1970, 6, 1–95.
Navellier, P., Encyclopedia of Industrial Chemical Analysis, Ed. F. D. Snell and L. S. Ettre, Interscience, New York, 1970, 10, 373–447.
Teply, L. J. and Prier, R. F., J. agric. Fd Chem., 1957, 5, 375–7.
Czok, G., Proc. 2nd Coll. ASIC, 1965, 239–46.
Clifford, M. N., Proc. Biochem., 1975 (March), 20–9.
Merritt, M. C. and Proctor, B. E., Fd Res., 1959, 24, 672–80.
Thaler, H. and Gaigl, R., Z. Lebensm. Unters. Forsch., 1963, 119, 10–25.
Slotta, K. H. and Neisser, K., Ber., 1939, 72, 126–36.
Hughes, E. B. and Smith, R. F., J. Soc. Chem. Ind., 1946, 65, 284–6.
Trugo, L. D., PhD thesis, University of Reading, 1984.
Kwasny, H. and Werkhoff, P., Lebensm. Gerichlt. Chemie, 1978, 32, 36–8.
Viani, R. and Horman, I., J. Fd Sci., 1974, 39, 1216–17.
Viani, R. and Horman, I., Proc. 7th Coll. ASIC, 1975, 275–8.
Nottbohm, F. E. and Mayer, F., Z. Lebensm. Unters. Forsch., 1931, 61, 429–35.
François, M. and Blanc, L. G., Bull. Soc. Chim., 1933, 33, 640.
Perlzweig, W. A., Levy, E. D. and Sarett, H. P., J. biol. Chum., 1940, 136, 729–45.
Moores, R. G. and Greninger, D. M., Anal. Chum., 1951, 23, 327–31.
Hughes, E. B. and Smith, R. G., J. Soc. Chem. Ind., 1946, 65, 284–6.
Adrian, J., Proc. 1st Coll. ASIC, 1963, 141–9.
Adrian, J., Frangne, R., Xabregas, J. and Corte dos Santos, A., Proc. 3rd Coll. ASIC, 1967, 427–35.
Teply, L.J. and Prier, R. F., J. agric. Fd Chum., 1957, 5, 375–7.
Goldsmith, G. A., Miller, O. N., Unglaub, W. G. and Nercheval, K., Proc. Soc. exp. biol. Med., 1959, 102, 579.
Tchetche, A. G., Proc. 7th Coll. ASIC, 1977, 147–52.
Wang, Y. L. and Kodicek, E., Biochem. J., 1943, 37, 530–8.
Association of Vitamin Chemists, Methods of ’Vitamin Assay, Interscience, New York, 1966, 176–92.
Kuznetsova, C. M. and Chagovets, R. V., Ukr. Biochim. Zh., 1955, 27, 187.
Boddeker, H. and Mishkin, A. R., Anal. Chem., 1963, 35, 1662–3.
Okungbowa, P., Ma, M. C. F. and Truswell, A. S., Proc. Nutr. Soc., 1977, 36, 1A–27A.
Tressl, R., Proc. 9th Coll. ASIC, 1980, 55–76.
Barbiroli, G., Rassegna chimica, 1965, 17, 220–5.
Rof, Corte dos Santos, A., Mexia, J. T., Busson, F. and Maigrot, M., Proc. 5th Coll. ASIC, 1971, 179–200.
Thaler, H. and Gaigl, R., Z. Lebensm. Unters. Forsch., 1963, 120, 449–54.
Schweizerisches Lebensmittelbuch, Eidg. Drucksachen and Materialzentrale, Bern, 1973, Band III, Kap. 35.
Underwood, G. E. and Deatherage, F. E., Fd Res., 1952, 17, 419–24.
Amorim, H. V. and Josephson, R. V., J. Fd Sci., 1975, 40, 1179–84.
Amorim, H. V. and Josephson, R. V., Proc. 7th Coll. ASIC, 1975, 109–14.
Thaler, H. and Gaigl, R., Z. Lebensm. Unters. Forsch., 1963, 120, 357–63.
Herndlhofer, E., Biochem. Z., 1932, 255, 230–46.
Wilbaux, R., Ann. R.p. Congo Inst. Nat. Et. Agron. (2nd Part), 1938, 3–45.
Valencia, G. A., Cenicajé (Colombia), 1972, 23, 3–18.
Amorim, H. V. and Amorim, V. L., in Enzymes in Food and Beverage Processing, ACS Symposium Series, Ed. R. L. Ory and A. J. St Angelo, 1977, No. 47, 27–56.
Payne, R. C., Oliveira, A. R. and Fairbrothers, D. E., Biochem. Systemat., 1973, 1, 59–61.
Harpaz, N., Flowers, H. M. and Sharon, N., Biochim. biophys. Acta, 1974, 341, 213–21.
Berndt, W. and Maier-Cabell, E., Proc. 7th Coll. ASIC, 1975, 225–32.
Shadakscharaswamy, M. and Ramachandra, G., Enzymologia, 1968, 35, 93–9.
Rolz, C., Menchu, J. F.. Espinosa, R. and Garcia-Prendes, A., Proc. 5th Coll. ASIC, 1971, 259–68.
Maier, H. G., Kaffee, Paul Parey, Berlin, 1981, 64–7.
Maier, H. G. and Buttle, H., Z. Lebensm. Unters. Forsch., 1973, 150, 331–4.
Maier, H. G., Diemair, W. and Ganssmann, J., Z. Lebensm. Untcrs. Forsch., 1968, 137, 282–92.
Aurich, H., Hofmann, R., Klocking, R. and Mucke, D., Z. Lebensm. Untcrs. Forsch., 1967, 135, 59–64.
Feldman, J. R., Ryder, W. S. and Kung, J. T., J. agric. Fd Chum., 1969, 17, 733–9.
Wewetzer, H., Dissertation, TU Braunschweig, Fed. Rep. Germany, 1978.
Klocking, R., Hofmann, R. and Mucke, D., Z. Lebensm. Untcrs. Forsch., 1967, 135, 1–9.
Walter, W., Grigal, H. G. and Heukeshoven, J., Naturwiss., 1970, 57, 246–7.
Maier, H. G., Kaffee, Paul Parey, Berlin, 1981, 28.
Tressl, R., Holzer, M. and Kamperschroer, H., Proc. 10th Coll. ASIC, 1982, 279–92.
Campos, L. S. and Rodrigues, J. M. L., Proc. 5th Coll. ASIC, 1971, 91–6.
Pereira, A. and Pereira, M. M., Proc. 5th Coll. ASIC, 1971, 85–90.
Macrae, R. and Nicolson, 1. A., unpublished data, 1984.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1985 Elsevier Science Publishers Ltd
About this chapter
Cite this chapter
Macrae, R. (1985). Nitrogenous Components. In: Clarke, R.J., Macrae, R. (eds) Coffee. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4948-5_4
Download citation
DOI: https://doi.org/10.1007/978-94-009-4948-5_4
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8693-6
Online ISBN: 978-94-009-4948-5
eBook Packages: Springer Book Archive