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How Mössbauer spectroscopy can improve Li-ion batteries

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ICAME 2011

Abstract

In the domain of Li-ion batteries, Mössbauer spectroscopy is mainly used for the characterization of electrode materials and the analysis of electrochemical reactions. Depending on the properties under investigation, different approaches are often considered, which are based on ex situ, in situ and operando measurements. The specific electrochemical cells and sample preparations used for such measurements are described in this paper. Applications to selected examples of cathode and anode materials are presented in order to show how Mössbauer spectroscopy, when associated with other techniques, provides essential information to understand the mechanisms and improves the performances of Li-ion batteries.

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References

  1. Tarascon, J.M.: Phil. Trans. Royal Soc. A 368, 3227 (2010)

    Article  ADS  Google Scholar 

  2. Naille, S., Dedryvère, R., Zitoun, D., Lippens, P.E.: J. Power Sources 189, 814 (2009)

    Article  Google Scholar 

  3. Lippens, P.E., Jumas, J.C. (Guest Ed.): It’s all about the battery. Mössbauer Eff. Ref. Data J., 33(2) (2010)

    Google Scholar 

  4. Jumas, J.-C., Womes, M., Lippens, P.E., Olivier-Fourcade, J.: Hyperfine Interact. 182, 103 (2008)

    Article  ADS  Google Scholar 

  5. Robert, F., Lippens, P.E., Olivier-Fourcade, J., Jumas, J.C., Morcrette, M.: J. Power Sources 146, 492 (2005)

    Article  Google Scholar 

  6. Aldon, L., Kubiak, P., Picard, A., Lippens, P.E., Jumas, J.C., Olivier-Fourcade, J.: Hyperfine Interact. 156, 497 (2004)

    Article  ADS  Google Scholar 

  7. Lippens, P.E., Jumas, J.C.: Nanocomposites, Ionic Conducting Materials and Structural Spectroscopies. Springer, Series: Electronic Materials: Science & Technology, Vol. 10, Knauth, Philippe; Schoonman, Joop (Eds.), ISBN: 978-0-387-33202-4, p. 247–272 (2008)

    Google Scholar 

  8. Geronov, Y., Tomov, T., Georgiev, S.: J. Appl. Electrochem. 5, 351 (1975)

    Article  Google Scholar 

  9. Chianelli, R.R., Scanlon, J.C., Rao, B.M.L.: J. Electrochem. Soc. 125, 1563 (1978)

    Article  Google Scholar 

  10. Mao, O., Dunlap, R.A., Courtney, I.A., Dahn, J.R.: J. Electrochem. Soc. 145, 4195 (1998)

    Article  Google Scholar 

  11. Dunlap, R.A., Obrovac, M.N., Li, J., Smith, A., Hatchard, T.D., Sanderson, R.J., Dahn, J.R.: Mössbauer Eff. Ref. Data J. 33, 32 (2010)

    Google Scholar 

  12. Wattiaux, A., Fournès, L., Delmas, C.: Mössbauer Eff. Ref. Data J. 33, 37 (2010)

    Google Scholar 

  13. Ariyoshi, K., Ohzuku, T.: Mössbauer Eff. Ref. Data J. 33, 43 (2010)

    Google Scholar 

  14. Tarascon, J.M., Gozdz, A., Schmutz, C., Shokoohi, F., Warren, P.C.: Solid State Ionics 86, 49 (1996)

    Article  Google Scholar 

  15. Aldon, L., Ionica, C., Lippens, P.E., Morcrette, M., Larcher, D., Tarascon, J.M., Jumas, J.C.: Hyperfine Interact. 167, 729 (2006)

    Article  ADS  Google Scholar 

  16. Bousquet, C.M., Lippens, P.E., Aldon, L., Olivier-Fourcade, J., Jumas, J.C.: Chem. Mater. 18, 6442 (2006)

    Article  Google Scholar 

  17. Aboulaich, A., Robert, F., Lippens, P.E., Aldon, L., Olivier-Fourcade, J., Willmann, P., Jumas, J.C.: Hyperfine Interact. 167, 733 (2006)

    Article  ADS  Google Scholar 

  18. Leriche, J.B., Hamelet, S., Shu, J., Morcrette, M., Masquelier, C., Ouvrard, G., Zerrouki, M., Soudan, P., Belin, S., Elkaïm, E., Baudelet, F.: J. Electrochem. Soc. 157, A606 (2010)

    Article  Google Scholar 

  19. Pahdi, A.K., Nanjundaswami, K.S., Goodenough, J.B.: J. Electrochem. Soc. 144, 1188 (1997)

    Article  Google Scholar 

  20. Yamada, A., Chung, S.C., Hinokuma, K.: J. Electrochem Soc. 48, A224 (2001)

    Article  Google Scholar 

  21. Shiratsuchi, T., Okada, S., Yamaki, J.I., Yamashita, S., Nishida, T.: J. Power Sources 173, 979 (2007)

    Article  Google Scholar 

  22. Zhang, W.J.: J. Power Sources 196, 2962 (2011)

    Article  Google Scholar 

  23. Julien, C.M., Mauger, A., Zaghib, K.: J. Mater. Chem. 21, 9955 (2011)

    Article  Google Scholar 

  24. Wagemaker, M., Ellis, B.L., Luetzenkirchen-Hecht, D., Mulder, F.M., Nazar, L.F.: Chem. Mater. 20, 6313 (2008)

    Article  Google Scholar 

  25. Castro, L., Dedryvère, R., El Khalifi, M., Lippens, P.E., Bréger, J., Tessier, C., Gonbeau, D.: J. Phys. Chem C 114, 17995 (2010)

    Article  Google Scholar 

  26. Andersson, A.S., Kalska, B., Häggström, L., Thomas, J.O.: Solid State Ionics 130, 41 (2000)

    Article  Google Scholar 

  27. Aldon, L., Perea, A., Womes, M., Ionica-Bousquet, C.M., Jumas, J.-C.: J. Solid State Chem. 183, 218 (2010)

    Article  ADS  Google Scholar 

  28. Yamada, A., Hosoya, M., Chung, S.C., Kudo, Y., Hinokuma, K., Liu, K.Y., Nishi, Y.: J. Power Sources 119, 232 (2003)

    Article  Google Scholar 

  29. Yamada, A., Kudo, Y., Liu, K.Y.: J. Electrochem. Soc. 148, A1153 (2001)

    Article  Google Scholar 

  30. Rho, Y.H., Nazar, L., Perry, L., Ryan, D.: J. Electrochem. Soc. 154, A283 (2007)

    Article  Google Scholar 

  31. Wang, F., Zhao, M.S., Song, X.P.: J. Power Sources 175, 558 (2008)

    Article  Google Scholar 

  32. Chouvin, J., Olivier-Fourcade, J., Jumas, J.C., Simon, B., Biensan, P.H., Madrigal, F.J.F., Tirado, J.L., Vicente, C.P.: J. Electroanal. Chem. 494, 136 (2000)

    Article  Google Scholar 

  33. Idota, Y., Kubota, T., Matsufuji, A., Maekawa, Y., Miyasaka, T.: Science 276, 1395 (1997)

    Article  Google Scholar 

  34. Zheng, Y., Yang, J., Nuli, Y.N., Wang, J.L.: J. Power Sources 174, 624 (2007)

    Article  Google Scholar 

  35. Aboulaich, A., Mouyane, M., Robert, F., Lippens, P.E., Olivier-Fourcade, J., Willmann, P., Jumas, J.C.: J. Power Sources 174, 1224 (2007)

    Article  Google Scholar 

  36. Mouyane, M., Lippens, P.E., Womes, M., Ducourant, B., Willmann, P., Olivier-Fourcade, J.: Hyperfine Interact. 187, 27 (2008)

    Article  ADS  Google Scholar 

  37. Naille, S., Dedryvère, R., Leroy, S., Martinez, H., Lippens, P.E., Jumas, J.C., Gonbeau, D.: J. Power Sources 174, 1086 (2007)

    Article  Google Scholar 

  38. Naille, S., Lippens, P.E., Morato, F., Olivier-Fourcade, J.: Hyperfine Interact. 167, 785 (2006)

    Article  ADS  Google Scholar 

  39. Ehinon, K.K.D., Naille, S., Dedryvère, R., Lippens, P.E., Jumas, J.C., Gonbeau, D.: Chem. Mater. 20, 5388 (2008)

    Article  Google Scholar 

  40. Hassoun, J., Panero, S., Simon, P., Taberna, P.L., Scrosati, B.: Advanced Mat. 19, 1632 (2007)

    Article  Google Scholar 

  41. Alcantara, R., Rodriguez, I., Tirado, J.L.: Chem. Phys. Chem. 9, 1171 (2008)

    Article  Google Scholar 

  42. He, J., Zhao, H., Wang, J., Chen, J.: J. Alloys Compd. 508, 629 (2010)

    Article  Google Scholar 

  43. Mao, O., Dunlap, R.A., Dahn, J.R.: Solid State Ionics 118, 99 (1999)

    Article  Google Scholar 

  44. Nwokeke, U.G., Alcántara, R., Tirado, J.L., Stoyanova, R., Zhecheva, E.: J. Power Sources 196, 6768 (2011)

    Article  Google Scholar 

  45. Chamas, M., Lippens, P.E., Jumas, J.C., Boukerma, K., Dedryvère, R., Gonbeau, D., Hassoun, J., Panero, S., Scrosati, B.: J. Power Sources 196, 7011 (2011)

    Article  Google Scholar 

  46. Naille, S., Mouyane, M., El Amraoui, M., Lippens, P.-E., Jumas, J.-C., Olivier-Fourcade, J.: Hyperfine Interact. 187, 19 (2008)

    Article  ADS  Google Scholar 

  47. Sony, U.S. Patent 0053131

    Google Scholar 

  48. Ferguson, P.P., Martine, M.L., George, A.E., Dahn, J.R.: J. Power Sources 194, 794 (2009)

    Article  Google Scholar 

  49. Ferguson, P.P., Todd, A.D.W., Dahn, J.R.: Electrochem. Commun. 10, 25 (2008)

    Article  Google Scholar 

  50. Ortiz, G.F., Alcántara, R., Rodríguez, I., Tirado, J.L.: J. Electroanal. Chem. 605, 98 (2007)

    Article  Google Scholar 

  51. Hassoun, J., Panero, S., Mulas, G., Scrosati, B.: J. Power Sources 171, 928 (2007)

    Article  Google Scholar 

  52. Nwokeke, U.G., Chadwick, A.V., Alcántara, R., Alfredsson, M., Tirado, J.L.: J. Alloys Compd. 509, 3074 (2011)

    Article  Google Scholar 

  53. Robert, F., Lippens, P.E., Fourcade, R., Jumas, J.C., Morcrette, M., Tarascon, J.M.: Hyperfine Interact. 167, 797 (2006)

    Article  ADS  Google Scholar 

  54. Robert, F., Lippens, P.E., Olivier-Fourcade, J., Jumas, J-C., Gillot, F., Morcrette, M., Tarascon, J-M.: J. Solid State Chem. 180, 339 (2007)

    Article  ADS  Google Scholar 

  55. Lippens, P.E., Aldon, L., Ionica, C.M., Robert, F., Olivier-Fourcade, J., Jumas, J.C.: Characterization of Li insertion mechanisms in negative electrode materials for Li-ion batteries by Mössbauer spectroscopy and first-principles calculations. In: Knauth, P., Masquelier, C., Traversa, E., Wachsman, E.D. (eds.) Solid State Ionics 2004. Materials Research Society Symposium Proceedings, vol. 835, pp. 249–260. Materials Research Society, Warrendale (2005)

    Google Scholar 

  56. Chamas, M., Lippens, P-E., Jumas, J-C., Hassoun, J., Panero, S., Scrosati, B.: Electrochim. Acta 56, 6732 (2011)

    Article  Google Scholar 

  57. Sivasankaran, V., Marino, C., Chamas, M., Soudan, P., Guyomard, D., Jumas, J.C., Lippens, P.E., Monconduit, L., Lestriez, B.: J. Mater. Chem 21, 5076 (2011)

    Article  Google Scholar 

  58. Li, J., Le, D.B., Ferguson, P.P., Dahn, J.R.: Electrochim. Acta 55, 2991 (2010)

    Article  Google Scholar 

  59. Dunlap, R.A., Mao, O., Dahn, J.R.: Phys. Rev. B 59, 3494 (1999)

    Article  ADS  Google Scholar 

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Correspondence to Pierre-Emmanuel Lippens .

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Lippens, PE. et al. (2013). How Mössbauer spectroscopy can improve Li-ion batteries. In: Yoshida, Y. (eds) ICAME 2011. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4762-3_54

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