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Thermodynamics of Ion Exchange: Prediction of Multicomponent Equilibria from Binary Data

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Ion Exchange: Science and Technology

Part of the book series: NATO ASI Series ((NSSE,volume 107))

Abstract

The elementary principles of ion exchange are covered in the excellent monograph by Helfferich [5]. Solid materials such as zeolites and resins are used to capture ions from solution by adsorption. However, the requirement of electroneutrality means that the solid must release one ion equivalent for every one captured. A typical cation exchange is:

$$2NaX(s) + CaC{1_2}(aq) = Ca{X_2}(s) + 2NaC1(aq)$$
(1)

where NaX is a solid ion exchanger containing exchangeable Na+ ions.

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© 1986 Martinus Nijhoff Publishers, Dordrecht

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Myers, A.L., Byington, S. (1986). Thermodynamics of Ion Exchange: Prediction of Multicomponent Equilibria from Binary Data. In: Rodrigues, A.E. (eds) Ion Exchange: Science and Technology. NATO ASI Series, vol 107. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4376-6_5

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  • DOI: https://doi.org/10.1007/978-94-009-4376-6_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8445-1

  • Online ISBN: 978-94-009-4376-6

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