Abstract
The elementary principles of ion exchange are covered in the excellent monograph by Helfferich [5]. Solid materials such as zeolites and resins are used to capture ions from solution by adsorption. However, the requirement of electroneutrality means that the solid must release one ion equivalent for every one captured. A typical cation exchange is:
where NaX is a solid ion exchanger containing exchangeable Na+ ions.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Barrer, R.M. and W.M. Meier. Exchange Equilibria in a Synthetic Crystalline Exchanger. Trans. Faraday Soc. 55, 130 (1959).
Bonner, O.D. and Rhett, V. Equilibrium Studies of the Silver-Sodium-Hydrogen System on Dowex 50. J. Amer. Chem. Soc. 57, 254 (1953).
Bonner, O.D. and W. Payne. Equilibrium Studies of Some Monovalent Ions on Dowex 50. J. Amer. Chem. Soc. 58, 183 (1954)
Dranoff, J. and L. Lapidus. Equilibrium in Ternary Ion Exchange Systems. Ind. Eng. Chem. 49, 1297 (1957)
Helfferich, F. Ion Exchange (McGraw-Hill, New York,1962)
Kataoka, K. and H. Yoshida. Ion Exchange Equilibria in Ternary Systems. J. of Chem. Engrng. of Japan. 1, 328 (1980)
Manning, M. and S. Melshelmer. Binary and Ternary Ion-Exchange Equilibria with a Perfluorosulfonic Acid Membrane. Ind. Eng. Chem. 22, 311 (1983)
Novosad, J. and A.L. Myers. Thermodynamics of Ion Exchange as an Adsorption Process. Canadian J. of Chem. Engrng. 60, 500 (1982)
Pal, G., Chakravarti, A. and M. Sengupta. Studies in Ion Exchange Equilibria II: Some Cation and Anion Exchange Selectivities in Amberlite Resins. Ion Exchange and Membranes 2, 21 (1974)
Pieroni, L. and J. Dranoff. Ion Exchange Equilibrium in a Ternary System. AIChE Journal, 42 (1963)
Smith, R.P. and E.T. Woodburn. Prediction of Multicomponent Ion Exchange Equilibria for the Ternary System SO2/NO/C1 from Data on Binary Systems. AIChE Journal 24, 577 (19 78)
Soldatov, V.S. and V.A. Bychkova. Ion Exchange in Multicomponent Systems.Calculation of Ion-Exchange Equilibrium in the Ternary System K NH H from Data for Binary Systems. Russ. J. of Phys.Chem. 44, 1297 (1970)
Subba Rao, H. and M.M. David. AIChE Journal. 3, 187 (1957)
Streat, M. and W. Brignal. Representation of Ternary Ion Exchange Equilibria. Trans. Inst. Chem. Engrs. 48, T151 (1970)
Tondeur, D. and G. Klein. Multicomponent Ion Exchange in Fixed Beds. Ind. Eng. Chem. Fund. 6, 351 (1967)
Khoroshko, R., Kolnenkov, V., Soldatov, V., Sudarikova, N. and N.G. Peryshkina. Synthetic Culture Media for the Growth of Plants on the Basis of Ion Exchange Materials. Agrokhimiya, 10 (1974) 122.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1986 Martinus Nijhoff Publishers, Dordrecht
About this chapter
Cite this chapter
Myers, A.L., Byington, S. (1986). Thermodynamics of Ion Exchange: Prediction of Multicomponent Equilibria from Binary Data. In: Rodrigues, A.E. (eds) Ion Exchange: Science and Technology. NATO ASI Series, vol 107. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4376-6_5
Download citation
DOI: https://doi.org/10.1007/978-94-009-4376-6_5
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8445-1
Online ISBN: 978-94-009-4376-6
eBook Packages: Springer Book Archive