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Biogeochemistry of Trace Elements: Reactions in Soils

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Salinity and Drainage in San Joaquin Valley, California

Part of the book series: Global Issues in Water Policy ((GLOB,volume 5))

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Abstract

The trace element of greatest concern in the San Joaquin Valley is Se, although As, B, Mo, V, and U have been found at elevated concentrations in the soils, groundwater, and parent materials. Biogeochemical reactions involving dissolution, precipitation, adsorption, organic complexation, oxidation, and reduction affect the relative mobility and toxicity of these elements. Generally, Se, B, Mo, and V are solubilized under aerobic conditions during irrigation of upland soils. Reduction reactions and organic matter production in flooded soils results in the accumulation of Se, Mo, V, and U in these soils. Boron and As remain soluble under reducing conditions. Changing management to increase aerobic conditions in formerly flooded soils and pond sediments increases Se availability to biota.

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Authors and Affiliations

  1. Department of Environmental Sciences, University of California, Riverside, CA, 92521, USA

    Christopher Amrhein

  2. Department of Environmental Sciences, Policy and Management, University of California, Berkeley, CA, USA

    Harvey E. Doner

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  1. Christopher Amrhein
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  2. Harvey E. Doner
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Correspondence to Christopher Amrhein .

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Editors and Affiliations

  1. Center for Water Resources, University of California, Riverside, California, USA

    Andrew C. Chang

  2. Center for Water Resources, University of California, Riverside, California, USA

    Deborah Brawer Silva

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Amrhein, C., Doner, H.E. (2014). Biogeochemistry of Trace Elements: Reactions in Soils. In: Chang, A., Brawer Silva, D. (eds) Salinity and Drainage in San Joaquin Valley, California. Global Issues in Water Policy, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6851-2_5

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