Abstract
In the domain of Li-ion batteries, Mössbauer spectroscopy is mainly used for the characterization of electrode materials and the analysis of electrochemical reactions. Depending on the properties under investigation, different approaches are often considered, which are based on ex situ, in situ and operando measurements. The specific electrochemical cells and sample preparations used for such measurements are described in this paper. Applications to selected examples of cathode and anode materials are presented in order to show how Mössbauer spectroscopy, when associated with other techniques, provides essential information to understand the mechanisms and improves the performances of Li-ion batteries.
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Tarascon, J.M.: Phil. Trans. Royal Soc. A 368, 3227 (2010)
Naille, S., Dedryvère, R., Zitoun, D., Lippens, P.E.: J. Power Sources 189, 814 (2009)
Lippens, P.E., Jumas, J.C. (Guest Ed.): It’s all about the battery. Mössbauer Eff. Ref. Data J., 33(2) (2010)
Jumas, J.-C., Womes, M., Lippens, P.E., Olivier-Fourcade, J.: Hyperfine Interact. 182, 103 (2008)
Robert, F., Lippens, P.E., Olivier-Fourcade, J., Jumas, J.C., Morcrette, M.: J. Power Sources 146, 492 (2005)
Aldon, L., Kubiak, P., Picard, A., Lippens, P.E., Jumas, J.C., Olivier-Fourcade, J.: Hyperfine Interact. 156, 497 (2004)
Lippens, P.E., Jumas, J.C.: Nanocomposites, Ionic Conducting Materials and Structural Spectroscopies. Springer, Series: Electronic Materials: Science & Technology, Vol. 10, Knauth, Philippe; Schoonman, Joop (Eds.), ISBN: 978-0-387-33202-4, p. 247–272 (2008)
Geronov, Y., Tomov, T., Georgiev, S.: J. Appl. Electrochem. 5, 351 (1975)
Chianelli, R.R., Scanlon, J.C., Rao, B.M.L.: J. Electrochem. Soc. 125, 1563 (1978)
Mao, O., Dunlap, R.A., Courtney, I.A., Dahn, J.R.: J. Electrochem. Soc. 145, 4195 (1998)
Dunlap, R.A., Obrovac, M.N., Li, J., Smith, A., Hatchard, T.D., Sanderson, R.J., Dahn, J.R.: Mössbauer Eff. Ref. Data J. 33, 32 (2010)
Wattiaux, A., Fournès, L., Delmas, C.: Mössbauer Eff. Ref. Data J. 33, 37 (2010)
Ariyoshi, K., Ohzuku, T.: Mössbauer Eff. Ref. Data J. 33, 43 (2010)
Tarascon, J.M., Gozdz, A., Schmutz, C., Shokoohi, F., Warren, P.C.: Solid State Ionics 86, 49 (1996)
Aldon, L., Ionica, C., Lippens, P.E., Morcrette, M., Larcher, D., Tarascon, J.M., Jumas, J.C.: Hyperfine Interact. 167, 729 (2006)
Bousquet, C.M., Lippens, P.E., Aldon, L., Olivier-Fourcade, J., Jumas, J.C.: Chem. Mater. 18, 6442 (2006)
Aboulaich, A., Robert, F., Lippens, P.E., Aldon, L., Olivier-Fourcade, J., Willmann, P., Jumas, J.C.: Hyperfine Interact. 167, 733 (2006)
Leriche, J.B., Hamelet, S., Shu, J., Morcrette, M., Masquelier, C., Ouvrard, G., Zerrouki, M., Soudan, P., Belin, S., Elkaïm, E., Baudelet, F.: J. Electrochem. Soc. 157, A606 (2010)
Pahdi, A.K., Nanjundaswami, K.S., Goodenough, J.B.: J. Electrochem. Soc. 144, 1188 (1997)
Yamada, A., Chung, S.C., Hinokuma, K.: J. Electrochem Soc. 48, A224 (2001)
Shiratsuchi, T., Okada, S., Yamaki, J.I., Yamashita, S., Nishida, T.: J. Power Sources 173, 979 (2007)
Zhang, W.J.: J. Power Sources 196, 2962 (2011)
Julien, C.M., Mauger, A., Zaghib, K.: J. Mater. Chem. 21, 9955 (2011)
Wagemaker, M., Ellis, B.L., Luetzenkirchen-Hecht, D., Mulder, F.M., Nazar, L.F.: Chem. Mater. 20, 6313 (2008)
Castro, L., Dedryvère, R., El Khalifi, M., Lippens, P.E., Bréger, J., Tessier, C., Gonbeau, D.: J. Phys. Chem C 114, 17995 (2010)
Andersson, A.S., Kalska, B., Häggström, L., Thomas, J.O.: Solid State Ionics 130, 41 (2000)
Aldon, L., Perea, A., Womes, M., Ionica-Bousquet, C.M., Jumas, J.-C.: J. Solid State Chem. 183, 218 (2010)
Yamada, A., Hosoya, M., Chung, S.C., Kudo, Y., Hinokuma, K., Liu, K.Y., Nishi, Y.: J. Power Sources 119, 232 (2003)
Yamada, A., Kudo, Y., Liu, K.Y.: J. Electrochem. Soc. 148, A1153 (2001)
Rho, Y.H., Nazar, L., Perry, L., Ryan, D.: J. Electrochem. Soc. 154, A283 (2007)
Wang, F., Zhao, M.S., Song, X.P.: J. Power Sources 175, 558 (2008)
Chouvin, J., Olivier-Fourcade, J., Jumas, J.C., Simon, B., Biensan, P.H., Madrigal, F.J.F., Tirado, J.L., Vicente, C.P.: J. Electroanal. Chem. 494, 136 (2000)
Idota, Y., Kubota, T., Matsufuji, A., Maekawa, Y., Miyasaka, T.: Science 276, 1395 (1997)
Zheng, Y., Yang, J., Nuli, Y.N., Wang, J.L.: J. Power Sources 174, 624 (2007)
Aboulaich, A., Mouyane, M., Robert, F., Lippens, P.E., Olivier-Fourcade, J., Willmann, P., Jumas, J.C.: J. Power Sources 174, 1224 (2007)
Mouyane, M., Lippens, P.E., Womes, M., Ducourant, B., Willmann, P., Olivier-Fourcade, J.: Hyperfine Interact. 187, 27 (2008)
Naille, S., Dedryvère, R., Leroy, S., Martinez, H., Lippens, P.E., Jumas, J.C., Gonbeau, D.: J. Power Sources 174, 1086 (2007)
Naille, S., Lippens, P.E., Morato, F., Olivier-Fourcade, J.: Hyperfine Interact. 167, 785 (2006)
Ehinon, K.K.D., Naille, S., Dedryvère, R., Lippens, P.E., Jumas, J.C., Gonbeau, D.: Chem. Mater. 20, 5388 (2008)
Hassoun, J., Panero, S., Simon, P., Taberna, P.L., Scrosati, B.: Advanced Mat. 19, 1632 (2007)
Alcantara, R., Rodriguez, I., Tirado, J.L.: Chem. Phys. Chem. 9, 1171 (2008)
He, J., Zhao, H., Wang, J., Chen, J.: J. Alloys Compd. 508, 629 (2010)
Mao, O., Dunlap, R.A., Dahn, J.R.: Solid State Ionics 118, 99 (1999)
Nwokeke, U.G., Alcántara, R., Tirado, J.L., Stoyanova, R., Zhecheva, E.: J. Power Sources 196, 6768 (2011)
Chamas, M., Lippens, P.E., Jumas, J.C., Boukerma, K., Dedryvère, R., Gonbeau, D., Hassoun, J., Panero, S., Scrosati, B.: J. Power Sources 196, 7011 (2011)
Naille, S., Mouyane, M., El Amraoui, M., Lippens, P.-E., Jumas, J.-C., Olivier-Fourcade, J.: Hyperfine Interact. 187, 19 (2008)
Sony, U.S. Patent 0053131
Ferguson, P.P., Martine, M.L., George, A.E., Dahn, J.R.: J. Power Sources 194, 794 (2009)
Ferguson, P.P., Todd, A.D.W., Dahn, J.R.: Electrochem. Commun. 10, 25 (2008)
Ortiz, G.F., Alcántara, R., Rodríguez, I., Tirado, J.L.: J. Electroanal. Chem. 605, 98 (2007)
Hassoun, J., Panero, S., Mulas, G., Scrosati, B.: J. Power Sources 171, 928 (2007)
Nwokeke, U.G., Chadwick, A.V., Alcántara, R., Alfredsson, M., Tirado, J.L.: J. Alloys Compd. 509, 3074 (2011)
Robert, F., Lippens, P.E., Fourcade, R., Jumas, J.C., Morcrette, M., Tarascon, J.M.: Hyperfine Interact. 167, 797 (2006)
Robert, F., Lippens, P.E., Olivier-Fourcade, J., Jumas, J-C., Gillot, F., Morcrette, M., Tarascon, J-M.: J. Solid State Chem. 180, 339 (2007)
Lippens, P.E., Aldon, L., Ionica, C.M., Robert, F., Olivier-Fourcade, J., Jumas, J.C.: Characterization of Li insertion mechanisms in negative electrode materials for Li-ion batteries by Mössbauer spectroscopy and first-principles calculations. In: Knauth, P., Masquelier, C., Traversa, E., Wachsman, E.D. (eds.) Solid State Ionics 2004. Materials Research Society Symposium Proceedings, vol. 835, pp. 249–260. Materials Research Society, Warrendale (2005)
Chamas, M., Lippens, P-E., Jumas, J-C., Hassoun, J., Panero, S., Scrosati, B.: Electrochim. Acta 56, 6732 (2011)
Sivasankaran, V., Marino, C., Chamas, M., Soudan, P., Guyomard, D., Jumas, J.C., Lippens, P.E., Monconduit, L., Lestriez, B.: J. Mater. Chem 21, 5076 (2011)
Li, J., Le, D.B., Ferguson, P.P., Dahn, J.R.: Electrochim. Acta 55, 2991 (2010)
Dunlap, R.A., Mao, O., Dahn, J.R.: Phys. Rev. B 59, 3494 (1999)
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Lippens, PE. et al. (2013). How Mössbauer spectroscopy can improve Li-ion batteries. In: Yoshida, Y. (eds) ICAME 2011. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4762-3_54
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DOI: https://doi.org/10.1007/978-94-007-4762-3_54
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-4761-6
Online ISBN: 978-94-007-4762-3
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